A method of calculating an ammonia (NH3) mass generated in a lean NOx trap (LNT) of an exhaust purification device includes sequentially calculating a NH3 mass flow at a downstream of each slice from a first slice to an n-th slice, and integrating the NH3 mass flow at the downstream of the n-th slice over a predetermined time, wherein the calculation of the NH3 mass flow at the downstream of the i-th slice comprises calculating a NH3 mass flow flowing into the i-th slice, calculating a NH3 mass flow generated at the i-th slice, and adding the NH3 mass flow generated at the i-th slice to a value obtained by subtracting the NH3 mass flow used to reduce the NOx and the O2 at the i-th slice from the NH3 mass flow flowing into the i-th slice.

An exhaust gas purifying system includes: a NOx trapping agent (2) which adsorbs nitrogen oxide when an excess air ratio of exhaust gas is more than 1, and releases nitrogen oxide when the excess air ratio is 1 or less; a NOx purifying catalyst (13) which reduces nitrogen oxide to nitrogen; and an oxygen concentration controller which controls oxygen concentration in the exhaust gas. When the excess air ratio of the exhaust gas is more than 1, nitrogen oxide is adsorbed to the NOx trapping agent (2). When the excess air ratio of the exhaust gas is 1 or less, the oxygen concentration controller controls the oxygen concentration of the exhaust gas at an inlet of the NOx purifying catalyst between 0.8 and 1.5% by volume, so that the NOx purifying catalyst reduces nitrogen oxide released from the NOx trapping agent.

A method for controlling regeneration a catalyst by an exhaust gas purification device includes: measuring a temperature of exhaust gas flowing into a first catalyst unit; estimating a NO.sub.x amount loaded into the first catalyst unit and a slip amount of NO.sub.x of the first catalyst unit by using the temperature and an amount of the exhaust gas of the first catalyst unit; calculating a temperature of a second catalyst unit by using the temperature of the first catalyst unit; and estimating a NO.sub.x amount flowing into the second catalyst unit by using at least one of the slip amount of NO.sub.x of the first catalyst unit and the temperature of the second catalyst unit.

A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.

An exhaust gas treatment system, comprising an ozone purification system. The ozone purification system comprises an ozone amount control apparatus (209), used to control an amount of ozone so as to effectively oxidize gas components to be treated in exhaust gas, the ozone amount control apparatus (209) comprising a control unit (2091). By means of the present exhaust gas treatment system, particulate matter can be effectively removed from exhaust gas, and the system features a better exhaust gas purification treatment effect.

Methods and systems are provided for adjusting a regeneration scheme in response to ageing of a first catalyst and a second catalyst. In one example, a method may include determining a first ageing of the first catalyst and a second ageing of the second catalyst and updating factors of the regeneration scheme based on the first ageing and the second ageing.

Constraints on arrangement of catalysts are reduced, and early activation and long-term performance maintenance of the catalysts are both achieved. An exhaust pipe includes a first catalyst provided in a first exhaust pipe extending upward on the side of an exhaust manifold, and a second catalyst provided in a second exhaust pipe that extends downward from a bent pipe extending from the first exhaust pipe and that is adjacent to the first exhaust pipe. The second catalyst is disposed at a position offset to a higher location from an up-down middle position of the first exhaust pipe.

An exhaust treatment system includes an exhaust line, a series of emission treatment units, and an electronic control unit. The series of emission treatment units includes a catalytic unit, a particulate filter unit, an oxidation catalytic unit, a hydrogen injection unit, and a Lean NOx Trap (LNT) for trapping select emissions. A method of operating an exhaust treatment system includes introducing a fuel to a combustion engine of a motor vehicle, directing emissions from the combustion engine to an exhaust line, and passing the emissions in the exhaust line through a series of emission treatment units on the exhaust line. The method further includes injecting hydrogen into the exhaust line via a hydrogen injection unit, where an amount of hydrogen gas injected from a hydrogen inlet line reduces the trapped emissions in the LNT to an inert gas.

A vehicle includes a battery and a CO.sub.2 recovery device using electric power of the battery to recover CO.sub.2 contained in inflowing gas. A control device mounted in the vehicle controls the CO.sub.2 recovery device. The control device permits operation of the CO.sub.2 recovery device in the case where a high efficiency recovery condition, at which it is predicted that the efficiency of recovery of CO.sub.2, showing a ratio of the amount of recovery of CO.sub.2 in the CO.sub.2 recovery device with respect to the electric power consumed by the battery, will become equal to or greater than a preset predetermined efficiency, is satisfied, and prohibits operation of the CO.sub.2 recovery device in the case where the high efficiency recovery condition is not satisfied.

A control system for a vehicle, the control system having one or more controllers, the control system being arranged to: determine a likelihood of a NOx adsorber trap of a vehicle requiring purging; determine an efficiency of purging the NOx adsorber trap; determine an operating efficiency of a selective catalyst reduction system of the vehicle; determine a schedule for purging of the NOx adsorber trap of the vehicle in dependence on the likelihood of the NOx adsorber trap requiring purging, the efficiency of purging the NOx adsorber trap, and the operating efficiency of the selective catalyst reduction system; and control purging of the NOx adsorber trap according to the schedule.