A catalytic converter system having oxygen storage materials is disclosed and methods for determining whether to reactivate oxygen storage materials and monitoring failure events of the oxygen storage materials are also disclosed.

The present disclosure describes methods for evaluating ammonia storage capacity of a close-coupled SCR unit while remaining compliant with prescribed emissions limits, methods of controlling an emission aftertreatment system including multiple SCR units and emission management systems for a vehicle including an internal combustion engine and an emission aftertreatment system that includes two or more SCR units.

A catalytic converter system having oxygen storage materials is disclosed and methods for determining whether to reactivate oxygen storage materials and monitoring failure events of the oxygen storage materials are also disclosed.

In a method and a device for monitoring the operability of an emission control system of an internal combustion engine, at least two catalytic converters are situated in succession in an exhaust duct. For tracking control, breakthrough detection for diagnosing the first catalytic converter, and for a second balancing for the storage capacity of oxygen or rich gas of the second catalytic converter, a two-point lambda probe be used and, for the latter, tolerance and aging effects are compensated. This results in particular in cost advantages in emission control systems for fulfilling stricter emission and diagnostic requirements.

Systems and methods for controlling a gasoline urea selective catalytic reductant catalyst are described. In one example, an observer is provided that corrects an estimate of an amount of NH.sub.3 that is stored in a SCR. The amount of NH.sub.3 that is stored in the SCR is a basis for generating additional NH.sub.3 or ceasing generation of NH.sub.3.

An exhaust gas control apparatus for an internal combustion engine that can be operated at a lean air-fuel ratio is provided. This exhaust gas control apparatus is equipped with a three-way catalyst, an occlusion reduction NOx catalyst (an NSR catalyst) that is provided upstream of the three-way catalyst, a bypass passage that bypasses the NSR catalyst, a changeover valve that causes exhaust gas to flow through one of the bypass passage and the NSR catalyst, and an electronic control unit. The electronic control unit carries out rich spike, causes exhaust gas to flow through the bypass passage in starting rich spike, and causes exhaust gas to flow through the NSR catalyst after having carried out rich spike for a predetermined period.

An exhaust purification system comprising an exhaust purification catalyst, a downstream side air-fuel ratio sensor, and a control device performing air-fuel ratio control for controlling an air-fuel ratio of exhaust gas and abnormality diagnosis control for diagnosing the downstream side air-fuel ratio sensor. In the air-fuel ratio control, the control device alternately and repeatedly switches the air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst between a rich air-fuel ratio and a lean air-fuel ratio. In the abnormality diagnosis control, the control device judges that the downstream side air-fuel ratio sensor has become abnormal when the air-fuel ratio of the exhaust gas is made the rich air-fuel ratio by the air-fuel control and the output air-fuel ratio of the downstream side air-fuel ratio sensor changes from an air-fuel ratio richer than a predetermined lean judged air-fuel ratio to an lean air-fuel ratio.

To keep medium purification efficiency at a high level and prevent deterioration of emission performance. An aspect of the present invention includes: a downstream equivalence ratio calculation unit that calculates a catalyst downstream exhaust gas equivalence ratio by using a catalyst statistical model that receives at least a detection value of an air-fuel ratio sensor on an upstream side of a catalyst and outputs a catalyst downstream exhaust gas equivalence ratio; an oxygen output calculation unit that calculates an output value of an oxygen sensor by using an oxygen sensor statistical model that receives the catalyst downstream exhaust gas equivalence ratio and outputs an output value of the oxygen sensor on the downstream side of the catalyst; a downstream equivalence ratio correction unit that corrects the catalyst downstream exhaust gas equivalence ratio calculated by the downstream equivalence ratio calculation unit based on a calculation result of the oxygen output calculation unit and the detection value of the oxygen sensor; and an air-fuel ratio control unit that controls an air-fuel ratio of an air-fuel mixture of an internal combustion engine based on the corrected catalyst downstream exhaust gas equivalence ratio and air-fuel ratio target value.

A reduction method for a catalytic converter in an exhaust system of an internal combustion engine for reducing the oxygen content in the catalytic converter, in particular after an overrun fuel cutoff mode of the internal combustion engine, the method including first injection of fuel into a first cylinder, the first injection taking place after an ignition point in time of a compression stroke of a first working cycle of the cylinder and including an introduction of the injected fuel from the cylinder into the catalytic converter during an exhaust stroke of the first cylinder.

Methods and systems are provided for continually monitoring a functionality of an exhaust catalyst based on roll-down of a monotonically decreasing catalyst activity parameter representing catalyst storage capacity. Catalyst degradation may be indicated responsive to the estimate of catalyst storage capacity lowering below a threshold. Engine operating parameters may be adjusted based on a current level of catalyst storage capacity.