A nickel-based superalloy comprises, in percentages by mass, 4.0 to 5.5% rhenium, 1.0 to 3.0 ruthenium, 2.0 to 14.0% cobalt, 0.3 to 1.0% molybdenum, 3.0 to 5.0% chromium, 2.5 to 4.0% tungsten, 4.5 to 6.5% aluminum, 0.50 to 1.50% titanium, 8.0 to 9.0% tantalum, 0.15 to 0.30% hafnium, 0.05 to 0.15% silicon, the balance being nickel and unavoidable impurities. A single-crystal blade comprises such an alloy and a turbomachine comprising such a blade.

Using the systems and methods discussed herein, CMAS corrosion is inhibited via CMAS interception in an engine environment and/or is prevented or reduced by the formation of a metal oxide protective coating on a hot engine section component. The CMAS interception can occur while the engine is in operation in flight or in a testing or quality control environment. The metal oxide protective coating can be applied over other coatings, including Gd-zirconates (GZO) or yttria-stabilized zirconia (YSZ). The metal oxide protective coating is applied at original equipment manufacturers (OEM) and can also be applied in-situ using a gas injection system during engine use in-flight or during maintenance or quality testing. The metal oxide protective coating contains a rare earth element, aluminum, zirconium, chromium, or combinations thereof and can have a thickness from 1 nm to 3,000 nm.

Using the systems and methods discussed herein, CMAS corrosion is inhibited via CMAS interception in an engine environment and/or is prevented or reduced by the formation of a metal oxide protective coating on a hot engine section component. The CMAS interception can occur while the engine is in operation in flight or in a testing or quality control environment. The metal oxide protective coating can be applied over other coatings, including Gd-zirconates (GZO) or yttria-stabilized zirconia (YSZ). The metal oxide protective coating is applied at original equipment manufacturers (OEM) and can also be applied in-situ using a gas injection system during engine use in-flight or during maintenance or quality testing. The metal oxide protective coating contains a rare earth element, aluminum, zirconium, chromium, or combinations thereof.

A repaired oxidation and corrosion resistant coating may comprise a repair material applied to a damaged portion of the oxidation and corrosion resistant coating. The repair material may be free of hexavalent chromium and may be compatible with a plurality of oxidation and corrosion resistant materials that comprise hexavalent chromium. The repair material may be burnished. The oxidation and corrosion resistant coating may comprise hexavalent chromium.

A turbine component includes a substrate made from monocrystalline nickel-based superalloy including rhenium, which has a γ-γ′ Ni phase, and an average weight faction of chromium of less than 0.08, a sublayer made from nickel-based metal superalloy covering the substrate, in which the sublayer made from metal superalloy includes at least aluminium, nickel, chromium, silicon, hafnium and has, predominantly by volume, a γ′-Ni 3 Al phase.

Thermal sprayed coating made from a thermal spray powder material containing aluminum containing particles mechanically alloyed to a transition metal. The coating includes aluminum alloy portions alloyed to the transition metal. The thermal spray powder is made of aluminum containing particles mechanically alloyed to a transition metal.

A method of coating a component including aluminizing an array of internal passageways within the component; and chromizing a portion of the array of internal passageways within the component. A component, including an airfoil having an array of aluminized internal passageways, the array of aluminized internal passageways chromized up to a demarcation.

Methods for depositing protective coatings on aerospace components are provided and include sequentially exposing the aerospace component to a chromium precursor and a reactant to form a chromium-containing layer on a surface the aerospace component by an atomic layer deposition process. The chromium-containing layer contains metallic chromium, chromium oxide, chromium nitride, chromium carbide, chromium silicide, or any combination thereof.

Using the systems and methods discussed herein, CMAS corrosion is inhibited via CMAS interception in an engine environment and/or is prevented or reduced by the formation of a metal oxide protective coating on a hot engine section component. The CMAS interception can occur while the engine is in operation in flight or in a testing or quality control environment. The metal oxide protective coating can be applied over other coatings, including Gd-zirconates (GZO) or yttria-stabilized zirconia (YSZ). The metal oxide protective coating is applied at original equipment manufacturers (OEM) and can also be applied in-situ using a gas injection system during engine use in-flight or during maintenance or quality testing. The metal oxide protective coating contains a rare earth element, aluminum, zirconium, chromium, or combinations thereof, and is from 1 nm to 3 microns in thickness.

A rocket engine has: a combustion chamber having a chamber inlet for receiving an oxidizer and a chamber outlet for expelling combustion gases in an environment outside the combustion chamber; a manifold having a manifold inlet fluidly connectable to a source of the oxidizer and a manifold outlet; a catalyst having a catalyst inlet fluidly connected to the manifold outlet and a catalyst outlet; and an injector plate having a injector inlet fluidly connected to the catalyst outlet and an injector outlet fluidly connected to the chamber inlet.