The present disclosure relates to an energy storage device for water electrolysis hydrogen production coupled with low temperature and an energy storage method, which are used for solving the problem of the contradiction between the discontinuous photoelectric resources and the continuous requirements of green hydrogen for production. The device comprises a liquid nitrogen precooling hydrogen liquefaction system, a liquid hydrogen-liquid nitrogen heat exchanging system, a cold energy storage system and a cold energy utilization system of an air separation device. According to the present disclosure, the systems are highly coupled with each other, the photoelectric renewable energy can be maximized in the form of hydrogen storage, the energy consumption cost of green hydrogen preparation and utilization can be effectively reduced while high-efficiency energy storage and peak regulation are realized, the energy saving effect is achieved, and a good popularization prospect occurs.

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen.

An integrated industrial unit is provided, which can include: a nitrogen source configured to provide liquid nitrogen; a hydrogen source; a hydrogen liquefaction unit, wherein the hydrogen liquefaction unit comprises a precooling system, and a liquefaction system; and a liquid hydrogen storage tank, wherein the precooling system is configured to receive the gaseous hydrogen from the hydrogen source and cool the gaseous hydrogen to a temperature between 75 K and 100 K, wherein the precooling system comprises a primary refrigeration system and a secondary refrigeration system, wherein the liquefaction system is in fluid communication with the precooling system and is configured to liquefy the gaseous hydrogen received from the precooling system to produce liquid hydrogen, wherein the liquid hydrogen storage tank is in fluid communication with the liquefaction system and is configured to store the liquid hydrogen received from the liquefaction system.

A hydrogen feed stream is introduced into a primary refrigeration system of a precooling system and cooling the hydrogen stream to a first precooling temperature. From there, the precooled hydrogen stream is then introduced to a secondary refrigeration system of the precooling system and cooling the precooled hydrogen stream to a second temperature. Next, the cooled hydrogen stream is then liquefied in the liquefaction system to produce liquid hydrogen. The refrigeration is provided by expansion of a pressurized gaseous nitrogen stream and vaporization of a liquid nitrogen stream that is sourced from a nearby air separation unit.

A method for converting excess liquid oxygen into liquid nitrogen, including introducing a gaseous nitrogen stream into a main heat exchanger, therein exchanging heat with a vaporized oxygen stream, a vapor phase nitrogen steam, and a waste liquid nitrogen stream; thereby producing a cold gaseous nitrogen stream, an oxygen vent stream, a nitrogen vent steam, and a gaseous nitrogen waste stream, introducing the cold gaseous nitrogen stream into a secondary heat exchanger, therein exchanging heat with a liquid oxygen stream; thereby producing the vaporized oxygen stream and a cold liquid nitrogen stream, introducing the cold liquid nitrogen stream into a nitrogen pressure reduction valve thereby producing a two-phase nitrogen stream, introducing the two-phase nitrogen stream into a nitrogen flash vessel thereby producing a liquid phase nitrogen stream and the vapor phase nitrogen stream, wherein the method is performed in the absence of refrigerant turbo-expanders, refrigerant expansion turbines, or refrigerant compressors.

An apparatus for converting excess liquid oxygen into liquid nitrogen, including a main heat exchanger to exchange heat between a gaseous nitrogen stream, a vaporized oxygen stream, a vapor phase nitrogen steam, and a waste liquid nitrogen stream; thereby producing a cold gaseous nitrogen stream, an oxygen vent stream, a nitrogen vent steam, and a gaseous nitrogen waste stream, a secondary heat exchanger to exchange heat between a liquid oxygen stream and the cold gaseous nitrogen stream; thereby producing the vaporized oxygen stream and a cold liquid nitrogen stream, a nitrogen pressure reduction valve to reduce the pressure of the cold liquid nitrogen stream; thereby producing a two-phase nitrogen stream, a nitrogen flash vessel to receive the two-phase nitrogen stream, and to generate a liquid phase nitrogen stream and a vapor phase nitrogen stream, wherein the apparatus does not include any refrigerant turbo-expanders, refrigerant expansion turbines, or refrigerant compressors.

A process for producing liquid oxygen, including an offshore platform the system including cooling a high-pressure nitrogen gas stream in a main heat exchanger, thereby producing a cooled high-pressure nitrogen gas stream, expanding the cooled high-pressure nitrogen gas stream in a turbo-expander, thereby producing a cold low-pressure nitrogen gas stream, warming the cold low-pressure nitrogen gas stream by indirect heat exchange with a high-pressure gaseous oxygen stream, thereby producing a liquefied oxygen stream and a warm low-pressure nitrogen gas stream, wherein, at least a portion of the warm low-pressure nitrogen gas stream is vented to the atmosphere.

The present invention relates to a process and a system for supplying a backup gas at a higher pressure from a source gas at a lower pressure. The backup gas at the lower pressure is at least partially condensed against a backup liquid at a higher pressure in a reprocessing heat exchanger and as a result, the backup liquid is at least partially vaporized. The backup liquid at the higher pressure is formed from boosting liquefied backup gas at the lower pressure. A backup vaporizer is disposed downstream of the reprocessing heat exchanger to completely vaporize the backup liquid at a higher pressure before it was delivered to the customer. The present invention eliminates the use of costly gas compressor and mitigates associated safety risks, in particular when the backup gas is oxygen.

A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.