Patent classifications
F25J1/0234
HIGH ENERGY RECOVERY NITRIC ACID PROCESS USING LIQUID OXYGEN CONTAINING FLUID
A novel concept for a high energy and material efficient nitric acid production process and system is provided, wherein the nitric acid production process and system, particularly integrated with an ammonia production process and system, is configured to recover a high amount of energy out of the ammonia that it is consuming, particularly in the form of electricity, while maintaining a high nitric acid recovery in the conversion of ammonia to nitric acid. The energy recovery and electricity generation process comprises pressurizing a liquid gas, such as air, oxygen and/or N.sub.2, subsequently evaporating and heating the pressurized liquid gas, particularly using low grade waste heat generated in the production of nitric acid and/or ammonia, and subsequently expanding the evaporated pressurized liquid gas over a turbine. In particular, the generated electricity is at least partially used to power an electrolyzer to generate the hydrogen needed for the production of ammonia. The novel concepts set out in the present application are particularly useful in the production of nitric acid based on renewable energy sources.
LIQUEFACTION APPARATUS
A liquefaction apparatus that automatically adjusts the load on the liquefaction apparatus correspondingly with an upper limit value of contracted power in different time slots, and which is capable of maximizing the amount of liquefied product produced and of achieving optimum operating efficiency is provided. In certain embodiments, the liquefaction apparatus can include: a production amount calculation unit 91 for obtaining an actual production amount of a liquefied product; a predicted power calculation unit 92 for obtaining a predicted power amount after a predetermined time has elapsed, on the basis of an integrated power value obtained by integrating a usage power; and a power demand control unit 93 for comparing the predicted power amount and a moving average of instantaneous power, and controlling a discharge flow rate of a compressor 3 in such a way as to come infinitely close to a target value, without exceeding the target value, and while using the larger value of the predicted power amount and the moving average of instantaneous power as a value being controlled.
Apparatus and Process for Liquefying Gases
A liquefier device which may be a retrofit to an air separation plant or utilized as part of a new design. The flow needed for the liquefier comes from an air separation plant running in a maxim oxygen state, in a stable mode. The three gas flows are low pressure oxygen, low pressure nitrogen, and higher pressure nitrogen. All of the flows are found on the side of the main heat exchanger with a temperature of about 37 degrees Fahrenheit. All of the gasses put into the liquefier come out as a subcooled liquid, for storage or return to the air separation plant. This new liquefier does not include a front end electrical compressor, and will take a self produced liquid nitrogen, pump it up to a runnable 420 psig pressure, and with the use of turbines, condensers, flash pots, and multi pass heat exchangers. The liquefier will make liquid from a planned amount of any pure gas oxygen or nitrogen an air separation plant can produce.
POWER GENERATION PROCESS UTILIZING FUEL, LIQUID AIR AND/OR OXYGEN WITH ZERO CO2 EMISSIONS
A system which integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.
INTEGRATED GAS COMPRESSION AND REFRIGERATION WITH INTERNAL COOLING REGENERATION
A gas oil separation plant may include a gas compression plant, configured to receive, compress, and separate one or more feed streams and a warmed refrigerant stream into a compressed gas stream and a condensate stream, a flow system for dividing the condensate stream into an export condensate stream and a refrigerant stream, a gas dewpoint control plant comprising a gas chiller configured for indirectly contacting the compressed gas stream with the refrigerant stream, producing the warmed refrigerant stream, and a flow line for feeding the warmed refrigerant stream to the gas compression plant. A method for gas oil separation may include compressing and separating one or more feed streams and a warmed refrigerant stream into a compressed gas stream and a condensate stream. The condensate stream is divided into an export condensate stream and the refrigerant stream which chills the compressed gas stream and becomes the warmed refrigerant stream.
POWER GENERATION PROCESS UTILIZING FUEL, LIQUID AIR AND/OR OXYGEN WITH ZERO CO2 EMISSIONS
A system that integrates a power production system and an energy storage system represented by gas liquefaction systems is provided.
Method for liquefying natural gas and nitrogen
A method for producing liquefied natural gas and a stream of liquid nitrogen including step a): producing gaseous nitrogen in an air separation unit; step b): liquefying a stream of natural gas in a natural gas liquefaction unit including a main heat exchanger and a system for producing cold; step c): liquefying the nitrogen stream resulting from step a) in the main exchanger of the natural gas liquefaction unit in parallel with the liquefied natural gas in step b); wherein all the cold necessary for liquefying the stream of nitrogen and for liquefying the natural gas is supplied by the system for producing cold of the natural gas liquefaction unit.
COOLING SYSTEM
Cooling system, preferably adapted for use in or including a refrigeration plant and/or liquefier plant, having a refrigeration circuit (1) configured to use a refrigerant including a mixture of helium and neon; wherein the refrigerant is based on a raw mixture, preferably is the raw mixture, including helium and neon, extracted from air by an air separation plant (2). Method for producing a refrigerant usable in a refrigeration circuit (1), comprising: extracting a raw mixture including helium and neon from air, wherein the raw mixture preferably further includes nitrogen and hydrogen; and using the raw mixture as the refrigerant or obtaining the refrigerant from the raw mixture.
Apparatus and process for liquefying gases
A liquefier device which may be a retrofit to an air separation plant or utilized as part of a new design. The flow needed for the liquefier comes from an air separation plant running in a maxim oxygen state, in a stable mode. The three gas flows are low pressure oxygen, low pressure nitrogen, and higher pressure nitrogen. All of the flows are found on the side of the main heat exchanger with a temperature of about 37 degrees Fahrenheit. All of the gasses put into the liquefier come out as a subcooled liquid, for storage or return to the air separation plant. This new liquefier does not include a front end electrical compressor, and will take a self produced liquid nitrogen, pump it up to a runnable 420 psig pressure, and with the use of turbines, condensers, flash pots, and multi pass heat exchangers. The liquefier will make liquid from a planned amount of any pure gas oxygen or nitrogen an air separation plant can produce.
STAGED CRYOGENIC STORAGE TYPE SUPERCRITICAL COMPRESSED AIR ENERGY STORAGE SYSTEM AND METHOD
The present disclosure provides a supercritical compressed air energy storage system. The supercritical compressed air energy storage system includes a supercritical liquefaction subsystem, an evaporation and expansion subsystem, a staged cryogenic storage subsystem, a heat storage and heat exchange subsystem, and a cryogenic energy compensation subsystem, the staged cryogenic storage subsystem being used for implementing the staged storage and release of cryogenic energy, improving efficiency of recovering cryogenic energy during energy release and energy storage, and thereby improving cycle efficiency of the system. The present disclosure does not need to provide any inputs of additional cryogenic energy and heat energy input externally, and has the advantages of high cycle efficiency, low cost, independent operation, environmental friendliness, and no limitation on terrain conditions, and it is suitable for large-scale commercial applications.