Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

An NGL recovery facility utilizing a single, closed-loop mixed refrigerant cycle for recovering a substantial portion of the C.sub.2 and heavier or C.sub.3 and heavier NGL components from the incoming gas stream. Less severe operating conditions, including a warmer refrigerant temperature and a lower feed gas pressure, contribute to a more economical and efficient NGL recovery system.

Disclosed herein are processes for producing and separating ethane and ethylene. In some embodiments, an oxidative coupling of methane (OCM) product gas comprising ethane and ethylene is introduced to a separation unit comprising two separators. Within the separation unit, the OCM product gas is separated to provide a C.sub.2-rich effluent, a methane-rich effluent, and a nitrogen-rich effluent. Advantageously, in some embodiments the separation is achieved with little or no external refrigeration requirement.

The disclosure provides a process for recovery of C.sub.2 and C.sub.3 components in an on-purpose propylene production system utilizing a packed rectifier with a countercurrent stream to strip C.sub.2 and C.sub.3 components from a combined de-ethanizer overhead lights vapor and cracked gas vapor stream.

The invention relates to a method for recovery of methane from hydrocarbon streams comprising the following steps: a. Introducing a feed fluid stream (F), which comprises methane fluid, at least one hydrocarbon free fluid, wherein in particular said at least one hydrocarbon free fluid is nitrogen, and at least one hydrocarbon fluid, into a demethanizer system (1); b. Separating said feed fluid stream (F) in the demethanizer system (1) into a carbon rich fraction (C), comprising hydrocarbons with a carbon content of C2 and higher, and a separation stream (S), comprising methane fluid and at least one hydrocarbon free fluid; c. Introducing said separation stream (S) into a hydrocarbon-free fluid separation system (2), in particular in a cryogenic hydrocarbon-free fluid separation system (2′), more particularly into a cryogenic nitrogen rejection system (2″); wherein said separation stream (S) is compressed by a compressor system (6) before said separation stream (S) is introduced in said hydrocarbon-free fluid separation system (2), wherein said separation stream is compressed to a pressure of 12 bar to 80 bar; d. Separating said separation stream (S) in said free fluid separation system (2) into a methane stream (M) and a hydrocarbon-free fluid stream (HF) and a respective system for recovery of methane from hydrocarbon streams.

A method for producing hydrocarbons is proposed, in which a product stream containing hydrocarbons is produced from a methane-rich feed stream and from an oxygen-rich feed stream in a reaction unit which is configured for implementing a method for oxidative coupling of methane, the product stream or at least a stream formed therefrom being treated cryogenically in at least one separation unit using at least one liquid, methane-rich stream. It is provided that in the at least one separation unit (10) a recycle stream is formed from methane contained in product stream (c) and from methane contained in the at least one liquid, methane-rich stream (e, v), the recycle stream being fed to the reaction unit (1) as the methane-rich feed stream (a), and in that the liquid, methane-rich stream (e, v) is provided as makeup.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as a low-pressure tail gas of an ammonia production plant is provided. The disclosed system and method provides for a rectification system wherein an argon depleted gaseous stream and a methane rich liquid stream are produced and subsequently combined in whole or in part prior to vaporization. Nitrogen and argon containing streams may also be produced from the rectification system. An argon stripping column arrangement is also disclosed where residual argon is removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.