Methods are provided for emissions control of a vehicle. In one example, a method for an engine may include, responsive to a plurality of diagnostic entry conditions being met, indicating degradation of a hydrocarbon trap based on an NH.sub.3 amount in an exhaust gas. In some examples, the NH.sub.3 amount may be determined based on one or more NO.sub.x sensor outputs. In some examples, the plurality of diagnostic entry conditions may include the engine having been in operation over an initial duration immediately following an engine cold start. Conditions of the exhaust gas following the engine cold start may be opportunistically utilized in determining the NH.sub.3 amount from the one or more NO.sub.x sensor outputs. In some examples, the exhaust gas may be actively provided at a predetermined air-fuel ratio to meet at least one of the plurality of diagnostic entry conditions.

An evaporative emission control canister system comprises an initial adsorbent volume having an effective incremental adsorption capacity at 25° C. of greater than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, and at least one subsequent adsorbent volume having an effective incremental adsorption capacity at 25° C. of less than 35 grams n-butane/L between vapor concentration of 5 vol % and 50 vol % n-butane, an effective butane working capacity (BWC) of less than 3 g/dL, and a g-total BWC of between 2 grams and 6 grams. The evaporative emission control canister system has a two-day diurnal breathing loss (DBL) emissions of no more than 20 mg at no more than 210 liters of purge applied after the 40 g/hr butane loading step.

An exhaust passage includes a main passage and bypass passage, a catalyst, an exhaust control valve, and an HC adsorbent in the bypass passage. The exhaust control valve is controlled so that, when a temperature of the catalyst is higher than a predetermined sintering occurrence temperature, the quality of HC desorbed from the HC adsorbent is greater when the air-fuel ratio of the exhaust gas flowing through the upstream exhaust passage portion is a lean air-fuel ratio compared to when it is a stoichiometric air-fuel ratio or rich air-fuel ratio, or the quality of HC desorbed from the HC adsorbent is greater when the air-fuel ratio of the exhaust gas flowing through the upstream exhaust passage portion is a larger lean air-fuel ratio compared to when it is a smaller lean air-fuel ratio.

A control device for an internal combustion engine includes an internal combustion engine and a valve opening-closing timing control device. The valve opening-closing timing control device has a phase adjustment mechanism for setting a relative rotation phase of a driving-side rotator and a driven-side rotator. The phase adjustment mechanism overlaps a timing of opening an intake valve with a timing of opening an exhaust valve, by setting, in a predetermined period, the relative rotation phase such that the exhaust valve closes after a top dead center position has been reached, and a bypass passage is provided that connects an exhaust passage of one cylinder that is in an exhaust process to the exhaust passage of another cylinder that is in an intake process at the same time as the exhaust process.

The present description provides high working capacity adsorbents with low DBL bleed emission performance properties that allows the design of evaporative fuel emission control systems that are lower cost, simpler and more compact than those possible by prior art. Emission control canister systems comprising the adsorbent material demonstrate a relatively high gasoline working capacity, and low emissions.

Subject of the invention is an exhaust gas purification system for a gasoline engine, comprising in consecutive order the following devices:

a first three-way-catalyst (TWC1), a gasoline particulate filter (GPF) and a second three-way-catalyst (TWC2),
wherein the wash coat load (WCL) of the GPF is greater than the WCL of the TWC2, wherein the WCL is determined in g/l of the volume of the device.
The invention also relates to methods in which the system is used and uses of the system.

Provided are an exhaust purification device and an exhaust purification method which can achieve improved fuel efficiency. The exhaust purification device (100) is equipped with: a DOC (5) for occluding hydrocarbons in an exhaust gas; a DPF (6) that is provided downstream from the DOC (5) and is for trapping particulate matter in the exhaust gas; and an ECU (10) for determining, in accordance with the amount of occluded hydrocarbons in the DOC (5), a start time for a regeneration process for removing particulate matter accumulated in the DPF (6).

The invention provides an emission control system for treatment of an exhaust gas stream that includes an oxidation catalyst composition disposed on a substrate in fluid communication with the exhaust gas stream; at least one selective catalytic reduction (SCR) composition disposed on a substrate downstream from the oxidation catalyst composition, and a hydrogen injection article configured to introduce hydrogen into the exhaust gas stream upstream of the oxidation catalyst composition or downstream of the oxidation catalyst composition and upstream of the at least one SCR composition. The invention also provides a method of treating an exhaust gas stream, the method including receiving the exhaust gas stream into the emission control system of the invention and intermittently introducing hydrogen upstream of the oxidation catalyst article or downstream of the oxidation catalyst article and upstream stream of the SCR article.

A catalyst article for treating exhaust gas from a gasoline engine comprising: a substrate comprising an inlet end, an outlet end with an axial length L; a first catalytic region beginning at the inlet end and extending for less than the axial length L, wherein the first catalytic region comprises a first PGM component and a first inorganic oxide; a second catalytic region beginning at the outlet end, wherein the second catalytic region comprises a second PGM component, a second oxygen storage capacity (OSC) material, and a second inorganic oxide; wherein the first catalytic region is substantially free of ceria; and wherein the first PGM component is palladium (Pd), platinum (Pt) or a combination thereof.

Methods and systems for operating an engine with a pump that is driven via the engine are described. In one example, start of opening of an injector that supplies a fluid to an engine exhaust system is timed based on a period of the pump so that the output of the fluid injector may be repeatable in the presence of fluid pressure oscillations that are periodic with pump rotation.