Described are exhaust gas treatment systems for treatment of a gasoline engine exhaust gas stream. The exhaust gas treatment systems comprise an ammonia generating catalyst and an ammonia selective catalytic reduction (SCR) catalyst downstream of the ammonia generating catalyst. The ammonia generating catalyst comprises a NO.sub.x storage component, a refractory metal oxide support, a platinum component, and a palladium component. The ammonia generating catalyst is substantially free of ceria. The platinum and palladium components are present in a platinum to palladium ratio of greater than about 1 to 1.

Provided herein is a catalytic article including a catalytic coating disposed on a substrate, wherein the catalytic coating comprises a bottom coating on the substrate and a top coating layer on the bottom coating layer, one such coating layer containing a platinum group metal on a refractory metal oxide support and the other such coating layer containing a ceria-containing molecular sieve. Such catalytic articles are effective toward treating exhaust gas streams of internal combustion engines and exhibit outstanding resistance to sulfur.

An exhaust aftertreatment system includes a cross-flow selective catalytic reduction catalyst. The cross-flow selective catalytic reduction catalyst includes a housing and a substrate assembly. The substrate assembly includes a plurality of first substrate layers defining a plurality of first flow channels and a plurality of second substrate layers defining a plurality of second flow channels. The exhaust aftertreatment system includes a passive NO.sub.x adsorber. The passive NO.sub.x adsorber includes a housing. The housing includes an inlet in exhaust gas receiving communication with the plurality of first flow channels of the cross-flow selective catalytic reduction catalyst. The housing includes an outlet in exhaust gas providing communication with the plurality of second flow channels of the cross-flow selective catalytic reduction catalyst. The passive NO.sub.x adsorber includes a substrate positioned in the housing. The substrate includes a passive NO.sub.x adsorber washcoat.

An aftertreatment system comprises a housing defining a first and a second internal volume fluidly isolated from each other. A first aftertreatment leg extends from the first to the second internal volume and includes an oxidation catalyst and a filter. The oxidation catalyst receives exhaust gas from an inlet conduit and the filter emits exhaust gas into the second internal volume. A second aftertreatment leg extends from the second to the first internal volume and includes at least one SCR catalyst disposed offset from the first aftertreatment leg. A decomposition tube is disposed offset from the SCR catalyst and the oxidation catalyst. The decomposition tube is configured to receive the exhaust gas from the second internal volume and communicate it to the inlet of the at least one SCR catalyst. A reductant injection inlet is defined proximate to the inlet of the decomposition tube for reductant insertion.

The present disclosure is directed to an emission treatment system for NO.sub.x abatement in an exhaust stream of an ammonia-fueled engine, the emission treatment system including a selective catalytic reduction (SCR) catalyst disposed on a substrate in fluid communication with the exhaust stream, an oxidation catalyst disposed on a substrate positioned either upstream or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, and optionally, one or more adsorption components disposed on a substrate positioned upstream and/or downstream of the SCR catalyst and in fluid communication with the exhaust stream and the SCR catalyst, the adsorption component chosen from low temperature NO.sub.x adsorbers (LT-NA), low temperature ammonia adsorbers (LT-AA), low temperature water vapor adsorbers (LT-WA), and combinations thereof. The disclosure further provides a related method of treatment of an exhaust gas.

An oxidation catalyst for treating an exhaust gas produced by a diesel engine comprises a catalytic region and a substrate, wherein the catalytic region comprises a catalytic material comprising: bismuth (Bi) or an oxide thereof; a Group 8 metal or an oxide thereof; a platinum group metal (PGM) selected from the group consisting of (i) platinum (Pt), (ii) palladium (Pd) and (iii) platinum (Pt) and palladium (Pd); and a support material, which comprises alumina, silica, a mixed oxide of alumina and a refractory oxide, a mixed oxide of silica and a refractory oxide, a composite oxide of alumina and a refractory oxide, a composite oxide of silica and a refractory oxide, alumina doped with a refractory oxide or silica doped with a refractory oxide.

A nitrogen oxide storage material comprising: Mg.sub.1-yAl.sub.2O.sub.4-y, wherein y is a number satisfying 0≤y≤0.2, a noble metal, an oxide of a metal other than the noble metal, and a barium compound, the noble metal, the oxide, and the barium compound being loaded on Mg.sub.1-yAl.sub.2O.sub.4-y. The metal oxide comprises at least one metal oxide selected from zirconium oxide, praseodymium oxide, niobium oxide, and iron oxide.

An exhaust gas treatment system for an internal combustion engine includes an exhaust gas pathway configured to receive exhaust gas from the internal combustion engine, a first treatment element positioned within the exhaust gas pathway, the first treatment element including a selective catalytic reduction (SCR) element, a first injector configured to selectively introduce ammonia gas into the exhaust gas pathway upstream of the first treatment element, a second injector configured to introduce diesel exhaust fluid into the exhaust gas pathway downstream of the first treatment element, and a second treatment element positioned within the exhaust gas pathway downstream of the second injector, the second treatment element including a SCR element.

A method for determining a reference value of a presence of at least one substance (NO.sub.x) occurring in an exhaust gas stream of an internal combustion engine (101), wherein the at least one substance is subjected to exhaust treatment, the exhaust treatment being carried out in dependence on the reference value (Em.sub.ref; Em.sub.ref,1; Em.sub.ref,2) When the internal combustion engine (101) is started: accumulating the occurrence (Em.sub.ACC,1; Em.sub.ACC,2) of the at least one substance (NO.sub.x) downstream from the exhaust treatment during a first period, and determining whether to redetermine the reference value (Em.sub.ref; Em.sub.ref,1; Em.sub.ref,2) based on the accumulated occurrence (Em.sub.ACC,1; Em.sub.ACC,2) of the at least one substance (NO.sub.x).

The present disclosure relates to a gas engine heat pump including: an engine which burns a mixed air of air and fuel; a first charger which compresses the mixed air and supplies to the engine; a first exhaust flow path which is connected to the engine, and through which exhaust gas discharged from the engine flows; and a second charger which is driven by the exhaust gas branched from the first exhaust flow path to a second exhaust flow path, and compresses the exhaust gas discharged from the engine and supplies the compressed exhaust gas to the engine, thereby reducing the emission of nitrogen oxide by recirculating the exhaust gas without additional power consumption.