Methods and systems are provided for a multicomponent aftertreatment device arranged in a vehicle exhaust gas passage. In one example, a system may include an oxygen storage catalyst and an underbody trap catalyst comprising metal modified zeolite, the oxygen storage catalyst arranged upstream of the underbody trap catalyst in an exhaust passage of the vehicle.

Methods and systems are provided for emissions control of a vehicle. In one example, an emissions treatment device includes a porous substrate and a catalytic washcoat disposed thereon, the catalytic washcoat having nickel and no other metal. The porous substrate may be configured to filter particulate matter (PM) exiting the vehicle and the catalytic washcoat may be configured to oxidize at least a portion of the PM. The nickel in the catalytic washcoat may provide additional oxygen storage capacity and increased tolerance to sulfur poisoning of catalytic activity of the catalytic washcoat, further promoting PM oxidation. Moreover, because the catalytic washcoat may increase PM oxidation during passive regeneration events, a total number of active regeneration events may be decreased and fuel economy may be maintained.

The present disclosure provides an exhaust gas purification catalyst having improved durability, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the downstream portion contains Rh fine particles, and wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation a of the particle size of 0.8 nm or less.

The exhaust purification system of an internal combustion engine comprises a catalyst 20 arranged in an exhaust passage and able to store oxygen, and an air-fuel ratio control device configured to control an air-fuel ratio of inflowing exhaust gas flowing into the catalyst. The catalyst has a precious metal and the precious metal has a property of a vapor pressure at a predetermined temperature becoming lower when oxidized. If a temperature of the catalyst is equal to or greater than a threshold temperature or if predicting a rise in temperature of the catalyst, the air-fuel ratio control device is configured to make the air-fuel ratio of the inflowing exhaust gas leaner than a stoichiometric air-fuel ratio so that an oxygen storage amount of the catalyst becomes equal to or greater than an upper side reference amount.

An exhaust purification system of an internal combustion engine is provided with: an exhaust purification catalyst supporting a precious metal and able to store oxygen; and a control device controlling an amount of fuel fed to a combustion chamber. When a predetermined condition for performing a fuel cut operation stands, the control device is configured to perform fuel feed control in which fuel is temporarily fed to the combustion chamber so that the air-fuel ratio of the exhaust gas flowing into the exhaust purification catalyst is a rich air-fuel ratio richer than the stoichiometric air-fuel ratio, then start fuel cut control stopping the feed of fuel to the combustion chamber in the state the internal combustion engine is operating.

An internal combustion engine inducts no air from outside atmosphere and it discharges no gas into outside environment. The engine receives hydrocarbon fuel and oxygen, and its combustion gas consists mostly of carbon dioxide and water vapor. Carbon dioxide is captured, stored and subsequently sequestered by using it with water to create a hydrocarbon fuel that can be supplied back to the engine. In that way, the engine fuel is repeatedly regenerated and reused, and the engine operates in a carbon neutral mode of operation. Some of the combustion gas is used as a diluent gas in the engine. High specific heat and high density of that gas permit operation in high-efficiency overexpanded cycle without an increase in the engine size. Various methods of the engine control and operation are described, including methods to reduce pumping loss. Various modes of in-cylinder diluent gas formation are considered.

An exhaust gas purification apparatus includes a three-way catalyst. The three-way catalyst includes a downstream catalyst layer and an upstream catalyst layer. The downstream catalyst layer is to be provided in an exhaust pipe. The downstream catalyst layer contains a noble metal material containing at least one of Pd, Rh, or Pt, and an OSC material containing at least ceria. The upstream catalyst layer is to be provided in the exhaust pipe closer to an engine than the downstream catalyst layer is. The upstream catalyst layer contains the noble metal material and the OSC material. The upstream catalyst layer contains the ceria at a content less than a content of the ceria in the downstream catalyst layer.

An exhaust gas purification apparatus for an internal combustion engine includes a particulate filter, an air fuel ratio sensor to detect an air fuel ratio of exhaust gas at the downstream side of the filter, and a controller configured to: change an air fuel ratio, determine whether an amount of particulate matter (PM) deposited in an interior of a partition wall of the filter is equal to or smaller than a predetermined amount, and estimate a maximum storable oxygen amount of the catalyst from a change of the air fuel ratio of exhaust gas at the time when the air fuel ratio of the exhaust gas is changed, in cases where the amount of PM deposited in the interior of the partition wall of the filter is equal to or smaller than the predetermined amount.

A method and a control device for regulating a modeled fill level of an exhaust gas component reservoir of a catalytic converter of an internal combustion engine. Regulation of the modeled fill level is accomplished using a system model. An actual maximum storage capacity of the catalytic converter for the exhaust gas component is ascertained during operation of the internal combustion engine and is taken into consideration in regulating the modeled fill level.

A system includes an exhaust aftertreatment system including a particulate filter and a controller. The controller is configured to: receive a particulate filter regeneration event trigger; receive information, the information comprising a temperature regarding the particulate filter; determine the temperature regarding the particulate filter is below a temperature threshold associated with a particulate filter regeneration event; and responsive to determining the temperature regarding the particulate filter is below the temperature threshold, command the engine to operate in a cylinder deactivation mode, whereby at least one cylinder of a plurality of cylinders of the engine is deactivated.