The invention relates to a method for starting an internal combustion engine, the exhaust gas system of which is equipped with an electrically heatable lambda sensor and a catalytic converter with an oxygen reservoir. The combination of method steps according to the invention allows the internal combustion engine to be started with an optimal raw emission reduction directly after a cold start and an optimal pollutant conversion in the warm-up phase. The invention likewise relates to a motor vehicle with an internal combustion engine comprising an exhaust gas system having an electrically heatable lambda sensor and a catalytic converter with an oxygen reservoir, and comprising a controller, wherein the controller is designed to carry out the method according to the invention.

The invention relates to a method for starting an internal combustion engine, the exhaust gas system of which is equipped with an electrically heatable lambda sensor and a catalytic converter with an oxygen reservoir. The combination of method steps according to the invention allows the internal combustion engine to be started with an optimal raw emission reduction directly after a cold start and an optimal pollutant conversion in the warm-up phase. The invention likewise relates to a motor vehicle with an internal combustion engine comprising an exhaust gas system having an electrically heatable lambda sensor and a catalytic converter with an oxygen reservoir, and comprising a controller, wherein the controller is designed to carry out the method according to the invention.

The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.

An exhaust gas purification apparatus for an internal combustion engine includes a filter supporting the catalyst with an oxygen storage capacity, an air fuel ratio sensor to detect an air fuel ratio of exhaust gas at the downstream side of the filter, and a controller configured to change an air fuel ratio of exhaust gas flowing into the filter, to estimate an amount of particulate matter deposited in an interior of a partition wall of the filter, estimate a maximum storable oxygen amount of the catalyst from a change of the air fuel ratio of exhaust gas obtained by the air fuel ratio sensor at the time when the air fuel ratio of exhaust gas is changed by the controller, and correct the maximum storable oxygen amount of the catalyst based on the amount of particulate matter deposited in the interior of the partition wall of the filter.

A method and a control device for regulating a modeled fill level of an exhaust gas component reservoir of a catalytic converter of an internal combustion engine. Regulation of the modeled fill level is accomplished using a system model. An actual maximum storage capacity of the catalytic converter for the exhaust gas component is ascertained during operation of the internal combustion engine and is taken into consideration in regulating the modeled fill level.

An internal combustion engine comprises an exhaust purification catalyst, a downstream side air-fuel ratio sensor which is arranged at a downstream side of the exhaust purification catalyst, and an air flow meter which detects an amount of intake air. The control system of the internal combustion engine controls the exhaust air-fuel ratio to a target air-fuel ratio by feedback control, sets the target air-fuel ratio at a lean air-fuel ratio when the output air-fuel ratio of the downstream side air-fuel ratio sensor becomes a rich air-fuel ratio, and sets the target air-fuel ratio at a rich air-fuel ratio when the output air-fuel ratio of the downstream side air-fuel ratio sensor becomes a lean air-fuel ratio. When a change in the amount of intake air occurs so that it increases, the lean degree is set lower than before, in at least part of the time period during which the target air-fuel ratio is set to the lean air-fuel ratio, and the rich degree is set lower than before, in at least part of the timer period during which the target air-fuel ratio is set to the rich air-fuel ratio.

A catalyst oxygen purge control method may include a catalyst oxygen purge control method during a cold engine period of a catalyst oxygen purge control apparatus which includes a three way catalytic converter through which an exhaust gas combusted when air and fuel are mixed in a combustion chamber is exhausted and the exhaust gas passes, wherein the method includes determining whether a fuel cut condition of an injector which injects the fuel to the combustion chamber is satisfied, performing fuel cut of the injector when the fuel cut condition is satisfied, measuring an oxygen storage capacity of the three way catalyst, and adjusting an oxygen purge time based on the measured oxygen storage capacity.

Methods and systems are provided for an exhaust aftertreatment arrangement. In one example, a system includes a LNT upstream of an SCR with an oxygen storage component arranged therebetween, and where a rich operation of an engine is limited based on an oxygen load of the oxygen storage component when an exhaust gas temperature is higher than a limit temperature.

An exhaust purification system of an internal combustion engine includes a catalyst arranged in an exhaust passage of the internal combustion engine and able to store oxygen, a storage amount calculating part configured to calculate an oxygen storage amount of the catalyst, a poisoning amount calculating part configured to calculate a poisoning amount of the catalyst, and an oxygen amount control part configured to control an amount of oxygen supplied to the catalyst based on the oxygen storage amount and the poisoning amount.

A control device for an internal combustion engine performs feedback control so that the air-fuel ratio of the exhaust gas flowing into an exhaust purification catalyst becomes a target air-fuel ratio and switches the target air-fuel ratio to lean when an output air-fuel ratio of a downstream side air-fuel ratio sensor is judged rich and switches the target air-fuel ratio to rich when an output air-fuel ratio of the downstream side air-fuel ratio sensor is judged lean. The control device judges that the downstream side air-fuel ratio sensor has not become abnormal when the value of the excess/deficiency parameter from when switching the target air-fuel ratio to lean or rich to when the output air-fuel ratio of the downstream side air-fuel ratio sensor is judged rich or lean is larger than a predetermined limit value.