Patent classifications
F01N3/106
CATALYST FOR SIMULTANEOUSLY INHIBITING EMISSION OF AMMONIA AND NITROUS OXIDE
An object of the present invention is to increase the reduction performance of nitrogen oxides compared to existing three-way catalysts; simultaneously inhibit the emission of ammonia and nitrous oxide; simplify a process by means of a method of further doping an iridium-ruthenium catalyst into a commercial three-way catalyst; and expand the scope of application. The present invention provides a catalyst for simultaneously inhibiting the emission of ammonia and nitrous oxide by doping an iridium-ruthenium catalyst component into a three-way catalyst (TWC), a diesel oxidation catalyst, or a lean NOx trap supported on a honeycomb support.
SYSTEMS AND METHODS FOR REACTIVE REGENERATION OF SELECTIVE CATALYTIC REDUCTION CATALYSTS
A controller for controlling regeneration of a selective catalytic reduction (SCR) catalyst of an aftertreatment system is configured to cause increase in a SCR catalyst temperature of the SCR catalyst to a first regeneration temperature, the first regeneration temperature being lower than a high regeneration temperature that is equal to or greater than 500 degrees Celsius. The controller is configured to determine an amount of ammonia slip downstream of the SCR catalyst; and cause an increase in the SCR catalyst temperature to a second regeneration temperature greater than the first regeneration temperature but lower than the high regeneration temperature based on the determined amount of ammonia slip.
EXHAUST AFTERTREATMENT UNIT FOR CLEANING EXHAUST GASES
An exhaust aftertreatment unit for cleaning exhaust gases includes an emission reducing module being a diesel particulate filter, DPF, and/or a diesel oxidation catalyst, DOC, a selective catalyst reduction, SCR, catalyst, an electrical heating element arranged upstream of the emission reducing module, a casing housing at least the emission reducing module and the electrical heating element, and a service lid removably arranged to cover a service opening of the casing through which the emission reducing module may be accessed. The electrical heating element is removably arranged relative the casing and is arranged accessible upon removal of the service lid and the emission reducing module.
CONTROLLER AND METHOD FOR CONTROLLING OPERATION OF AN AFTERTREATMENT SYSTEM BASED ON SHORT-TERM AND LONG-TERM CUMULATIVE DEGRADATION ESTIMATES
A controller for controlling operation of an aftertreatment system that is configured to treat constituents of an exhaust gas produced by an engine, the aftertreatment system including a selective catalytic reduction (SCR) catalyst, the controller configured to: generate a short-term cumulative degradation estimate of the SCR catalyst corresponding to reversible degradation of the SCR catalyst due to sulfur and/or hydrocarbons based on a SCR catalyst temperature parameter; generate a long-term cumulative degradation estimate of the SCR catalyst corresponding to thermal aging of the SCR catalyst based on the SCR catalyst temperature parameter; generate a combined degradation estimate of the SCR catalyst based on the short-term cumulative degradation estimate and the long-term cumulative degradation estimate; and adjust an amount of reductant and/or an amount of hydrocarbons inserted into the aftertreatment system based on the combined degradation estimate of the SCR catalyst.
Method for controlling an exhaust flow in an Exhaust Aftertreatment System (EATS) of a vehicle
A method for controlling exhaust flow in an EATS of a vehicle. A NO.sub.x sensor output parameter is monitored. It is determined that the NO.sub.x sensor output parameter is below a limit. When the NO.sub.x sensor output parameter is below the limit, it is determined that a first part of the exhaust flow should bypass at least a first area of the SCR unit and that a second part of the exhaust flow should be inputted to at least the first area of the SCR unit. It is initiated that the first part is bypassed and that the second part is inputted to at least the first area of the SCR unit. An amount of reductant that should be added to the second part of the exhaust flow is determined. Addition of the amount of reductant is initiated.
SYSTEMS AND METHODS FOR DIAGNOSING NOx SENSOR BASED ON AMMONIA SLIP
A method for diagnosing a NOx sensor is provided. The method includes receiving data indicative of operating conditions of an engine or an aftertreatment system; determining, during a first period of time, that an amount of NOx output from the aftertreatment system satisfies a low NOx operating mode condition; determining, during a second period of time, that operating conditions for ammonia slip are present based on data regarding operation of the aftertreatment system; responsive to the determination that operating conditions for ammonia slip are present, determining that the amount of NOx output from the aftertreatment system satisfies a high NOx operating mode condition; comparing a difference between a minimum value from the first period of time and a maximum value from a second period of time to a diagnostic threshold; and responsive to the difference being less than the diagnostic threshold, setting an alert.
COMPOSITE, ZONE-COATED, DUAL-USE AMMONIA (AMOX) AND NITRIC OXIDE OXIDATION CATALYST
A composite, zone-coated, dual-use ammonia (AMOX) and nitric oxide oxidation catalyst (12) comprises: a substrate (5) having a total length L and a longitudinal axis and having a substrate surface extending axially between a first substrate end (I) and a second substrate end (O); two or more catalyst washcoat zones (1; 2) comprised of a first catalyst washcoat layer (9) comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon and a second catalyst washcoat layer (11) different from the first catalyst washcoat layer (9) and comprising a refractory metal oxide support material and one or more platinum group metal components supported thereon, which two or more catalyst washcoat zones (1; 2) being arranged axially in series on and along the substrate surface, wherein a first catalyst washcoat zone (1) having a length L.sub.1, wherein L.sub.1<L, is defined at one end by the first substrate end (I) and at a second end (13) by a first end (15) of a second catalyst washcoat zone (2) having a length L.sub.2, wherein L.sub.2<L, wherein the first catalyst washcoat zone (1) comprises a first refractory metal oxide support material and one or more platinum group metal components supported thereon; and the second catalyst washcoat zone comprises a second refractory metal oxide support material and one or more platinum group metal components supported thereon; and a washcoat overlayer (G) extending axially from the first substrate end for up to 200% of the axial length of the underlying first catalyst washcoat layer, which washcoat overlayer comprising a particulate metal oxide loading of >48.8 g/l (>0.8 g/in.sup.3), wherein the particulate metal oxide is an aluminosilicate zeolite including at least one of copper, iron and manganese, wherein a total platinum group metal loading in the first catalyst washcoat zone (1) defined in grams of platinum group metal per litre of substrate volume (g/l) is different from the total platinum group metal loading in the second catalyst washcoat zone (2).
Selective catalytic reduction catalyst on a filter substrate
A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.
Systems and methods for mixing exhaust gases and reductant in an aftertreatment system
A multi-stage mixer includes a multi-stage mixer inlet, a multi-stage mixer outlet, a first flow device, and a second flow device. The multi-stage mixer inlet is configured to receive exhaust gas. The multi-stage mixer outlet is configured to provide the exhaust gas to a catalyst. The first flow device is configured to receive the exhaust gas from the multi-stage mixer inlet and to receive reductant such that the reductant is partially mixed with the exhaust gas within the first flow device. The first flow device includes a plurality of main vanes and a plurality of main vane apertures. The plurality of main vane apertures is interspaced between the plurality of main vanes. The plurality of main vane apertures is configured to receive the exhaust gas and to cooperate with the plurality of main vanes to provide the exhaust gas from the first flow device with a swirl flow.
Method and system for determining internal temperature of a mid-brick catalyst for machine control
Systems and methods for controlling a regeneration process of catalyst(s) are disclosed. The method includes receiving, via Kalman filter, initial estimation from a previous instance of time. The initial estimation includes one or more first estimated inside temperature(s) and/or first estimated outlet temperature of A/T catalyst. An output from a simulation model may be generated to calculate a mean and covariance. Sensor measurement covariance may be compared against the mean and covariance of the output to update Kalman filter gain and process covariance. A weighted average may be calculated between sensor measurements and mean of the output to generate a second estimation for the next instance of time, wherein weight is based on Kalman filter gain. The second estimation includes one or more second estimated inside temperature(s) and/or second estimated outlet temperature of A/T catalyst to control the mass flow rate in diesel engine via a closed loop control system.