An exhaust gas treatment system for an internal combustion engine includes an exhaust gas pathway configured to receive exhaust gas from the internal combustion engine, a first treatment element positioned within the exhaust gas pathway, a first injector configured to introduce a first reductant into the exhaust gas pathway upstream of the first treatment element, a second injector configured to introduce a second reductant into the exhaust gas pathway downstream of the first treatment element, a second treatment element positioned within the exhaust gas pathway downstream of the second injector, the second treatment element including a SCR element, and a controller configured to periodically initiate a desulfuring regeneration cycle by increasing a concentration of hydrocarbons in the exhaust gas and increasing the flow of the first reductant through the first injector to oxidize sulfur contamination in the first treatment element at temperatures between 400 and 500 degrees Celsius.

An oxidation catalyst device is placed so that a central axis of the oxidation catalyst device may be oriented along a right and left direction of a work vehicle; a reducing agent injection device is placed so that a central axis of the reducing agent injection device may be oriented along a front and rear direction of the work vehicle; and a selective catalytic reduction device is placed so that a central axis of the selective catalytic reduction device may be oriented along the front and rear direction of the work vehicle, in which the oxidation catalyst device, the reducing agent injection device, and the selective catalytic reduction device are arranged so as to have a relationship that the central axes thereof become the same in height, and the central axis of the selective catalytic reduction device is placed so as to pass through the oxidation catalyst device.

An exhaust gas treatment system for an internal combustion engine includes an exhaust gas pathway configured to receive exhaust gas from the internal combustion engine, a first treatment element positioned within the exhaust gas pathway, a first injector configured to introduce a first reductant into the exhaust gas pathway upstream of the first treatment element, a second injector configured to introduce a second reductant into the exhaust gas pathway downstream of the first treatment element, a second treatment element positioned within the exhaust gas pathway downstream of the second injector, the second treatment element including a SCR element, and a controller configured to periodically initiate a desulfuring regeneration cycle by increasing a concentration of hydrocarbons in the exhaust gas and increasing the flow of the first reductant through the first injector to oxidize sulfur contamination in the first treatment element at temperatures between 400 and 500 degrees Celsius.

This catalyst system simultaneously removes ammonia and enhances net NOx conversion by placing an NH.sub.3-SCR catalyst formulation downstream of a lean NOx trap. By doing so, the NH.sub.3-SCR catalyst adsorbs the ammonia from the upstream lean NOx trap generated during the rich pulses. The stored ammonia then reacts with the NOx emitted from the upstream lean NOx trap-enhancing the net NOx conversion rate significantly, while depleting the stored ammonia. By combining the lean NOx trap with the NH.sub.3-SCR catalyst, the system allows for the reduction or elimination of NH.sub.3 and NOx slip, reduction in NOx spikes and thus an improved net NOx conversion during lean and rich operation.

There is provided an exhaust gas purification system that allows efficient purification of NOx present in exhaust gas emitted from an internal combustion engine. The exhaust gas purification system of the disclosure comprises a first exhaust gas purification device that purifies exhaust gas emitted from an internal combustion engine, wherein the atmosphere alternately switches between a reducing agent-excess atmosphere and an oxidizing agent-excess atmosphere with respect to the stoichiometric atmosphere, and a second exhaust gas purification device that further purifies the exhaust gas that has been purified by the first exhaust gas purification device, wherein the first exhaust gas purification device has a three-way catalyst, and the second exhaust gas purification device has an exhaust gas purifying catalyst that comprises an AMn.sub.2O.sub.4 spinel-type oxide support (A=Mg, Zn or Li) on which a precious metal is supported.

Constraints on arrangement of catalysts are reduced, and early activation and long-term performance maintenance of the catalysts are both achieved. An exhaust pipe includes a first catalyst provided in a first exhaust pipe extending upward on the side of an exhaust manifold, and a second catalyst provided in a second exhaust pipe that extends downward from a bent pipe extending from the first exhaust pipe and that is adjacent to the first exhaust pipe. The second catalyst is disposed at a position offset to a higher location from an up-down middle position of the first exhaust pipe.

An energy recovery converter for exhaust gases or waste heat is provided. The converter includes a membrane electrode assembly (MEA), an exhaust gas having a first molecular oxygen content, and an external electrical load. The MEA includes a first electrode, a second electrode and an oxygen ion conductive membrane sandwiched between the first and second electrodes. Each of the first and second electrodes includes at least one oxidation catalyst configured to promote an electrochemical reaction. The second electrode of the MEA is exposed to the exhaust gas and the first electrode of the MEA is exposed to a gas having a second molecular oxygen content. The second molecular oxygen content is higher than the first molecular oxygen content. The external electrical load is connected between the first and second electrodes of the MEA.

An exhaust gas purification including: a base of wall flow structure having inlet side cells wherein an end on the exhaust gas inflow side is open and outlet side cells wherein an end on the exhaust gas outflow side is open, and a porous partition wall that partitions the side cells; and first and second catalyst layers disposed in the interior of the porous partition wall so as to be in contact with the side cells, wherein either of the catalyst layers contains an oxidation catalyst but does not contain a reduction catalyst, and the other contains the reduction catalyst but does not contain the oxidation catalyst; and a ratio of the lengths of the catalyst layers differs between a surface of the porous partition wall on the side in contact with the inlet side cells and a surface on the side in contact with the outlet side cells.

The present disclosure describes methods for evaluating NOx conversion efficiency of a close coupled SCR unit of an EAS including the close coupled SCR unit and a downstream SCR unit. The determined NOx conversion efficiency of the close coupled SCR unit is used to diagnose the close coupled SCR unit and or EAS and to control operation parameters of the EAS and/or internal combustion engine operably connected to the EAS.

An exhaust gas treatment system for an internal combustion engine includes an exhaust gas pathway configured to receive exhaust gas from the internal combustion engine, a first injector configured to selectively introduce a first reductant into the exhaust gas pathway in response to a sensed temperature of the exhaust gas being within a predetermined temperature range, and a first treatment element positioned within the exhaust gas pathway downstream of the first injector. The first treatment element includes a selective catalytic reduction (SCR) layer, a porous filter substrate, and a precious metal catalyst layer. The system also includes a second injector configured to introduce a second reductant into the exhaust gas pathway downstream of the first treatment element and a second treatment element positioned within the exhaust gas pathway downstream of the second injector. The second treatment element includes a SCR element.