A method of operation of a thermal power plant having an air separation system with a plurality of air storage unit (ASU) compressors and a liquid oxygen/liquid air (LOX/LA) storage facility for oxyfuel firing of fossil fuel and a power plant having a control system to perform the same are described. The method is characterized by the step of controlling the net power output of the plant in response to short term variations in grid demanded net plant output by dynamically adjusting the works power of the ASU compressors preferably in conjunction with co-ordinated changes in firing demand. The method is in particular a method to produce an improved primary and secondary response to transient changes in grid demand and to provide accurate response to load dispatch ramps.

A method for obtaining one or more air products, wherein an air separation system having a rectification column system is used, in which pressurized air is processed in an adjustable total air volume, wherein the total air volume is set to a first value during a first operating period and set to a second value that is different from the first value during a second operating period, and wherein the setting of the total air volume is changed from the first value to the second value in a third operating period from a first time to a second time. The second operating period is after the first operating period, the third operating period is between the first operating period and the second operating period. In the third operating period, a setting of a volume of a fluid, is changed from a third time up to a fourth time.

A method for producing an air product in an air separation plant. Feed air is cooled at least in a main air compressor and is fed into a distillation column system. A fluid storage unit and a cold accumulator are used. In a first operating mode, fluid is stored in the fluid storage unit and the cold accumulator is heated. In a third operating mode, fluid is released and the cold accumulator is cooled, and in a second operating mode, fluid is neither stored nor released.

An air product is produced in an air separation plant having a heat exchanger, an expansion/compression unit, a rectification unit, liquid storage, cold storage and an air compressor. The air supplied to the rectification unit is conducted through the main air compressor at a pressure level at least 3 bar above the highest operation pressure for the rectification unit. Cryogenic liquids are produced in a first production amount by a first operating mode, a lower second production amount by a second operating mode and a higher third production amount by a third operating mode. Cryogenic liquid is stored in the liquid storage in the third operating mode and removed from storage in the second operating mode. Cryogenic liquid is evaporated in different amounts in each operating mode, which amounts differ by no more than 10%.

Process and apparatus for producing pressurized gaseous nitrogen by cryogenic separation of air. The distillation column system includes a high pressure column, a medium pressure column, a main condenser and top condenser both being condenser-evaporators. Compressed and purified feed air is cooled in a heat exchanger and introduced to the distillation system. A gaseous nitrogen stream from the high pressure column is condensed in the main condenser. Bottom liquid of the medium pressure column is evaporated and gaseous nitrogen from the medium pressure column is condensed in the top condenser. Liquid nitrogen from the medium pressure column is pressurized and introduced to the high pressure column. A second gaseous nitrogen stream from the high pressure column is recovered as pressurized gaseous nitrogen product. A portion of the compressed and purified feed air is work-expanded and then warmed in the main heat exchanger.

A method for obtaining an air product from an air separation plant having a distillation column system and a tank system. The tank system includes a first tank and a second tank. Cryogenic liquid is withdrawn from the distillation column system, stored in the tank system, and used as the air product. The cryogenic liquid is supplied to the first tank and withdrawn from the second tank during a first period, and is supplied to the second tank and withdrawn from the first tank during a second period. The tank system has a third tank to which cryogenic liquid withdrawn from the first tank and the second tank is transferred unheated. The air product is withdrawn from the third tank in liquid state, vaporized and discharged. Alternatively, the cryogenic liquid can be withdrawn from the third tank and stored in the liquid state in a fourth tank.

A nitrogen liquefier configured to be integrated with an argon and nitrogen producing cryogenic air separation unit and method of nitrogen liquefaction are provided. The integrated nitrogen liquefier and associated methods may be operated in at least three distinct modes including: (i) a nil liquid nitrogen mode; (ii) a low liquid nitrogen mode; and (iii) a high liquid nitrogen mode. The present systems and methods are further characterized in an oxygen enriched stream from the lower pressure column of the air separation unit is an oxygen enriched condensing medium used in the argon condenser.

The invention relates to a cryogenic distillation apparatus for a gas mixture, including a purification apparatus for purifying a gas mixture in a system with a plurality of adsorbant bottles, a column system, a capacity, means for feeding a cryogenic liquid to the capacity, means for feeding a vaporized liquid from the capacity to a column of the system, a vaporizer in the capacity for vaporizing the contained liquid; means for feeding a calorigenic gas to the vaporizer, and means for drawing a liquid from the capacity.

The disclosure pertains to a plant for the production of ammonia. The ammonia is produced from hydrogen obtained by electrolysis of water. The electrolysis is powered by a renewable source of energy, complemented with power obtained from the plant during periods of low or no availability of the renewable energy. To this end, the plant is configured such that it can be operated in a charge configuration (obtaining and storing power) and a discharge configuration (employing said power).

A method for providing a nitrogen product, an oxygen product and a hydrogen product, wherein an air separation installation is used which is designed for the low-temperature separation of feed air and which has a rectification column system, the rectification column system comprising an air-fed rectification column and a main heat exchanger. The provision of the nitrogen product comprises, in particular, subjecting feed air to low-temperature rectification using the air-fed rectification column such that a tops gas is obtained, and using part of the tops gas as the nitrogen product. The provision of the oxygen product and the hydrogen product comprises subjecting water to water electrolysis in an electrolyzer, such that a water-containing oxygen stream and a hydrogen stream are obtained, the water-containing oxygen stream or part thereof being subjected, at least in one operating phase, to drying and, in an unmixed state, to liquefaction in the air separation installation.