The presently claimed invention provides a layered catalytic article comprising a first layer comprising a nickel component and a ceria component, wherein the amount of the nickel component is 1.0 to 50 wt. %, calculated as nickel oxide, based on the total weight of the first layer, and wherein the first layer is essentially free of copper; a second layer comprising a platinum group metal component, an oxygen storage component, and an alumina component, wherein the platinum group metal component comprises platinum, rhodium, palladium, or any combination thereof, and wherein the amount of the platinum group metal component is 0.0 to 5 wt. %. based on the total weight of the second layer; and a substrate. The presently claimed invention also provides a process for preparing the layered catalytic article. It further provides an exhaust system for internal combustion engines comprising a layered catalytic article.

A device for treating exhaust gases of an internal combustion engine includes: a heating disk arranged in a housing; and a main catalytic converter arranged downstream of the heating disk in the flow direction in the housing. The flow can pass through the heating disk and the main catalytic converter in the flow direction along a plurality of flow channels. The heating disk is formed from a metallic honeycomb body and the main catalytic converter is formed from a ceramic honeycomb body fixed in relation to the housing by a fixing structure. The heating disk is electrically contacted by an electrical feedthrough guided through the housing from the outside to the inside.

A heating device includes a heating element in the form of a metal foam, and a case defined by a side wall that extends along a longitudinal axis. The metal foam is housed in the case. An electrical thermal insulator is arranged between the metal foam and the case. The heating device includes at least one electrode and the metal foam includes a zone configured to receive the at least one electrode.

An oxygen storage material (OSM) includes a zinc manganese iron oxide (ZMF) and an alkali metal base on the ZMF surface. The ZMF has a spinel structure. The alkali metal containing ZMF can be formed to have a weight percent of alkali metal up to about two percent. The alkali metal carbonate is retained on the ZMF surface upon heating to a temperature greater than 1,000° C. and stabilizes the ZMF to the cycling of an oxygen rich and oxygen lean atmosphere. The OSM additionally catalyzes the oxidation of hydrocarbons and CO and catalyzes the reduction of NO.sub.x for use in catalytic converters.

Bimetallic three-way catalyst devices include a support body, one or more Rh bulk deposits disposed on the support body, and a plurality of Pt atomic clusters disposed on the surface of each of the Rh bulk deposits. Substantially no Pt is deposited on the support body. At least 85% by weight of the Pt atomic clusters comprise up to 10 atoms and the maximum Pt atomic cluster size is 200 Pt atoms. The combined loading of Rh and Pt can be less than 1.5% by weight relative to the weight of the support body. The molar ratio of Rh in a bulk Rh deposit to Pt disposed on the surface of that deposit is at least 5:1.

An oxygen storage material (OSM) includes a zinc manganese iron oxide (ZMF) and an alkali metal base on the ZMF surface. The ZMF has a spinel structure. The alkali metal containing ZMF can be formed to have a weight percent of alkali metal up to about two percent. The alkali metal carbonate is retained on the ZMF surface upon heating to a temperature greater than 1,000° C. and stabilizes the ZMF to the cycling of an oxygen rich and oxygen lean atmosphere. The OSM additionally catalyzes the oxidation of hydrocarbons and CO and catalyzes the reduction of NO.sub.x for use in catalytic converters.

Described herein are catalytic converter substrates or cores based on triply periodic minimal surfaces (TPMS) geometries, along with methods of making and using the same.

A catalyst substrate may include a ceramic base body including first and second ends, the second end being opposite to the first end, and the ceramic base body being provided with a plurality of cells each extending between the first and second ends; and a plurality of metal particles or metal fragments introduced into one or more internal spaces of one or more selected cells in the plurality of cells. Each of the plurality of metal particles or metal fragments has a size equal to or less than an opening width of the cell. The plurality of metal particles or metal fragments is configured to generate heat in accordance with varying magnetic field.

Provided is a catalyst device that makes it possible to efficiently purify exhaust gas. A catalyst device that comprises: a carrier that is formed by stacking and rolling a metal-foil-shaped flat plate and a metal-foil-shaped corrugated plate and that carries a catalyst; and an outer cylinder that houses the carrier and supports the carrier such that one end part of the carrier is oriented toward an exhaust gas upstream side and another end part of the carrier is oriented toward an exhaust gas downstream side. The flat plate and the corrugated plate have a plurality of holes and are covered by a coating film that includes a catalyst substance. The coating film that covers the downstream side of the holes is thicker than the coating film that covers the upstream side of the holes.

An exhaust gas purification device includes a substrate including an upstream end and a downstream end, the substrate having a length Ls between the upstream end and the downstream end; a first catalyst layer containing first catalyst particles, extending across a first region, and being in contact with the substrate, the first region extending between the upstream end and a first position, the first position being at a first distance La from the upstream end toward the downstream end; and a second catalyst layer containing second catalyst particles, extending across a second region, and being in contact with the substrate, the second region extending between the downstream end and a second position, the second position being at a second distance Lb from the downstream end toward the upstream end. The first catalyst layer has an inner surface defining macropores.