A non-contact, non-immersive method and apparatus are provided for accurately measuring quantitatively one or more elements in liquid metal or alloy samples using laser-induced breakdown spectroscopy (LIBS). The method is particularly useful for process and/or quality control within the metallurgy industry for accurately and very quickly measuring minor component or impurity elements in liquid metal in the production process, without touching the liquid metal and without the need for cooling and solidifying samples for analysis. In the method and apparatus a pre-determined distance is dynamically maintained between emission receiving optics and the surface of a liquid sample being analysed and the instrument does not come in contact with the liquid metal surface. Liquid samples are heated and/or maintained at a desired temperature. For many elements, values for limit-of-detection, measurement repeatability and accuracy about or below 1 ppm are achieved using this method.

A device for measuring a temperature of a molten metal bath, comprising: an optical cored wire; a tube, wherein the optical cored wire is at least partly arranged in the tube, wherein the tube has an outer diameter in the range of 4 mm to 8 mm, and a wall-thickness in the range of 0.2 mm to 0.5 mm; and a plurality of separating elements comprising more than two separating elements arranged in the tube spaced apart from each other, and forming at least one compartment between two of the more than two separating elements.

The invention also relates to a system and method for measuring a temperature of a molten metal bath.

A potentiometric oxygen sensor for measuring the oxygen concentration of a liquid metal, including: a metal tube forming at least one sensor body part; an electrochemical subassembly containing an electrolyte, intended to be in contact with the liquid metal, and a reference electrode contained in the electrolyte, the electrolyte being made of yttrium-doped or calcium-doped hafnia (HfO.sub.2), or of thoria (ThO.sub.2), which is optionally yttrium-doped or calcium-doped, or of yttrium-doped or calcium-doped zirconia (ZrO.sub.2), the reference electrode containing at least one metal and its oxide form at the operating temperature of the sensor, an insert made of a transition metal from group 4 of the Periodic Table or an alloy thereof, arranged between the sensor body part and the electrolyte, the insert being attached to the sensor body part and brazed onto the electrolyte by a brazing joint.

A potentiometric oxygen sensor for measuring the oxygen concentration of a liquid metal, including: a metal tube forming at least one sensor body part; an electrochemical subassembly containing an electrolyte, intended to be in contact with the liquid metal, and a reference electrode contained in the electrolyte, the electrolyte being made of yttrium-doped or calcium-doped hafnia (HfO.sub.2), or of thoria (ThO.sub.2), which is optionally yttrium-doped or calcium-doped, or of yttrium-doped or calcium-doped zirconia (ZrO.sub.2), the reference electrode containing at least one metal and its oxide form at the operating temperature of the sensor, an insert made of a transition metal from group 4 of the Periodic Table or an alloy thereof, arranged between the sensor body part and the electrolyte, the insert being attached to the sensor body part and brazed onto the electrolyte by a brazing joint.

The present disclosure belongs to the technical field of casting equipment, and provides a method and system for adjusting process parameters of a die-casting machine, and a storage medium. The method and the system can receive die wheel type, molten aluminum temperature, interruption time and defect information in real time, respond to the above information one by one according to a set response priority order, select die-casting process parameters, and automatically adjust different process parameters for different products and different working conditions, thereby realizing simultaneous control of multiple die-casting machines, replacing manual adjustment and improving product quality stability and production efficiency.

A device for characterising at least one liquid material includes an analysis head and a rotating mechanical mixer. The mixer includes a central part having an internal cavity which forms an analysis chamber, a first end connected to the analysis head, and a plurality of stirring blades which are connected to a second end that is hollow so as to ensure fluid communication between the internal cavity and the liquid bath. The mechanical stirring blades are intended to be totally submerged, the central part comprises one or more openings intended to be partially submerged, and each mechanical stirring blade comprises at least one stirring flange oriented at a non-zero angle of orientation.

A device for characterising at least one liquid material includes an analysis head and a rotating mechanical mixer. The mixer includes a central part having an internal cavity which forms an analysis chamber, a first end connected to the analysis head, and a plurality of stirring blades which are connected to a second end that is hollow so as to ensure fluid communication between the internal cavity and the liquid bath. The mechanical stirring blades are intended to be totally submerged, the central part comprises one or more openings intended to be partially submerged, and each mechanical stirring blade comprises at least one stirring flange oriented at a non-zero angle of orientation.

Disclosed is a method and system for adjusting process parameters of a die-casting machine, and a storage medium. The method and the system can receive die wheel type, molten aluminum temperature, interruption time and defect information in real time, respond to the above information one by one according to a set response priority order, select die-casting process parameters, and automatically adjust different process parameters for different products and different working conditions, thereby realizing simultaneous control of multiple die-casting machines, replacing manual adjustment and improving product quality stability and production efficiency.

A casting solidification analysis method, which can analyze positions of shrinkage cavities more accurately than in the past, a casting method using the above method, and an electronic program are provided. A following casting solidification analysis method is provided. An amount of expansion/shrinkage for each solidification step length separated by inflection points in a cooling curve is determined, by setting a solid phase ratio at a completion of pouring to 0, setting a solid phase ratio at an end of solidification to 1.0, and determining the expansion/shrinkage amount for the each solidification step length by proportionally distributing the each solidification step length to the total solid phase ratio length.

A casting solidification analysis method, which can analyze positions of shrinkage cavities more accurately than in the past, a casting method using the above method, and an electronic program are provided. A following casting solidification analysis method is provided. An amount of expansion/shrinkage for each solidification step length separated by inflection points in a cooling curve is determined, by setting a solid phase ratio at a completion of pouring to 0, setting a solid phase ratio at an end of solidification to 1.0, and determining the expansion/shrinkage amount for the each solidification step length by proportionally distributing the each solidification step length to the total solid phase ratio length.