The present invention relates to a method for detecting the presence of gas hydrates and/or ice in a medium. The method comprises at least the following steps: measuring at least at one measurement point in said medium two characteristic values of Raman spectra corresponding to two distinct vibration modes of the OH bonds of water, and determining the ratio of said two characteristic values, determining the temperature T in said medium at said measurement point of said spectra, comparing ratio with a value .sub.0 corresponding to a predetermined threshold of formation of said crystals for said temperature T, and determining the presence or not of hydrate and/or ice crystals from said comparison.

A method includes providing a length of pipeline that has a housing defining a central bore extending the length of the pipe and a space formed within the housing and extending the length of the pipe. At least one condition within the space is continuously monitored within the space to detect in real time if a change in the housing occurs.

Presented herein are systems and methods directed to a multispectral absorption-based imaging approach that provides for rapid and accurate detection, localization, and quantification of gas leaks. The imaging technology described herein utilizes a scanning optical sensor in combination with structured and scannable illumination to detect and image spectral signatures produced by absorption of light by leaking gas in a quantitative manner over wide areas, at distance, and in the presence of background such as ambient gas and vapor. Moreover, the specifically structured and scannable illumination source of the systems and methods described herein provides a consistent source of illumination for the scanning optical sensor, allowing imaging to be performed even in the absence of sufficient natural light, such as sunlight. The imaging approaches described herein can, accordingly, be used for a variety of gas leak detection, emissions monitoring, and safety applications.

A system comprising a parts-per-million (PPM) analyzer configured to analyze a multiphase fluid, the fluid comprising water. The analyzer includes a mesh comprising first adsorbent materials that adsorb specific substances from the multiphase fluid. The system includes a mass meter configured to measure a mass of multiphase fluid passing through the PPM analyzer; a molecular sieve dryer comprising second adsorbent material configured to adsorb the water from the multiphase fluid; and a plurality of valves configured to couple the mass meter and the molecular sieve dryer to the PPM analyzer. During routine operation, the valves direct the multiphase fluid through the PPM analyzer. During a validation operation, the valves divert the multiphase fluid through the molecular sieve dryer prior to entering the PPM analyzer.

The invention discloses a gas hydrate pressure maintaining replacement device and method for in-situ Raman analysis. Comprehensive experiments such as the formation/decomposition/displacement of high-pressure gas hydrates can be realized, and in-situ Raman characterization can be performed. Including reaction kettle system with temperature control unit, pressure control gas supply system, pressure holding system, replacement gas system, sample pre-cooling system, vacuum system and data acquisition and processing system. The device can solve the problem that the Raman peak position of the 512 cage is covered by the Raman peak position of the gas when the high-pressure gas hydrate is characterized in situ in the reaction kettle, at the same time, it solves the problems of sampling difficulties in ex-situ Raman characterization and experimental errors caused by sample transfer.

An improved liquefied natural gas vaporization system is provided for converting liquefied natural gas (LNG) to vapor so that it can be measured for integrity. The liquefied natural gas vaporization system of the present invention makes use of a sample probe that uses a cryogenic check valve to allow the vaporization process to begin early, and, due to design and incorporation with heated regulation, reduces the need for an accumulator, which is often used in other systems. By eliminating the need for an accumulator, a more real-time and authentic measurement of the LNG sample may be taken. After the probe takes the sample, the sample is sent to a sampling system and subsequently to an analytical measuring system, where the sample is measured.

A single-wavelength light source is configured to generate an excitation light source. A sample holder that defines an inner cavity is capable of holding a sample and includes a surface transparent to the excitation light source. One or more mounts are attached to at least one of the light source or the sample holder. The mounts are configured to change an incident angle of the excitation light source on the surface. One or more optical components are positioned in a path of a fluorescence emission emitted from the surface and guide the fluorescence emission to a detector. A detector detects an intensity of the fluorescence emission.

A method and a device monitors the quality of gaseous media dispensed by a filling station, in particular hydrogen, by an infrared measuring system. The infrared measuring system is connected into the dispensing path of the respective gaseous medium extending from the filling station to a consumer, and measures the transmission of infrared radiation at different wavelengths and different pressures. From the transmission measurements, the concentration of contaminants, which influence the quality, is calculated. At least when predetrminable quality parameters are exceeded, this exceeding is indicated.

A method for monitoring air quality is described. The method includes measuring ethane and methane using a mobile sensor platform to provide sensor data. The sensor data includes methane data and ethane data captured at a nonzero mobile sensor platform speed. Methane and ethane peak(s) are identified in the sensor data. Correlation(s) between the methane and ethane peak(s) and/or between the methane peak(s) and at least one amount of .sup.13C are determined. A source for the methane is determined based on the correlation.

A system for on-stream sampling of pressurized process gas such as natural gas or the like, said system optimized for use with pressurized process gas having liquid entrained therein, or otherwise referenced as wet. In the preferred embodiment, a probe and method of sampling is contemplated to provide linear sample of fluids from a predetermined area of said fluid stream. Further taught is the method of preventing compositional disassociation of a gas sample having entrained liquid utilizing a probe having a passage formed to facilitate capillary action in fluid(s) passing therethrough. The present invention further contemplates the use of a screen or membrane provided exterior the probe tip body to block or lessen the likelihood of undesirable particulates or liquids from entering the probe.