The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In particular, the crash cooling process involves the addition of a toner slurry having a temperature between 70 C. and 90 C. to an equivalent amount of cold water having a temperature between 5 C. and 20 C. Polyester and styrene acrylic toners as well as polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this cooling process results in an improvement to the amount of toner waste, thereby achieving a higher toner usage efficiency for an electrophotographic printing system.

A toner composite material includes toner particles that include a sulfonated polyester and a wax and metal nanoparticles disposed on the surface of the toner particles. A method includes providing such toner composite materials, fusing the material to a substrate and covalently linking a ligand to the surface of the silver nanoparticles via a thiol, carboxylate, or amine functional group. Detection strips include a substrate and such toner composite materials fused on the substrate.

A toner composite material includes toner particles that include a sulfonated polyester and a wax and metal nanoparticles disposed on the surface of the toner particles. A method includes providing such toner composite materials, fusing the material to a substrate and covalently linking a ligand to the surface of the silver nanoparticles via a thiol, carboxylate, or amine functional group. Detection strips include a substrate and such toner composite materials fused on the substrate.

Disclosed is a method for producing a toner comprising combining a binder resin, a wax, a negatively-chargeable charge control resin and a colorant to form the toner, prior to said combining, the negatively-chargeable charge control resin is obtained by drying treatment conducted for 2 to 24 hours under conditions of a drying temperature of 45 to 80 C. and a pressure of 0.5 to 20 kPa, wherein the negatively-chargeable charge control resin comprises a monomer unit having a functional group that imparts a negative charging property, a vinyl aromatic hydrocarbon monomer unit, and a (meth)acrylate monomer unit.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In particular, the crash cooling process involves the addition of a toner slurry having a temperature between 70 C. and 90 C. to an equivalent amount of cold water having a temperature between 5 C. and 20 C. Polyester and styrene acrylic toners as well as polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this cooling process results in an improvement to the amount of toner waste, thereby achieving a higher toner usage efficiency for an electrophotographic printing system.

A liquid developer includes toner particles and a carrier liquid, wherein the toner particles include, as a binder resin, an amorphous polyester resin and a crystalline saturated aliphatic polyester resin having a composition ratio (C/O ratio) of carbon atoms and oxygen atoms of 3.4 or less, and with respect to a toner obtained by vacuum drying the toner particles, a crystal melting peak at a first temperature rise in differential heating calorimetry is 60 C. or more.

A toner comprising a toner particle and inorganic fine particles present on the surface of the toner particle, wherein particle diameter numerical distribution of the inorganic fine particles on the toner particle surface has a peak A1 and B1 present in specific particle diameter ranges, the proportion of inorganic fine particles having a particle diameter of 5 nm to 30 nm is not more than 10 number %, after the toner has been subjected to a water wash treatment, the particle diameter numerical distribution of the of the primary particles of the inorganic fine particles on the toner particle surface has a peak A2 and B2 in specific particle diameter ranges; and HB1, which is a peak value of the peak B1, and HB2, which is a peak value of the peak B2, satisfy a specific relationship.

A toner configured to produce less odor in printing and to have excellent charge stability. Disclosed is a toner comprising polymer particles obtained by polymerizing a polymerizable monomer and an external additive attached to a surface of the polymer particles, wherein a volatilization amount a of an alkylthiol with a molecular weight of 110 or more and less than 150 with respect to the toner, which is quantitated at a volatilization temperature of 160 C. in purge & trap/gas chromatography measurement A, is 1 mass ppm or less, and a volatilization amount b of the alkylthiol with respect to the toner, which is quantitated at a volatilization temperature of 220 C. in purge & trap/gas chromatography measurement B, is 30 mass ppm or more and 1,000 mass ppm or less.

There is provided a toner comprising a binder resin, a wax, a charge control resin and a colorant. As a result of gas chromatography analysis, a first total amount of components detected in a range of a peak detecting time of hydrocarbons having 5 to 9 carbons is 500 ppm or less in terms of styrene; a second total amount of components detected in a range of a peak detecting time of hydrocarbons having 10 to 18 carbons is 5,000 ppm or less in terms of styrene; and an amount of a component corresponding to a maximum peak of peaks of hydrocarbons having 10 to 18 carbons is 3,000 ppm or less in terms of styrene.

A toner having a toner particle that is produced through a step of melt-kneading a resin composition containing a binder resin, a colorant, a hydrocarbon wax, and a wax dispersing agent, cooling the obtained kneaded material, pulverizing the obtained cooled material, and heat treating the resulting resin particles, wherein the wax dispersing agent is a polymer provided by graft polymerizing a styrene-acrylic polymer onto a polypropylene, the styrene-acrylic polymer is a polymer having a monomer unit derived from a cycloalkyl (meth)acrylate, and specific relationships are satisfied where Mp(p) is the melting point ( C.) of the polypropylene and Mp(w) is the melting point ( C.) of the hydrocarbon wax.