Provided is an electrostatic latent image developing toner that, while ensuring low temperature fixability, can ensure image quality stability even during high-speed continuous printing. The toner is an electrostatic latent image developing core-shell type toner containing at least a binder resin. The binder resin includes a crystalline polyester resin, an amorphous polyester resin, and a hybrid amorphous vinyl resin in which a vinyl polymerization segment is chemically bonded to a polymerization segment other than the vinyl polymerization segment, in which a core portion of the toner contains the crystalline polyester resin and the amorphous polyester resin, whereas a shell portion of the toner contains the hybrid amorphous vinyl resin, and the hybrid amorphous vinyl resin has a vinyl polymerization segment content of from 51 to 99% by mass.

Toner comprising a toner particle, the toner particle includes a toner core particle and an organosilicon polymer covering the toner core particle surface, the organosilicon polymer has a structure represented by R.sup.4—SiO.sub.3/2 (R.sup.4 each independently represents an alkyl group having 1 to 6 carbon atoms or a phenyl group), the toner core particle includes a resin A having a substituted or unsubstituted silyl group in a molecule thereof, a substituent of the substituted silyl group is at least one selected from the group consisting of an alkyl group having 1 or more carbon atoms, an alkoxy group having 1 or more carbon atoms, a hydroxy group, a halogen atom, and an aryl group having 6 or more carbon atoms, a content of silicon atoms in the resin A is 0.02 to 10.00% by mass, and a content of silicon atoms in the organosilicon polymer is 30 to 50% by mass.

Provided is a means that can improve performance such as high-speed fixability and fixable temperature range while securing low temperature fixability, in an electrostatic charge image developing toner concurrently using a crystalline resin and an amorphous resin as binder resins constituting toner base particles. An electrostatic charge image developing toner containing toner base particles containing an amorphous resin and a crystalline resin is constituted such that lamellar crystal structures and fibrous crystal structures are dispersed in the cross section of the toner base particles.

A toner includes a toner particle including a surface layer containing an organosilicon polymer. The toner particle contains a styrene acrylic resin and a block polymer that has i) a polyester segment C and a vinyl polymer segment A, the mass ratio C/A of the polyester segment C to the vinyl polymer segment A being 40/60 to 80/20, and ii) a melting point Tm of 55° C. to 90° C. The organosilicon polymer has a partial structure represented by Rf—SiO.sub.3/2.

A method for preparing suspension polymerization toner of core-shell structure comprises following steps: 1) preparing a monomer oil phase containing a certain amount of polar resin forming toner soft core resin and aqueous dispersion liquid respectively; 2) adding the monomer oil phase into the aqueous dispersion liquid, transferring a mixture into a reactor after high-speed shearing and suspension granulation, and carrying out a first heating polymerization reaction to obtain toner particles of soft-core hard-shell structure; 3) taking the toner particles of soft-core hard-shell structure as a core layer, adding a cationic monomer component, and carrying out a second polymerization reaction through a water-soluble initiator to obtain the toner particles of soft-core hard-shell structure with dense charge surface layers uniformly distributed on outer surfaces; and 4) cleaning, filtering, and sufficiently drying a preceding product, and then adding silicon dioxide.

An electrostatic charge image developing toner includes a toner matrix particle having a core-shell structure. The toner matrix particle contains: a core particle including an amorphous resin, a colorant, a release agent, and a crystalline resin; and a shell layer coating a surface of the core particle at a coverage of 60 to 99%. The shell layer includes an amorphous resin. The amorphous resin contained in the core particle differs from the amorphous resin contained in the shell layer. The toner matrix particle has one to seven discrete shell domains determined by observation of a cross section of the toner matrix particle with an electron microscope.

A method of producing a toner for developing electrostatic images includes Steps I to III is provided. The toner includes a toner matrix particle having a core-shell structure. The toner matrix particle includes a core particle including an amorphous resin A and a crystalline material, and a shell including an amorphous resin B. The shell includes a phase of the amorphous resin B that is not fused with the core particle at the interface. The amorphous resin A differs from the amorphous resin B.

Fluorescent green toners are provided. In embodiments, a fluorescent green toner comprises fluorescent agent-incorporated resin particles comprising a resin, a fluorescence brightener, and a yellow fluorescent agent having an absorption spectrum that overlaps with a fluorescence emission spectrum of the fluorescence brightener; and a cyan colorant; blue dye-incorporated resin particles comprising the resin and a blue dye; or both. The fluorescent green toner has a weight ratio of the yellow fluorescent agent to the cyan colorant and, if present, the blue dye, in a range of from 100:1 to 0.2:1, and the fluorescent green toner exhibits Förster Resonance Energy Transfer (FRET) under illumination with UV light. Methods of making and using the fluorescent green toners are also provided.

Methods of making fluorescent pink toners are provided which comprise forming one or more fluorescent latexes which comprise a red fluorescent agent, a yellow fluorescent agent, a first type of amorphous resin, and a second type of amorphous resin, wherein the first and second types of amorphous resins are present at a ratio in a range of from 2:3 to 3:2; forming a mixture comprising the one or more fluorescent latexes; one or more emulsions which comprise a crystalline resin, the first type of amorphous resin, the second type of amorphous resin; and optionally, a wax dispersion; aggregating the mixture to form particles of a predetermined size; forming a shell over the particles of the predetermined size to form core-shell particles; and coalescing the core-shell particles to form a fluorescent pink toner. Fluorescent pink toners and methods of using such toners are also provided.

Methods of making a fluorescent white toner are provided. In embodiments, such a method comprises forming one or more fluorescent latexes which comprise a fluorescent agent, a first type of amorphous resin, and a second type of amorphous resin, wherein the first and second types of amorphous resins are present at a ratio in a range of from 2:3 to 3:2; forming a mixture comprising the one or more fluorescent latexes; a dispersion comprising a white colorant and a surfactant; one or more emulsions which comprise a crystalline resin, the first type of amorphous resin, the second type of amorphous resin; and optionally, a wax dispersion; aggregating the mixture to form particles of a predetermined size; forming a shell over the particles of the predetermined size to form core-shell particles; and coalescing the core-shell particles to form a fluorescent white toner. The fluorescent white toners and methods of using such toners are also provided.