Provided is a method of preparing a poly-silicic-ferric coagulant (PSFC) having a controlled aggregating strength. In particular, according to an embodiment, provided is a method of preparing a PSFC that may effectively suppress both formation of fine toner particles having a particle size that is smaller than a desired particle size and formation of coarse toner particles having a particle size that is greater than the desired particle size, wherein the PSFC for a toner is used in preparation of a toner by using an emulsion aggregation (EA) method. The PSFC for a toner prepared by using the method, according to an embodiment, significantly exhibits a controlled aggregating strength, and thus a viscosity of an emulsion aggregation solution for the toner preparation is appropriate, which results in suppressing production of fine toner particles and coarse toner particles. In this regard, a toner preparation yield may improve.

A composite charge control agent for use in electrostatic imaging comprises porous, inorganic core particles of at least 0.08 microns in diameter, impregnated with 2% to 50% by weight of one or more charge control chemicals and up to 50% by weight of one or more additional compounds such as a polymer, a wax, a dye, or other organic chemicals.

A toner having a toner particle which contains a binder resin, a fatty acid metal salt, and a resin having an ionic functional group, in which the fatty acid metal salt is a fatty acid metal salt of a polyvalent metal with valency of 2 or higher and a fatty acid with carbon atom number of at least 8 and not more than 28, and the acid dissociation constant pKa of the resin having an ionic functional group is at least 6.0 and not more than 9.0.

A method of producing an emissive toner composition including selecting a photoluminescent agent, a charge control agent, and one or more additives and combining the photoluminescent agent, charge control agent, and one or more additives to form an emissive toner composition that when printed to produce an image component on a substrate, the emission spectra of the image component for irradiation with a first excitation energy includes only dominant emission peaks corresponding to one or more dominant emission peaks of the photoluminescent agent. The photoluminescent agent is selected such that it emits light having one or more dominant emission peaks in a first emission spectral region when irradiated with the first excitation energy. The charge control agent and one or more additives are selected such that they do not emit light in the visible spectrum when irradiated with visible light and does not emit light in the first emission spectral region when irradiated with the first excitation energy.

Herein is disclosed magenta liquid electrostatic ink compositions. In some examples, the electrostatic ink compositions comprise a magenta pigment, a basic dispersant, a resin comprising a polymer having acidic side groups, a carrier liquid and a charge director, wherein the dispersant comprises a compound comprising a succinimide group linked to a primary, secondary or tertiary amine.

A toner comprising an external additive A, and a toner particle containing a binder resin and a colorant, wherein the external additive A: i) is an external additive that has a charge control agent on the surface thereof; ii) has a wall friction angle calculated from the following formula (1) of not more than 25.0

=/5.0formula (1);

iii) has a number-average particle diameter (D1) of primary particles of at least 70 nm and not more than 500 nm; and iv) has a solidity as given by the following formula (2) of at least 0.40 and not more than 0.90

solidity=area of external additive A/area of region encompassed by envelope for external additive A formula (2).

A toner comprising an external additive A, and a toner particle containing a binder resin and a colorant, wherein the external additive A: i) is an external additive that has a charge control agent on the surface thereof; ii) has a wall friction angle calculated from the following formula (1) of not more than 25.0

=/5.0formula (1);

iii) has a number-average particle diameter (D1) of primary particles of at least 70 nm and not more than 500 nm; and iv) has a solidity as given by the following formula (2) of at least 0.40 and not more than 0.90

solidity=area of external additive A/area of region encompassed by envelope for external additive A formula (2).

The toner of the present invention contains: a toner base particle, and a silica particle and a fatty acid metal salt particle adhering to a surface of the toner base particle. The toner base particle contains a crystalline polyester resin and an amorphous polyester resin. The toner particle has an average circularity of 0.945 to 0.965. The silica particle has a volume average particle size of 70 to 300 nm, and has an average circularity of 0.5 to 0.9. The fatty acid metal salt particle has a median diameter based on a volume of 0.50 to 2.00 m.

An image forming apparatus includes a developing unit that contains an electrostatic charge image developer which contains a carrier and an electrostatic charge image developing toner, wherein the toner includes toner particles which contain a polyester resin, which is a polycondensate of a polycarboxylic acid and a polyol, and has a glass transition temperature of 50 C. to 70 C., the polyol includes a polyol not having a bisphenol A structure in a range of 50% by weight to 100% by weight, and a melt viscosity A of the toner at 110 C. after storage for 2 hours under the environment of absolute humidity of 82.7 (g/m.sup.3) and a melt viscosity B of the toner at 110 C. after storage for 2 hours under the environment of absolute humidity of 16.5 (g/m.sup.3) each are in the ranges specified in the specification.

A toner includes a plurality of toner particles (10) each including a toner mother particle (11) and a plurality of external additive particles (12) attached to a surface of the toner mother particle (11). The external additive particles (12) each include a silica particles (12a), a metal hydroxide layer, and a coating layer (12b). The metal hydroxide layer is disposed on a surface of the silica particle (12a). At least a part of the coating layer (12b) is disposed on a surface of the metal hydroxide layer. The coating layer (12b) is made substantially from a nitrogen containing resin.