Provided is a photochromic film laminate including (a) a first polymeric film layer having a first surface and an opposing second surface; and (b) an adhesive layer over at least a portion of and in direct contact with the first surface of the first polymeric film layer (a). The adhesive layer is formed from a composition of a thermoplastic polyol having a number average molecular weight greater than or equal to 30,000 g/mol; a poly(anhydride); and a photochromic material. The thermoplastic polyol (i) is present in the composition in an amount greater than or equal to 60 percent by weight based on total combined weight of solids present in the thermoplastic polyol (i) and the poly(anhydride) (ii). Also provided is an optical article prepared with the photochromic film laminate.

Provided is a curable photochromic coating composition including (a) a polyol component, (b) a poly(anhydride) having at least three cyclic anhydride groups, (c) a secondary crosslinker, and (d) a photochromic material. The polyol component includes (i) a first polyol having two hydroxyl groups and a hydroxyl equivalent weight of at least 15,000 g/mol and (ii) a second polyol different from the first polyol having at least three hydroxyl groups and a hydroxyl equivalent weight of at least 300 g/mol. The secondary crosslinker is selected from a poly(carbodiimide), an oxazoline-functional material, or mixtures thereof. The present invention also provides an optical article prepared from the curable photochromic coating composition.

Provided is a curable photochromic coating composition including (a) a polyol component, (b) a poly(anhydride) having at least three cyclic anhydride groups, (c) a secondary crosslinker, and (d) a photochromic material. The polyol component includes (i) a first polyol having two hydroxyl groups and a hydroxyl equivalent weight of at least 15,000 g/mol and (ii) a second polyol different from the first polyol having at least three hydroxyl groups and a hydroxyl equivalent weight of at least 300 g/mol. The secondary crosslinker is selected from a poly(carbodiimide), an oxazoline-functional material, or mixtures thereof. The present invention also provides an optical article prepared from the curable photochromic coating composition.

Method for producing a photochromic material and a component including the photochromic material, where the method comprises the steps of:-first the formation on a substrate of a layer of an essentially oxygen free metal hydride with a predetermined thickness using a physical vapor deposition process; and -second exposing the metal hydride layer to oxygen where the oxygen reacts with the metal hydride, resulting in a material with photochromic properties.

Method for producing a photochromic material and a component including the photochromic material, where the method comprises the steps of:-first the formation on a substrate of a layer of an essentially oxygen free metal hydride with a predetermined thickness using a physical vapor deposition process; and -second exposing the metal hydride layer to oxygen where the oxygen reacts with the metal hydride, resulting in a material with photochromic properties.

A method of producing a photochromic resin body includes a first step, a second step and a third step. In the first step, a sublimable photochromic dye having sublimability is applied to a base body so as to obtain a function-adding base body. In the second step, the function-adding base body obtained in the first step is set to face a resin body, the function-adding base body is heated to sublimate the sublimable photochromic dye applied to the function-adding base body, and the sublimable photochromic dye is deposited on the resin body. In the third step, the resin body on which the sublimable photochromic dye is deposited in the second step is heated to fix the sublimable photochromic dye on the resin body.

A method of producing a photochromic resin body includes a first step, a second step and a third step. In the first step, a sublimable photochromic dye having sublimability is applied to a base body so as to obtain a function-adding base body. In the second step, the function-adding base body obtained in the first step is set to face a resin body, the function-adding base body is heated to sublimate the sublimable photochromic dye applied to the function-adding base body, and the sublimable photochromic dye is deposited on the resin body. In the third step, the resin body on which the sublimable photochromic dye is deposited in the second step is heated to fix the sublimable photochromic dye on the resin body.

The present invention provides: a photochromic curable composition which contains (A) a (meth)acrylate composition that contains from 24 to 100% by mass of a polyfunctional (meth)acrylate which has three or more (meth)acryloyl groups in each molecule and (B) a photochromic compound that is obtained by bonding at least one specific naphthopyran to a long-chain group having a number average molecular weight of from 300 to 10,000; and a photochromic optical article which is obtained by polymerizing this photochromic curable composition.

A primer composition for optical article, the composition includes (A) an urethane prepolymer that is a reactant between (A1) a polyisocyanate compound having two or more isocyanate groups per molecule and (A2) at least one polyol compound having two or more hydroxyl groups per molecule and being selected from the group consisting of polycarbonate polyols, polyester polyols, and polycaprolactone polyols, and that has two or more isocyanate groups per molecule protected by a blocking agent; (B) an active hydrogen-containing compound having, per molecule, two or more active hydrogen functional groups having an active hydrogen; and (C) an organic solvent not having an active hydrogen.

A primer composition for optical article, the composition includes (A) an urethane prepolymer that is a reactant between (A1) a polyisocyanate compound having two or more isocyanate groups per molecule and (A2) at least one polyol compound having two or more hydroxyl groups per molecule and being selected from the group consisting of polycarbonate polyols, polyester polyols, and polycaprolactone polyols, and that has two or more isocyanate groups per molecule protected by a blocking agent; (B) an active hydrogen-containing compound having, per molecule, two or more active hydrogen functional groups having an active hydrogen; and (C) an organic solvent not having an active hydrogen.