A polyester resin, including: (a) a constitutional unit derived from at least one tetravalent carboxylic acid selected from Compounds (A) and (B); a constitutional unit derived from a bisphenol A-alkylene oxide adduct; and a constitutional unit derived from an aliphatic alcohol having a boiling point of lower than or equal to 290° C., where the polyester resin is free of a constitutional unit derived from a monovalent carboxylic acid, an acid value of the polyester resin is 8 to 55 mg KOH/g, and an amount of the tetravalent carboxylic acid is 1 to 30 mol % when an total amount of the tetravalent carboxylic acid, and other polyvalent carboxylic acid excluding the Compounds (A) and (B) is set to 100 mol %, ##STR00001## where X.sup.1, X.sup.2, X.sup.3 and X.sup.4 each independently represent a trivalent organic group, and Z.sup.1 and Z.sup.2 each independently represent a single bond or a divalent organic group, wherein tetravalent carboxylic acid is, for example, 3,3′,4,4′-biphenyltetracarboxylic dianhydride, 2,2′,6,6′-biphenyltetracarboxylic dianhydride, 4,4′-oxydiphthalic dianhydride, 9,9-bis(3,4-dicarboxyphenyl) fluorene dianhydride, and/or 4,4′-(4,4′-isopropylidenediphenoxy) diphthalic anhydride.

Toner particles including a core and a shell thereover; wherein the core comprises at least one styrene-acrylate copolymer selected from styrene-acrylate copolymer 1, styrene-acrylate copolymer 2, and styrene-acrylate copolymer 3, and combinations thereof a wax; and an optional colorant; wherein the shell comprises at least one styrene-acrylate copolymer selected from styrene-acrylate copolymer 1, styrene acrylate copolymer 2, styrene acrylate copolymer 3, and combinations thereof.

A toner comprising a toner particle comprising a binder resin and a release agent, wherein the binder resin comprises a first resin and a second resin; the first resin is a crystalline resin having a melting point Tp of 50° C. to 90° C.; the second resin is an amorphous resin; in a cross section of the toner particle observed by a transmission electron microscope, the cross section of the toner particle has a matrix-domain structure composed of a matrix comprising the first resin and domains comprising the second resin; an area ratio of the matrix comprising the first resin in a total area of the cross section of the toner particle is 35 to 70 area %; and where a longest direction of each of the domains is taken as a longitudinal direction, a standard deviation of an angle of the longitudinal direction of the domains is 25° or less.

Provided is a toner blend composition comprising a first pigmented toner and a second toner that is devoid of any pigment additive, i.e., a ‘non-pigmented or clear toner’. The non-pigmented or clear toner is about 1% to about 15% by weight of the toner blend composition. The resulting inventive toner blend composition surprisingly exhibits similar print density on a page compared to a fully pigmented toner. Moreover, this toner blend composition exhibits improvement in toner usage per page, thus lowering toner cost compared to a fully pigmented toner. The non-pigmented or clear toner may be used in combination with either a monochrome or conventional toner using a carbon black pigment, or a chemically processed toners (‘CPT”) toners using a black pigment, magenta pigment, yellow pigment or a cyan pigment.

Provided is a toner blend composition comprising a first pigmented toner and a second toner that is devoid of any pigment additive, i.e., a ‘non-pigmented or clear toner’. The non-pigmented or clear toner is about 1% to about 15% by weight of the toner blend composition. The resulting inventive toner blend composition surprisingly exhibits similar print density on a page compared to a fully pigmented toner. Moreover, this toner blend composition exhibits improvement in toner usage per page, thus lowering toner cost compared to a fully pigmented toner. The non-pigmented or clear toner may be used in combination with either a monochrome or conventional toner using a carbon black pigment, or a chemically processed toners (‘CPT”) toners using a black pigment, magenta pigment, yellow pigment or a cyan pigment.

Provided is a toner blend composition comprising a first pigmented toner and a second toner that is devoid of any pigment additive, i.e., a ‘non-pigmented or clear toner’. The non-pigmented or clear toner is about 1% to about 15% by weight of the toner blend composition. The resulting inventive toner blend composition surprisingly exhibits similar print density on a page compared to a fully pigmented toner. Moreover, this toner blend composition exhibits improvement in toner usage per page, thus lowering toner cost compared to a fully pigmented toner. The non-pigmented or clear toner may be used in combination with either a monochrome or conventional toner using a carbon black pigment, or a chemically processed toners (‘CPT”) toners using a black pigment, magenta pigment, yellow pigment or a cyan pigment.

A toner includes a toner particle containing a resin component including a crystalline resin and an amorphous resin. In a cross-sectional observation of the toner particle, a domain-matrix structure which comprises a matrix containing the crystalline resin and domains containing the amorphous resin is observed. The maximum endothermic peak temperature Tm of the toner determined by DSC is 50° C. to 80° C. When the storage elastic modulus of the toner at a temperature 5° C. lower than Tm is G′(−5) (Pa), and the storage elastic modulus of the toner at a temperature 5° C. higher than Tm is G′(+5) (Pa), G′(−5) and G′(+5) satisfy inequality (1), and when the maximum loss tangent of the toner in a temperature range of from 50° C. to 130° C. is tan δ (Max), tan δ (Max) satisfies inequality (2).

A toner including toner particles having a resin component containing a crystalline resin and an amorphous resin, in which the resin component contains a tetrahydrofuran-insoluble component, and the content of the tetrahydrofuran-insoluble component with respect to the content of the resin component is 5.0% to 80.0% by mass, wherein a maximum endothermic peak temperature of the tetrahydrofuran-insoluble component is 55.0 to 80.0° C., and the amount of heat absorption in the maximum endothermic peak of the tetrahydrofuran-insoluble component is 10.0 to 80.0 Pa, and toner particles have a structure which comprises a matrix containing the crystalline resin and domains containing the amorphous resin.

Methods of making phosphorescent toner are provided. In an embodiment, such a method comprises forming a phosphorescent pigment emulsion comprising a phosphorescent pigment and a surfactant; homogenizing a mixture comprising a resin emulsion comprising a resin and the phosphorescent pigment emulsion; aggregating the mixture to form toner particles comprising the phosphorescent pigment embedded within and surrounded by the resin; and coalescing the toner particles to form a phosphorescent toner comprising the toner particles. The phosphorescent toners are also provided.

Methods of making a crosslinked fluorescent latex are provided. In an embodiment, such a method comprises adding a water-soluble initiator to an uncrosslinked fluorescent latex comprising water and uncrosslinked resin particles comprising an unsaturated resin and a fluorescent agent incorporated therein; and exposing the water-soluble initiator to conditions to activate the water-soluble initiator and induce crosslinking reactions between the activated water-soluble initiator and the unsaturated resin, thereby forming a crosslinked fluorescent latex comprising crosslinked fluorescent resin particles comprising crosslinked resin and the fluorescent agent incorporated therein. Crosslinked fluorescent latexes are also provided, as are fluorescent toners made from the same.