G03G9/09708

ELECTROSTATIC CHARGE IMAGE DEVELOPING TONER
20220206403 · 2022-06-30 ·

An electrostatic charge image developing toner includes: toner base particles containing a binder resin and a metal pigment; and an external additive containing lanthanum-containing strontium titanate particles.

TONER AND METHOD FOR PRODUCING THE SAME

To provide a toner having both low temperature fixability and hot offset resistance and having excellent scratch resistance of a fixed image. A toner including a toner particle containing a binder resin, a crystalline polyester, and a calcium carbonate particle, in which the crystalline polyester includes a unit derived from an aliphatic diol and a unit derived from an aliphatic dicarboxylic acid, an ester group concentration Ec of the crystalline polyester is 27% by mass or more to 50% by mass or less, a content Ma of the calcium carbonate particle included in the toner particle is 3% by mass or more to 40% by mass or less, and a ratio (Ma/Mc) of the content Ma of the calcium carbonate particle included in the toner particle to a content Mc (% by mass) of the crystalline polyester included in the toner particle is 0.2 or more to 20 or less.

TONER

A toner having high rub resistance is provided. A toner including a toner particle containing a binder resin and a calcium carbonate particle, wherein in X-ray diffractometry of the toner particle by CuKα radiation, when the Bragg angle is defined as θ, (i) the calcium carbonate particle has peaks at of 26.5°±0.5° and 29.5°±0.5°, (ii) a crystallite diameter of crystals thereof attributed to 2θ=29.5°±0.5° is 10 nm or more and 45 nm or less, and (iii) the ratio (a/b) of a peak intensity “a” at 2θ=26.5°±0.5° to a peak intensity “b” at 20θ=29.5°±0.5° is 0.15 or more and 0.24 or less.

TONER FORMULATIONS HAVING IMPROVED TONER USAGE EFFICIENCY
20220197169 · 2022-06-23 ·

A toner composition having improved toner usage efficiency, wherein toner particles having an average size range of 1-25 μm may be mixed with an extra particulate additive package including a first small silica surface treated with both a silane and an aminosilane having a primary particle size of about 5 nm-20 nm, a second fumed silica having a primary particle size of 30 nm-60 nm, a third silica having a primary particle size of about 70 nm-120 nm, an electro-conductive titania having a primary particle size of 30 nm-60 nm and an acicular titania having a size of about 1.6 μm to 1.7 μm in length and about 130 nm in diameter. An alternative embodiment of the extra particulate additive package does not include a third silica having a primary particle size of about 70 nm-120 nm.

TONER

A toner including a toner particle which contains: a resin component containing a binder resin; and an inorganic fine particle, the inorganic fine particle is at least one inorganic fine particle selected from the group consisting of (i) a particle containing CaCO.sub.3, (ii) a particle containing BaSO.sub.4, (iii) a particle containing Mg.sub.3Si.sub.4O.sub.10(OH).sub.2, and (iv) a particle containing Al.sub.2Si.sub.2O.sub.5(OH).sub.4, a number average particle diameter Dc of a primary particle of the inorganic fine particle is 100 nm or more and 1000 nm or less, when a cross section of the toner particle is observed, an inorganic fine particle domain A having a dispersion diameter of 2.0 times or more of Dc is present in the cross section, and the inorganic fine particle and the inorganic fine particle domain A occupy a specific percentage of an area in the cross section of the toner particle.

TONER HAVING EXTRA PARTICULAR ADDITIVES

A toner composition having improved toner usage efficiency, wherein toner particles having an average size range of 1-25 μm may be mixed with an extra particulate additive package including a first small silica surface treated with both a silane and an aminosilane having a primary particle size of about 5 nm-20 nm, a second fumed silica having a primary particle size of 30 nm-60 nm, a third silica having a primary particle size of about 70 nm-120 nm, an electro-conductive titania having a primary particle size of 30 nm-60 nm and an acicular titania having a size of about 1.6 μm to 1.7 μm in length and about 130 nm in diameter. An alternative embodiment of the extra particulate additive package does not include a third silica having a primary particle size of about 70 nm-120 nm.

Toner

A toner comprising a toner particle, wherein the toner has G1 of from 5.0×10.sup.−13 to 1.0×10.sup.−10, and a ratio G2/G1 of G2 to G1 is from 0.10 to 0.60, when a conductivity of the toner measured at a frequency of 0.01 Hz under a pressure of 1,000 kPa is designated by G1 in S/m, and a conductivity of the toner measured at a frequency of 0.01 Hz under a pressure of 100 kPa is designated by G2 in S/m.

TONER

A toner comprising a toner particle and an external additive, wherein the toner particle comprises a core comprising a resin A and a shell comprising a resin B on the surface of the core, the external additive comprises a hydrotalcite particle A, fluorine and aluminum are present in an inner part of the hydrotalcite particle A in line analysis in STEM-EDS mapping analysis of the toner, and a concentration ratio of the number of fluorine atoms relative to aluminum atoms (F/Al) in the hydrotalcite particle A, as determined by primary component mapping of the hydrotalcite particle A in the STEM-EDS mapping analysis of the toner, is 0.01 to 0.60.

TONER AND TONER PRODUCTION METHOD

The subject toner includes a toner particle containing a binding resin and an inorganic oxide particle, wherein the inorganic oxide particle is a particle of an oxide containing at least one element selected from the group consisting of: Si; Mg; Al; Ti; and Sr, wherein, when an area of the inorganic oxide particle is represented by Sm and a sectional area of the toner is represented by St in a cross-section of the toner observed with a transmission electron microscope, Sm/St is 4.0% or more, wherein an area Sm of the inorganic oxide particle that occupies each of four regions obtained by dividing the cross-section of the toner by a long diameter of the toner and a perpendicular bisector of the long diameter has a standard deviation of 0.40 or more in the observed cross-section, and wherein the toner has an average circularity of 0.950 or more.

TONER AND METHOD FOR PRODUCING TONER

The present disclosure provides a toner excellent in low-temperature fixability and excellent in durability under harsh environments of high-temperature and high-humidity, and a method for producing the toner. The toner can contain: a toner particle containing a binder resin, wax, and an inorganic oxide particle; and an external additive, wherein the inorganic oxide particle contains, as a main component, an oxide of at least one element selected from the group consisting of Si, Mg, Al, Ti, and Sr; when a thin piece obtained by cutting the toner with a microtome is observed with a transmission electron microscope (TEM), the major axis A of the inorganic oxide particle is 0.10 to 3.00 μm; and in a wettability test of the toner with respect to a methanol/water mixed solvent, a methanol concentration at a transmittance of light having a wavelength of 780 nm of 50% is 5.0 to 30.0% by volume.