A downhole fluid analysis system includes an optical sensor comprising, which includes a light source configured to emit light comprising a plurality of wavelengths, a light detector, and an optical tip through which at least a portion of the light travels and returns to the detector, wherein the incident angle of the light causes total internal reflection within the optical tip. The system further includes a piezoelectric helm resonator that generates a resonance response in response to an applied current, and an electromagnetic spectroscopy sensor positioned symmetrically with respect to the piezoelectric helm resonator in at least one direction. The light may be reflected in the optical tip at one or more reflection points, and each reflection point may generate an evanescent wave in a medium surrounding the optical tip. The light may be internally reflected in the optical tip at a plurality of reflection points.

A sensing system for monitoring a composition of a downhole fluid in a well, where the sensing system includes: a light source, an optical waveguide, an evanescent field sensing element that is indirect contact with a downhole fluid, and a detector. The light source is operable for emitting a beam and includes a frequency comb generator configured to modify at least a portion of the beam into a sensing comb beam. The evanescent field sensing element provides attenuated internal reflection of the sensing comb beam at the interface between the evanescent field sensing element and the downhole fluid, and the portion of the sensing comb beam interacts with the fluid to form at least a portion of an interacted beam. The detector obtains a spectral distribution of the interacted beam.

Improved devices, systems and methods for measuring in situ saturations of non-aqueous phase liquids and/or petroleum in media such as soil. A clear or otherwise UV-transparent well for detecting fluorescence in a soil column having a transparent casing and an oil sensing device positioned in the well configured to monitor the soil column. A method for real-time estimation of LNAPL saturations in media, including emplacing a UV-transparent well in the media and recording fluorescence in the media via an oil sensing device.

The present disclosure relates to systems and methods for analyzing fluids. The method for analyzing a chemical sample within a wellbore, contained within an interrogation device, may comprise broadcasting a coherent light from a frequency comb module, directing the coherent light through a fiber optic line to the interrogation device, irradiating the chemical sample with the coherent light, capturing light resulting from the irradiation of the chemical sample, and producing a spectrum resulting from the captured light from the chemical sample. A frequency comb system for analyzing a chemical sample may comprise a frequency comb module configured to broadcast a coherent light and a fiber optic line that extends into a wellbore to an interrogation device. The interrogation device may further be configured to contain the chemical sample for irradiation by the coherent light. The frequency comb system may further comprise a receiver and an information handling system.

A soil imaging probe has a housing with an interior cavity and an outer surface exposed for sliding contact with soil. A window is mounted in the outer surface for providing optical communication between the soil and the interior cavity. An optical module is positioned within the interior cavity. The optical module includes at least one light source and a camera mounted in a block. An indexing surface is defined in the interior cavity to maintain the optical module at a predetermined fixed distance from the window to keep the camera focused on the soil outside the window. An elastomeric fill material fills the interior cavity and substantially surrounds the optical module to reduce energy transference from the housing of the probe to the optical module. An image processing method is also provided to identify pixels in an image captured by the camera that show potential hydrocarbon contamination.

Downhole tools for isolating and analyzing one or more gases include a gas separation assembly in fluid communication with a gas specific analyzer. The gas separation assembly includes a piston disposed within a housing and a separation volume defined between the piston and the housing. The piston is movable to separate a gas component and a liquid component from a downhole formation fluid within the separation volume. The gas specific analyzer is operable to measure one or more properties of the gas component. In some configurations, the gas specific analyzer is an optical assembly containing a light source, an optical detector, and a gas cell that contains an observation volume. The optical assembly is operable to measure one or more properties of the gas component within the observation volume via the light source and the optical detector.

Improved devices, systems and methods for measuring in situ saturations of non-aqueous phase liquids and/or petroleum in media such as soil. A clear or otherwise UV-transparent well for detecting fluorescence in a soil column having a transparent casing and an oil sensing device positioned in the well configured to monitor the soil column. A method for real-time estimation of LNAPL saturations in media, including emplacing a UV-transparent well in the media and recording fluorescence in the media via an oil sensing device.

A method including generating integrated computational element (ICE) models and determining a sensor response as the projection of a convolved spectrum associated with a sample library with a plurality of transmission profiles determined from the ICE models. The method includes determining a regression vector based on a multilinear regression that targets a sample characteristic with the sensor response and the sample library and determine a plurality of regression coefficients in a linear combination of ICE transmission vectors that results in the regression vector. The method further includes determining a difference between the regression vector and an optimal regression vector. The method may also include modifying the ICE models when the difference is greater than a tolerance, and fabricating ICEs based on the ICE models when the difference is within the tolerance. A device and a system for optical analysis including multiple ICEs fabricated as above, are also provided.

A spectrometer probe is disclosed herein including a shaft having a first end and a second end, a fiberoptic bundle located within the shaft, the fiberoptic bundle having a first end and a second end, a mirror, a transparent window, a prism, a prism support, an elastically deformable material, an index-matching elastomer, wherein the prism is completely encompassed by the index-matching elastomer, and a penetration cone operatively attached to the second end of the fiberoptic bundle, the mirror located within the second end of the shaft, wherein the transparent window is substantially parallel with the fiberoptic bundle and the shaft, wherein the prism is angled at approximately a 45 degree angle in relation to the window and the fiberoptic bundle, wherein the prism is flush with the prism support, wherein the elastically deformable material is biasly connected to the prism support.

An in situ low-power wireless measurement apparatus and method suitable for reporting a soil moisture profile at various zones.