A sensor element includes an element body including an oxygen-ion-conductive solid electrolyte layer, the element body having a longitudinal direction, a measurement electrode disposed in the element body, a reference electrode disposed in the element body so as to come into contact with a reference gas, and a heater configured to heat the solid electrolyte layer. A center of gravity of the reference electrode overlaps the measurement electrode as viewed in a thickness direction of the solid electrolyte layer. A length of each of the reference electrode and the measurement electrode in a front-rear direction is less than or equal to 1.1 mm, the front-rear direction being a direction along the longitudinal direction of the element body. An area of the reference electrode as viewed in the thickness direction is greater than or equal to 1.0 mm.sup.2.

A method for manufacturing a sensor element that includes: a pair of electrodes; a ceramic layer having a hollow space that is to be an air introduction hole; and a first layer and a second layer stacked at both surfaces of the ceramic layer, One of the electrodes is in communication with the hollow space, The method includes: preparing an unsintered ceramic sheet, and a burn-out material sheet having a thickness different from that of the unsintered ceramic sheet, the burn-out material sheet having, in a plane orthogonal to the direction of an axial line O, a cross-sectional area substantially identical to a cross-sectional area of the pre-sintering hollow space; placing the burn-out material sheet in the pre-sintering hollow space; pressing the sheets so as to have an identical thickness; and burning out the burn-out material sheet.

Electrochemical sensors include a housing within which an electrolyte is provided over the electrodes. The housing includes an active region, which is the area around the electrodes in which the electrolyte must be positioned to ensure correct operation of the device. The inner walls, base and ceiling of the housing are coated in either hydrophobic or hydrophilic materials, or both, so as to encourage the electrolyte to take a position over the active region, which is defined by the position of the electrodes. In some electrochemical sensors, a combination of hydrophobic and hydrophilic materials is used and the materials can be arranged in a pattern, which encourages the electrolyte to take a position over the active region.

A gas sensor (100) extending in an axial direction AX including: a gas sensor element (120) which detects the concentration of a specific gas in a gas under measurement; a tubular metallic shell (110) having a polygonal tool engagement portion (110B) surrounding the gas sensor element (120); a tubular outer tube (103) which extends rearward from the metallic shell (110), surrounds the gas sensor element (120), and has an opening (103E) at a rear end thereof; a sealing member (191) which seals the opening (103E); and a tubular heat dissipating member (104) which surrounds the outer tube (103) and reduces the amount of heat transferred from the forward end side of the gas sensor (100) through the outer tube (103) to the sealing member (191). The maximum diameter D1 of the heat dissipating member (104) is equal to or less than the opposite side dimension D2 of the tool engagement portion (110B).

A controller of the gas sensor can perform diagnostic processing of diagnosing a situation of control to the gas sensor in a case that the gas sensor in an operation state is determined to satisfy a predetermined diagnostic condition and adjustment processing of adjusting a condition for controlling the gas sensor in accordance with a result of diagnosis. In the diagnostic processing, a main pump voltage and a diagnostic threshold as a value of a voltage not causing decomposition of NOx in the main pump cell are compared. In the adjustment processing, temperature adjustment processing to cause, in a case that the main pump voltage is diagnosed to be equal to the threshold or more, the main pump voltage to be less than the threshold, at least in a way that the heater part increases the element driving temperature in the operation state by a predetermined increase amount is performed.

A gas sensor includes a sensor element, a detection device, a reference gas regulating device. The sensor element includes an element body having disposed therein a measurement-object gas flow section, a measurement-object-gas-side electrode disposed in or out of the element body, a reference electrode disposed within the element body, and a reference gas introducing section that allows a reference gas to be introduced thereinto and to flow therethrough to the reference electrode. The reference gas regulating device allows an oxygen pump-in current to flow between the reference electrode and the measurement-object-gas-side electrode to pump oxygen into around the reference electrode from around the measurement-object-gas-side electrode. A ratio R1/R2 of a reaction resistance R1 of the reference electrode to a diffusion resistance R2 of the reference gas introducing section is greater than or equal to 0.1 and less than or equal to 2.0.

A carbon dioxide sensor includes: a solid electrolyte layer that is anion conductive; a reference electrode disposed on one surface of the solid electrolyte layer; and a detection electrode disposed on the other surface of the solid electrolyte layer. The detection electrode is made of a mixture containing: (a) one or more metals selected from the group consisting of Au, Ag, Pt, Pd, Rh, Ru, Os, and Ir; (b) a cation conductive carbonate; and (c) an oxide containing Li and at least one of Ce and Sm. The solid electrolyte layer is preferably oxide ion conductive, and the cation conductive carbonate is preferably lithium ion conductive.

A limiting current-type gas sensor element including a plurality of stacked ceramic layers and configured to output a limiting current value which depends on a concentration of a specific gas in a gas to be measured when a certain voltage is applied. The gas sensor element includes a solid electrolyte member having oxygen ion conductivity; a heater that heats the solid electrolyte member; a measurement electrode and a reference electrode provided on the solid electrolyte member; a chamber facing the measurement electrode and into which the gas to be measured is introduced; a gas inlet located to a tip side of the chamber in a longitudinal direction; and a diffusion resistance part provided in the gas inlet. A heating center of the heater is located further to the tip side than an electrode center of the measurement electrode is.

Methods and apparatus for sensing hydrogen in a mixture of hydrogen and natural gas are provided. One example of the apparatus comprises: a first chamber for receiving air; a second chamber for receiving the mixture of hydrogen and natural gas; a first electrode for adsorbing oxygen molecules from air in the first chamber and for reducing the oxygen molecules to oxide ions; a second electrode; an ionic conductor for transporting the oxide ions from the first electrode to the second electrode in order to cause the transported oxide ions to combine with hydrogen molecules at the second electrode; sensing circuitry for sensing an electrical parameter associated with the combination of the transported oxide ions with the hydrogen molecules at the second electrode; and processing circuitry configured to determine a proportion of hydrogen in the mixture, based at least in part on the electrical parameter sensed by the sensing circuitry.

A gas sensor includes: a substrate; an insulating layer arranged over the substrate; and a solid electrolyte layer, wherein the substrate is formed with a cavity that penetrates the substrate in a thickness direction of the substrate, wherein the insulating layer has a peripheral portion arranged over the substrate around the cavity, and a membrane portion which is located over the cavity and is connected to the peripheral portion, wherein the membrane portion includes a movable portion, wherein a through-hole, which penetrates the membrane portion around the movable portion in the thickness direction, is formed such that the movable portion is capable of being displaced along the thickness direction, and wherein the solid electrolyte layer is arranged over the movable portion.