Embodiments are provided for ultraviolet lamps for use in photoionization detectors and methods of manufacturing same. An example method of manufacturing an ultraviolet lamp includes providing a glass tube, the glass tube defining a first end; applying a mixed powder coating composition onto an edge surface of the first end of the glass tube, the mixed powder coating composition comprising indium powder and glass powder; applying a glass powder coating composition over the mixed powder coating composition; attaching a crystal window to the edge surface of the first end of the glass tube; and heating the glass tube and the crystal window to seal the crystal window to the glass tube.

A photoionization detector comprised of a gas discharge lamp that ionizes molecules of interest to create ionized molecules and electrons and a sensor having at least one opening for UV light to pass through and electrically conductive patterns on the top and bottom surfaces of the plate. A negative electrical potential pattern can be on one of the top or the bottom surface and can include an interior portion that is at least a first distance away from every edge of the at least one opening. An electron collecting electrode pattern can be on the other of the top or the bottom surface and can substantially fill an area surrounding the opening such that the negative electrical potential pattern and the electron collecting electrode pattern are offset relative to each other. The ionized molecules are collectable by a bias electrode and electrons are collectable by a collector electrode.

A photoionization detector sensor comprised of plate, at least one opening in the plate for UV light to pass through, and at least one electrically conductive pattern on at least one of the top and bottom surfaces of the plate. The at least one electrically conductive pattern can include a negative electrical potential pattern comprised of a first material. Further, the negative electrical potential pattern can have a void in its center, and the void can surround the at least one opening. The plate can be comprised of a second material that is different than the first material. The negative electrical potential pattern can be located on at least one of the top or the bottom surfaces, and the at least one electrically conductive pattern can further include an electron collecting electrode pattern on the other of top or bottom surface.