Apparatuses and methods of measuring a hydrogen diffusivity of a metal structure including during operation of the metal structure, are provided. A hydrogen charging surface is provided at a first location on an external surface of the structure. In addition, a hydrogen oxidation surface is provided at a second location adjacent to the first location on the external surface of the structure. Hydrogen flux is generated and directed into the metal surface at the charging surface. At least a portion of the hydrogen flux generated by the charging surface is diverted back toward the surface. A transient of the diverted hydrogen fluxes measured, and this measurement is used to determine the hydrogen diffusivity of the metal structure in service.

In order to remove dust attached to a filter member 40 to surely clean the filter member 40, an analysis apparatus 100 includes: a sample containing part 10 that contains a sample; the filter member 40 through which gas produced from the sample heated in the sample containing part 10 passes; and a gas flow path L1 adapted to lead the gas having passed through the filter member 40 to an analyzer. In addition, the filter member 40 is formed in a tubular shape, and in one end part of the filter member 40, a gas lead-out port 40a connecting to the gas flow path L1 is formed. Further, it is configured that the gas passes through a side wall part 42 of the filter member 40 from outside to inside, and flows from the gas lead-out port 40a to the gas flow path L1.

A potentiometric oxygen sensor for measuring the oxygen concentration of a liquid metal, including: a metal tube forming at least one sensor body part; an electrochemical subassembly containing an electrolyte, intended to be in contact with the liquid metal, and a reference electrode contained in the electrolyte, the electrolyte being made of yttrium-doped or calcium-doped hafnia (HfO.sub.2), or of thoria (ThO.sub.2), which is optionally yttrium-doped or calcium-doped, or of yttrium-doped or calcium-doped zirconia (ZrO.sub.2), the reference electrode containing at least one metal and its oxide form at the operating temperature of the sensor, an insert made of a transition metal from group 4 of the Periodic Table or an alloy thereof, arranged between the sensor body part and the electrolyte, the insert being attached to the sensor body part and brazed onto the electrolyte by a brazing joint.

A potentiometric oxygen sensor for measuring the oxygen concentration of a liquid metal, including: a metal tube forming at least one sensor body part; an electrochemical subassembly containing an electrolyte, intended to be in contact with the liquid metal, and a reference electrode contained in the electrolyte, the electrolyte being made of yttrium-doped or calcium-doped hafnia (HfO.sub.2), or of thoria (ThO.sub.2), which is optionally yttrium-doped or calcium-doped, or of yttrium-doped or calcium-doped zirconia (ZrO.sub.2), the reference electrode containing at least one metal and its oxide form at the operating temperature of the sensor, an insert made of a transition metal from group 4 of the Periodic Table or an alloy thereof, arranged between the sensor body part and the electrolyte, the insert being attached to the sensor body part and brazed onto the electrolyte by a brazing joint.

An analytical inspection system for determining concentration of mobile hydrogen of and/or on surfaces of a metallic object can include: a vacuum furnace; a hydrogen sensing device; and/or a flow path from the furnace to the sensing device. The sensing device can be configured to detect and/or measure the mobile hydrogen at levels less than or equal to 1 part per million (ppm). An analytical inspection method for determining concentration of mobile hydrogen of and/or on surfaces of a metallic object can include: placing the object into a vacuum furnace; drawing a vacuum in the furnace; and/or simultaneously heating the metallic object in the furnace and measuring a quantity of the mobile hydrogen released from the object using a hydrogen sensing device. The sensing device can be configured to detect and/or measure the mobile hydrogen at levels less than or equal to 1 ppm.

An analytical inspection system for determining concentration of mobile hydrogen of and/or on surfaces of a metallic object can include: a vacuum furnace; a hydrogen sensing device; and/or a flow path from the furnace to the sensing device. The sensing device can be configured to detect and/or measure the mobile hydrogen at levels less than or equal to 1 part per million (ppm). An analytical inspection method for determining concentration of mobile hydrogen of and/or on surfaces of a metallic object can include: placing the object into a vacuum furnace; drawing a vacuum in the furnace; and/or simultaneously heating the metallic object in the furnace and measuring a quantity of the mobile hydrogen released from the object using a hydrogen sensing device. The sensing device can be configured to detect and/or measure the mobile hydrogen at levels less than or equal to 1 ppm.

Provided are a method for assessing hydrogen environment severity of a rolling device during operation and a method for predicting likelihood that white structure damage occurs to the rolling device as a result of operation. A hydrogen environment severity assessment method is a method for assessing, among operating conditions of a rolling device including two rolling members coming into rolling contact with each other and having at least one of the two rolling members being a steel rolling member, hydrogen environment severity, the hydrogen environment severity being an index representing magnitude of influence exerted by hydrogen. The hydrogen environment severity assessment method includes a measurement step of measuring the amount of room temperature non-diffusible hydrogen contained in a rolling fatigue region, the rolling fatigue region being a region where rolling fatigue has been produced by rolling contact, within the steel rolling member of the rolling device operated under the operating conditions and an assessment step of assessing the hydrogen environment severity, based on a measurement result in the measurement step.

An element analysis device is provided, which can quantitatively analyze an H element contained in a sample gas with high accuracy. The element analysis device is provided with a heating furnace for heating a crucible having a sample contained therein while a carrier gas is introduced into the heating furnace to vaporize at least a part of the sample to generate a sample gas containing the H element and then deriving the sample gas with the carrier gas as a mixed gas and a mass spectrometer for quantitatively analyzing at least one element contained in the sample gas in the mixed gas that has been derived from the heating furnace, wherein the mass spectrometer quantitatively analyzes the H element contained as an H.sub.2O component in the mixed gas as the H element contained in the sample gas.

The present invention is a sensor for measuring a risk of hydrogen embrittlement of industrial equipment including a metallic wall in a reactor or in a pipeline comprising a body having a closed cavity including an end containing a pressure sensor which measures pressure within the closed cavity, the metallic wall having a wall thickness measured between inner and outer surfaces thereof, and wherein a ratio of thickness of the metallic wall to thickness of the industrial equipment ranges from 1/3 to 1/10.

The present invention is a sensor for measuring a risk of hydrogen embrittlement of industrial equipment including a metallic wall in a reactor or in a pipeline comprising a body having a closed cavity including an end containing a pressure sensor which measures pressure within the closed cavity, the metallic wall having a wall thickness measured between inner and outer surfaces thereof, and wherein a ratio of thickness of the metallic wall to thickness of the industrial equipment ranges from 1/3 to 1/10.