Patent classifications
G01N33/287
METHOD FOR ESTIMATING SULFUR COMPONENT CONCENTRATION IN GASOLINE
A method is provided that allows the sulfur component concentration in gasoline to be estimated to high precision. The measuring method of the disclosure is a method of measuring the concentration of sulfur components in gasoline that contains sulfur components and aromatic components. The measuring method of the disclosure comprises: (A1) removing a portion of the gasoline by gasification to lower the proportion of the aromatic component concentration with respect to the sulfur component concentration in the gasoline, (A2) measuring values related to the refractive index of the gasoline, and (A3) measuring the sulfur component concentration in the gasoline based on the values related to the refractive index.
SAMPLING CHAMBER WITH HYDROGEN SULFIDE-REACTIVE SCAVENGER
Systems, methods and devices for analyzing a sample of fluid extracted from a hydrocarbon-producing geological formation to detect a quantitative amount of hydrogen sulfide or disclosed. The systems methods and devices involve including a scavenger within a sample compartment to react with the hydrogen sulfide therein. The concentration of hydrogen sulfide in the sample may be derived as a function of the amount of scavenger remaining in the sample after reaction with hydrogen sulfide, an amount of byproduct of a reaction between the scavenger and the hydrogen sulfide, or an amount of hydrogen sulfide as measured following a secondary reaction that releases the hydrogen sulfide from the scavenger.
Sampling chamber with hydrogen sulfide-reactive scavenger
Systems, methods and devices for analyzing a sample of fluid extracted from a hydrocarbon-producing geological formation to detect a quantitative amount of hydrogen sulfide or disclosed. The systems methods and devices involve including a scavenger within a sample compartment to react with the hydrogen sulfide therein. The concentration of hydrogen sulfide in the sample may be derived as a function of the amount of scavenger remaining in the sample after reaction with hydrogen sulfide, an amount of byproduct of a reaction between the scavenger and the hydrogen sulfide, or an amount of hydrogen sulfide as measured following a secondary reaction that releases the hydrogen sulfide from the scavenger.
Graphene-based PPB level sulfur detector in fuels
A sensitive and selective, in-line method to measure and validate the sulfur content at ppb levels in both the liquid and gas phase of fuel. The method includes etching graphene, for example to form a mesa structure comprising horizontal or vertical lines or an array of multidentate star features; functionalizing the etched graphene and attaching metal oxide nanoparticles to the functionalized graphene to form a device; exposing the device to a fuel in the gas or liquid phase; detecting a change in conductivity when sulfur is present in the fuel; and recovering the device for future use. Also disclosed is the related in-line graphene-based ppb level sulfur detector for fuels.
Exhaust gas analysis method and exhaust gas analysis system
In order to separately evaluate an influence degree of fuel and an influence degree of lubricating oil with respect to particulate matters contained in exhaust gas, an exhaust gas analysis method includes: analyzing particulate matters contained in the exhaust gas exhausted from an engine, thereby making it possible to analyze the particulate matters derived from the lubricating oil by using isooctane as a fuel.
ELEMENTAL SULFUR ANALYSIS IN FLUIDS
Robust methods for quantitating the amount of elemental sulfur in a fluid whereby a caustic solution is mixed with the fluid, and the elemental sulfur present in the fluid reacts to form a colored solution that can be compared to a series of standards. The methods can be performed in a laboratory or the field and allow for real time feedback. Once the concentration of the elemental sulfur is known, appropriate methods of treatment can proceed. Test kits for performing the methods in the field are also described.
Method of analyzing an environmental sample
A method of directly analyzing an environmental sample, such as a crude oil sample, to determine distillation ranges, identify elements therein, and/or identify impurities. The method includes performing multi-element scanning thermal analysis (MESTA) on the environmental sample to obtain a thermogram of the elements within the environmental sample, wherein peak information within the thermogram indicates the presence of the elements, compounds, and/or impurities within the particular environmental sample.
Apparatus and downhole tools for measuring hydrogen sulfide in downhole fluids
A method of determining a concentration of hydrogen sulfide in a fluid comprises exposing a sensor to the fluid, the sensor comprising a pair of electrodes defining a gap therebetween and a sensing material bridging the gap between the electrodes, measuring a value of an electrical parameter of the sensor at an applied frequency of greater than about 10 kHz and a voltage of less than about 1.0 volt when the sensor is exposed to the fluid, and determining the concentration of hydrogen sulfide in the fluid based at least in part on the measured value of the electrical parameter. Related apparatuses and methods are also disclosed.
SYSTEM AND METHOD OF CHARACTERIZING CRUDE OIL AND ITS DERIVATIVES BY COMBINING TOTAL SULFUR DETERMINATION AND FT-ICR MASS SPECTROMETRY
A method and system to determine mass fraction of aromatic hydrocarbons, sulfur-multi-sulfur, sulfur-nitrogen, multi-sulfur-multi-nitrogen, and nitrogen containing aromatic compound classes present within a petroleum sample. The invention uses total sulfur determination, total nitrogen determination, and elemental formulas determination, with the latter determined through time-of-flight mass spectrometric analysis with atmospheric pressure photo ionization and Fourier-transform ion-cyclotron resonance mass spectrometric analysis with atmospheric pressure photo ionization.
SYSTEM AND METHOD FOR DIAGNOSING A CONDITION OF AN ENGINE
A method and system for diagnosing a condition of an air-breathing aircraft engine are described. The method comprises obtaining a sample of lubricating fluid from the engine, filtering the sample to obtain a plurality of particles from the lubricating fluid, obtaining chemical composition data for the plurality of particles, determining a quantity of volcanic ash in the lubricating fluid by considering each one of the particles as composed partially of volcanic ash and partially of at least one other material and analyzing the chemical composition data, the volcanic ash having associated thereto a predetermined chemical composition, and diagnosing a condition of the engine based on the quantity of volcanic ash found in the lubricating fluid.