The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, hot toner slurry is added to an external reactor containing a coolant comprised of previously cooled toner slurry in combination with cooled de-ionized water. The previously cooled toner slurry found in the coolant has the same toner composition as the incoming hot toner slurry. Also, the amount of the coolant in the external reactor is equivalent to the amount of incoming hot toner slurry. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling process results in an improvement to the toner performance especially a decrease in the overall toner usage.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, hot toner slurry is added to an external reactor containing a coolant comprised of previously cooled toner slurry in combination with cooled de-ionized water. The previously cooled toner slurry found in the coolant has the same toner composition as the incoming hot toner slurry. Also, the amount of the coolant in the external reactor is equivalent to the amount of incoming hot toner slurry. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling process results in an improvement to the toner performance especially a decrease in the overall toner usage.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, an amount of hot toner slurry is added to an external reactor holding an amount of chilled cooling water, wherein the temperature of the chilled cooling water in the external reactor is from about 8 C. to about 25 C. The amount of the chilled cooling water in the external reactor is about 10% to about 40% lower compared to the amount of the added hot toner slurry. Toner prepared using this crash cooling method is cooled at a rate of less than 0.8 C./min. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling processes using less water results in an improvement to the toner's print density and usage efficiency.

A toner that is suppressed from deteriorating owing to its long-term use and can maintain high transferability. The toner includes: a toner particle containing an amorphous polyester serving as a binder resin and a polymer A; and inorganic fine particles, wherein the polymer A includes a graft copolymer of a polyolefin and a vinyl-based polymer unit having a carboxylate anion group, and a metal ion having a valence of 2 or more.

Provided is a magnetic toner having a toner particle containing a binder resin and a magnetic body, wherein the binder resin contains a polymer A having a first monomer unit and a second monomer unit, the first polymerizable monomer is at least one selected from the group consisting of the (meth)acrylic acid esters having C.sub.18-36 alkyl groups, a content of the first monomer unit and a content of the second monomer unit based on the total moles of all monomer units in the polymer A are respectively 5.0 to 60.0 mol % and 20.0 to 95.0 mol %, and assuming that an SP value of the first monomer unit and the second monomer unit are taken as SP.sub.11 (J/cm.sup.3).sup.0.5 and SP.sub.21(J/cm.sup.3).sup.0.5, respectively, 3.00(SP.sub.21SP.sub.11)25.00 is satisfied, and an oil absorption of the magnetic body is 5 to 40 ml/100 g.

The invention relates to a toner for development of electrostatic images excellent in fusing property on polypropylene films and excellent in rubfastness of printed images, and a resin composition for a toner for development of electrostatic images. The toner for development of electrostatic images and the resin composition for a toner for development of electrostatic images each contain an amorphous polyester-based resin A and a crystalline polyester-based resin C, wherein the amorphous polyester-based resin A has a constituent moiety derived from a polyester resin, and a constituent moiety derived from a reactive functional group-having modified polyolefin-based polymer A, the polyester resin-derived constituent moiety and the modified polyolefin-based polymer A-derived constituent moiety being bonded via a covalent bond, and the amount of the modified polyolefin-based polymer A-derived constituent moiety is 5% by mass or more and 30% by mass or less relative to the total amount of the resin component in the toner.

By controlling the migration to the toner particle surface of the crystalline polyester present in the toner particle, a toner is provided that exhibits an excellent durability in long-term use, a stable charging performance after holding in a high-temperature, high-humidity environment, and an excellent low-temperature fixability, in which the toner having a toner particle that contains an amorphous resin, a crystalline polyester, and a wax, wherein the toner particle includes, at the surface thereof, a coat layer containing a cyclic polyolefin resin.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In particular, the crash cooling process involves the addition of a toner slurry having a temperature between 70 C. and 90 C. to an equivalent amount of cold water having a temperature between 5 C. and 20 C. Polyester and styrene acrylic toners as well as polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this cooling process results in an improvement to the amount of toner waste, thereby achieving a higher toner usage efficiency for an electrophotographic printing system.

The present invention relates to a binder resin composition for toners for development of electrostatic images capable of giving a toner excellent in fusing properties on PP films, a toner for development of electrostatic images containing the binder resin composition, a printing method using the toner, and a printed material. [1] A binder resin composition for toners for development of electrostatic images, including a polyester-based resin and polyolefin particles, wherein the polyolefin particles contain a polymer having a polymer skeleton of olefin having 2 or more and 3 or less carbon atoms, the volume median diameter (D.sub.50) of a small particle size component, as measured according to a dynamic light scattering method using a dispersion S of a small particle size component obtainable according to Methods 1 and 2, is 20 nm or more and 400 nm or less, the content of a large particle size component obtainable according to Method 2 is 0% by mass or more and 30% by mass or less relative to the total amount of the large particle size component and the small particle size component, and the content of the small particle size component is 70% by mass or more and 100% by mass or less relative to the total amount of the large particle size component and the small particle size component, and the melting endothermic energy amount of the small particle size component is 3 J/g or more and 10 J/g or less; [2] a toner for development of electrostatic images including the binder resin composition for toners for development of electrostatic images according to the above [1] in an amount of 20% by mass or more and 100% by mass or less in the binder resin therein, and including a releasing agent having a melting point of 60 C. or higher and 100 C. or lower in an amount of 1 part by mass or more and 10 parts by mass or less relative to 100 parts by mass of the binder resin; [3] a printing method including printing on a plastic film according to an electrophotographic method with the toner for development of electrostatic images according to the above [2]; and [4] a printed material obtainable according to the method of the above [3].

The present invention provides a toner for development of electrostatic images including a polyester-based resin and a polypropylene-based wax, which is excellent in fusing properties on a polypropylene film. The present invention relates to [1] a resin binder composition for toners for development of electrostatic images which has an endothermic amount ratio H.sub.CW/W of not less than 0.10 and not more than 0.80, [2] a resin binder composition for toners for development of electrostatic images in which a volume-median particle size (D.sub.50) of a wax as a whole contained therein is not less than 1 m and not more than 50 m; a volume-median particle size (D.sub.50) of a small particle size component of the wax is not less than 20 nm and not more than 400 nm; and a content of the small particle size component in the wax is not less than 20% by mass and not more than 90% by mass, [3] a process for producing a resin binder composition for toners for development of electrostatic images in which a polypropylene-based wax is added to a reaction system prior to addition polymerization upon production of a composite resin as a resin binder; and [4] a toner for development of electrostatic images including the resin binder composition as described in the above [1] or [2].