Patent classifications
G03G9/08722
MAGNETIC TONER AND METHOD FOR MANUFACTURING MAGNETIC TONER
Provided is a magnetic toner having a toner particle containing a binder resin and a magnetic body, wherein the binder resin contains a polymer A having a first monomer unit and a second monomer unit, the first polymerizable monomer is at least one selected from the group consisting of the (meth)acrylic acid esters having C.sub.18-36 alkyl groups, a content of the first monomer unit and a content of the second monomer unit based on the total moles of all monomer units in the polymer A are respectively 5.0 to 60.0 mol % and 20.0 to 95.0 mol %, and assuming that an SP value of the first monomer unit and the second monomer unit are taken as SP.sub.11 (J/cm.sup.3).sup.0.5 and SP.sub.21(J/cm.sup.3).sup.0.5, respectively, 3.00(SP.sub.21SP.sub.11)25.00 is satisfied, and an oil absorption of the magnetic body is 5 to 40 ml/100 g.
TWO-COMPONENT DEVELOPER
Provided is a two-component developer has a toner including a toner particle including a binder resin, and a magnetic carrier, wherein the binder resin includes a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer, the first polymerizable monomer is a specific (meth)acrylic acid ester, a content and an SP value of the first and second monomer units in the polymer A fall within respective specific ranges, the magnetic carrier has a magnetic core and a coating resin of the surface of the magnetic core, the coating resin includes a polymer B having monomer units (a) and (b), each SP value of the monomer units (a) and (b) is a specific value.
SUPPORT MATERIAL FORMULATION AND ADDITIVE MANUFACTURING PROCESSES EMPLOYING SAME
Novel support material formulations, characterized as providing a cured support material with improved dissolution rate, while maintaining sufficient mechanical strength, are disclosed. The formulations comprise a water-miscible non-curable polymer, a first water-miscible, curable material and a second, water-miscible material that is selected capable of interfering with intermolecular interactions between polymeric chains formed upon exposing the first water-miscible material to curing energy. Methods of fabricating a three-dimensional object, and a three-dimensional object fabricated thereby are also disclosed.
Electrophotographic toner binder, and toner composition
The present invention provides an electrophotographic toner binder containing, as a main component, a polymer whose constituent monomer is a monomer having an ethylenically unsaturated bond, the electrophotographic toner binder being excellent in low-temperature fixability, hot-offset resistance, and storage stability. The present invention provides an electrophotographic toner binder containing a polymer (A) containing a monomer (a) and a monomer (x) different from the monomer (a) as essential constituent monomers, wherein the monomer (a) is a (meth)acrylate having a C18-C36 acyclic hydrocarbon group, the polymer (A) has an acid value of 40 or less, and the polymer (A) satisfies the following relational expression (1):
1.1 (cal/cm.sup.3).sup.0.5|SP(x)SP(a)|8.0 (cal/cm.sup.3).sup.0.5relational expression (1):
wherein SP(a) is the SP value of a structural unit derived from the monomer (a) constituting the polymer (A); and
SP(x) is the SP value of a structural unit derived from the monomer (x) different from the monomer (a) constituting the polymer (A).
ELECTROPHOTOGRAPHIC TONER BINDER, AND TONER COMPOSITION
The present invention provides an electrophotographic toner binder containing, as a main component, a polymer whose constituent monomer is a monomer having an ethylenically unsaturated bond, the electrophotographic toner binder being excellent in low-temperature fixability, hot-offset resistance, and storage stability. The present invention provides an electrophotographic toner binder containing a polymer (A) containing a monomer (a) and a monomer (x) different from the monomer (a) as essential constituent monomers, wherein the monomer (a) is a (meth)acrylate having a C18-C36 acyclic hydrocarbon group, the polymer (A) has an acid value of 40 or less, and the polymer (A) satisfies the following relational expression (1):
1.1 (cal/cm.sup.3).sup.0.5|SP(x)SP(a)|8.0 (cal/cm.sup.3).sup.0.5relational expression (1):
wherein SP(a) is the SP value of a structural unit derived from the monomer (a) constituting the polymer (A); and
SP(x) is the SP value of a structural unit derived from the monomer (x) different from the monomer (a) constituting the polymer (A).
Binder resin composition for electrostatic image developing toners
The present invention provides a toner for development of electrostatic images including a polyester-based resin and a polypropylene-based wax, which is excellent in fusing properties on a polypropylene film. The present invention relates to [1] a resin binder composition for toners for development of electrostatic images which has an endothermic amount ratio H.sub.CW/W of not less than 0.10 and not more than 0.80, [2] a resin binder composition for toners for development of electrostatic images in which a volume-median particle size (D.sub.50) of a wax as a whole contained therein is not less than 1 m and not more than 50 m; a volume-median particle size (D.sub.50) of a small particle size component of the wax is not less than 20 nm and not more than 400 nm; and a content of the small particle size component in the wax is not less than 20% by mass and not more than 90% by mass, [3] a process for producing a resin binder composition for toners for development of electrostatic images in which a polypropylene-based wax is added to a reaction system prior to addition polymerization upon production of a composite resin as a resin binder; and [4] a toner for development of electrostatic images including the resin binder composition as described in the above [1] or [2].
IMAGE FORMING METHOD
Provided is an image forming method using an electrostatic image developing toner containing: toner mother particles including a binder resin; and an external additive, wherein the binder resin contains a vinyl resin in an amount of 40 mass % or more with respect to the total amount of the binder resin, the image forming method including a step of: forming an image so that an image surface resistance value at 70 C. by a temperature change method of the formed image is set to be 510.sup.13 or less.
OVERCOATED PRINTED SUBSTRATE
Described herein is a method of providing an overcoated printed substrate. The method may comprise: providing a printed substrate comprising a primer layer disposed on a print substrate and a liquid electrostatically printed layer disposed on the primer layer; and applying a UV curable overcoat composition to the printed layer of the printed substrate, wherein the UV curable overcoat composition comprises a UV curable resin and inorganic nanoparticles dispersed therein.
Toner and method of producing toner
A toner includes a toner particle containing a resin component containing an olefin copolymer, wherein the olefin copolymer includes a specific monomer unit Y1 and a specific monomer unit Y2, and the content of the olefin copolymer in the resin component is more than 50 mass % based on the total mass of the resin component, and the olefin copolymer has a melting point of 80 C. or more and 150 C. or less.
Method for producing toner
A method for producing a toner includes a step (1) of forming resin microparticles in an aqueous medium in the presence of a surfactant, a step (2) of aggregating the resin microparticles to form aggregated particles, and a step (3) of heating and the aggregated particles and allowing the aggregated particles to coalesce to form toner particles, in which a resin component in the resin microparticles contains an olefinic copolymer and resin A, the resin A has an acid value of 1 mgKOH/g or more and 50 mgKOH/g or less, the resin A has a SP value of 19.0 (J/cm.sup.3).sup.0.5 or more and 21.0 (J/cm.sup.3).sup.0.5 or less, and the resin component has an olefinic copolymer content of 50% by mass or more with respect to the total mass of the resin component.