A method for producing a toner includes a step (1) of forming resin microparticles in an aqueous medium in the presence of a surfactant, a step (2) of aggregating the resin microparticles to form aggregated particles, and a step (3) of heating and the aggregated particles and allowing the aggregated particles to coalesce to form toner particles, in which a resin component in the resin microparticles contains an olefinic copolymer and resin A, the resin A has an acid value of 1 mgKOH/g or more and 50 mgKOH/g or less, the resin A has a SP value of 19.0 (J/cm.sup.3).sup.0.5 or more and 21.0 (J/cm.sup.3).sup.0.5 or less, and the resin component has an olefinic copolymer content of 50% by mass or more with respect to the total mass of the resin component.

The present invention provides a toner for development of electrostatic images including a polyester-based resin and a polypropylene-based wax, which is excellent in fusing properties on a polypropylene film. The present invention relates to [1] a resin binder composition for toners for development of electrostatic images which has an endothermic amount ratio H.sub.CW/W of not less than 0.10 and not more than 0.80, [2] a resin binder composition for toners for development of electrostatic images in which a volume-median particle size (D.sub.50) of a wax as a whole contained therein is not less than 1 m and not more than 50 m; a volume-median particle size (D.sub.50) of a small particle size component of the wax is not less than 20 nm and not more than 400 nm; and a content of the small particle size component in the wax is not less than 20% by mass and not more than 90% by mass, [3] a process for producing a resin binder composition for toners for development of electrostatic images in which a polypropylene-based wax is added to a reaction system prior to addition polymerization upon production of a composite resin as a resin binder; and [4] a toner for development of electrostatic images including the resin binder composition as described in the above [1] or [2].

Provided is a toner comprising a toner particle containing a binder resin, a resin A, and a pigment, wherein the resin A has a pKa of at least 6.0 and not more than 9.0, and also has a hydrophobic parameter HPA of at least 0.65 and not more than 0.95.

A toner comprising a toner particle including a resin component, wherein the resin component includes an olefin resin and an olefin copolymer including a hydroxyl group, the olefin resin has a specific monomer unit Y1, the olefin copolymer including a hydroxyl group has a specific monomer unit Z1 and Z2, a hydroxyl value of the olefin resin is not more than 10 mg KOH/g, a hydroxyl value of the olefin copolymer including a hydroxyl group is at least 20 mg KOH/g and not more than 250 mg KOH/g, and a content of the olefin resin in the resin component is more than 50 mass % with respect to a total mass of the resin component.

The present invention relates to a toner for electrostatic charge image development, including toner base particles containing a binder resin containing as a main component a vinyl resin having a constitutional unit derived from a monomer having an acid group, and aluminum, wherein a concentration of the aluminum in the toner base particles, as measured by radio inductively coupled plasma emission spectral analysis, is from 900 to 2,200 ppm. According to the present invention, there is provided a means for improving the environmental stability of electrification, and the glossiness and the image density of the image to be formed in a good balance while maintaining sufficient low temperature fixability in a toner for electrostatic charge image development.

An electrostatic charge image developing white toner according to the present invention includes toner base particles including rutile type titanium oxide particles as colorant and a binder resin. The rutile type titanium oxide particles are composed of two groups Ga and Gb of rutile type titanium oxide particles have different volume particle size distribution. A volume particle size distribution curve of the rutile type titanium oxide particles represents diameter on a horizontal axis and volume ratio on a vertical axis and has two main peaks. Diameters Da and Db of peak top positions of the two main peaks are respectively within a range of 100 to 500 nm, and satisfy following Relational expressions:

25 nmDbDa200 nm(Relational expression 1):

(mass of Ga):(mass of Gb)=5:95 to 30:70(Relational expression 2):

A toner includes a toner particle containing a resin component containing an olefin copolymer, wherein the olefin copolymer includes a specific monomer unit Y1 and a specific monomer unit Y2, and the content of the olefin copolymer in the resin component is more than 50 mass % based on the total mass of the resin component, and the olefin copolymer has a melting point of 80 C. or more and 150 C. or less.

A toner including: a binder resin containing an ethylene-vinyl acetate copolymer; a polysiloxane derivative A represented by structural formula 1; and a polysiloxane derivative B represented by structural formula 2:

##STR00001##

(in structural formula 1, R.sub.1 to R.sub.10 each independently represent a methyl group or a phenyl group, and l, m and n each independently represent an integer of at least 1)

##STR00002##

(in structural formula 2, at least one of R.sub.11 to R.sub.20 is an organic group having a C.sub.4-30 alkyl group, a C.sub.4-30 alkoxy group, an acrylic group, an amino group, a methacrylic group or a carboxyl group, the remaining groups among R.sub.11 to R.sub.20 each independently represent a methyl group or a phenyl group, and p, q and r each independently represent an integer of at least 1).

A support material toner particle for use in xerographic additive manufacturing includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of a desired build material toner T.sub.g. A xerographic toner system includes a build toner material and a support toner material, the support toner material includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of the build material toner T.sub.g. A method of making a support toner material includes blending polyvinyl alcohol with blend additives including a chitosan and polyvinylpyrrolidone and forming support toner particles after the blending step.

The present invention relates to a toner for electrostatic charge image development, including toner base particles containing a binder resin containing as a main component a vinyl resin having a constitutional unit derived from a monomer having an acid group, and aluminum, wherein a concentration of the aluminum in the toner base particles, as measured by radio inductively coupled plasma emission spectral analysis, is from 900 to 2,200 ppm. According to the present invention, there is provided a means for improving the environmental stability of electrification, and the glossiness and the image density of the image to be formed in a good balance while maintaining sufficient low temperature fixability in a toner for electrostatic charge image development.