Patent classifications
G03G9/08724
Positive-charging toner
Provided is a positive-charging toner having a toner particle that contains a binder resin, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is at least one selected from the group consisting of (meth)acrylic acid esters having a C18 to C36 alkyl group, the content of the first monomer unit in the polymer A is 5.0 to 60.0 mol % and the content of the second monomer unit is 20.0 to 95.0 mol %, SP.sub.11 of the first monomer unit and SP.sub.21 of the second monomer unit satisfy 3.00(SP.sub.21SP.sub.11)25.00, and the work function of the toner is 5.0 to 5.4 V.
TONER BINDER AND TONER
The present invention relates to a toner binder containing: a polyester resin (A); and a vinyl resin (B), wherein the polyester resin (A) is a resin obtained by crosslinking a polyester (A1) by one or more carbon-carbon bonds, the vinyl resin (B) is a polymer containing a monomer (a) as an essential constituent monomer, the monomer (a) is a C21-C40 (meth)acrylate having an acyclic hydrocarbon group, and the weight proportion of the monomer (a) in monomers constituting the vinyl resin (B) is 15 to 99% by weight based on the weight of the vinyl resin (B).
Toner and method for producing toner
A toner has a toner particle including a binder resin, the binder resin includes a polymer A, the polymer A contains a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is selected from (meth)acrylic acid esters having an alkyl group having 18 to 36 carbon atoms, the content of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol %, the content of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, the SP value of the first monomer unit and the SP value of the second monomer unit satisfy a predetermined relationship, the polymer A includes a predetermined polyvalent metal, and the content of the polyvalent metal is 25 ppm to 500 ppm.
Image forming method
Provided is an image forming method using an electrostatic image developing toner containing: toner mother particles including a binder resin; and an external additive, wherein the binder resin contains a vinyl resin in an amount of 40 mass % or more with respect to the total amount of the binder resin, the image forming method including a step of: forming an image so that an image surface resistance value at 70 C. by a temperature change method of the formed image is set to be 510.sup.13 or less.
TONER
A toner comprising a toner particle comprising: a toner base particle; and an organosilicon polymer at a surface of the toner base particle, wherein protruded portions constituted from the organosilicon polymer are present at the surface of the toner base particle, when a specific reciprocating shaking test is carried out, the toner particle is measured in terms of a total area S of a surface of the toner particle and an area Sc of regions of the surface of the toner base particle coated with the organosilicon polymer at the surface of the toner particle before and after the test, values of Sc/S for the toner particle before and after the test are respectively defined as R.sub.0 and R.sub.1, the value of R.sub.0 is 0.30 to 0.70, a value of (R.sub.0R.sub.1)/R.sub.0 is 0.20 or less, and a storage elastic modulus at 100 C. of the toner is 8000 to 50,000 Pa.
Toner
A toner comprising: a toner particle that contains a resin component and a silicone compound, wherein the resin component contains at least 50 mass % of olefin resin; a content of the silicone compound is from 1 mass part to 42 mass parts per 100 mass parts of the resin component; a weight-average molecular weight of the silicone compound as measured by GPC is from 1,000 to 25,000; and a content, in a molecular weight distribution of the silicone compound as measured by GPC, of a component having a weight-average molecular weight of not more than 500 is not more than 0.05 mass % of the silicone compound.
TONER AND METHOD FOR PRODUCING TONER
A toner has a toner particle including a binder resin, the binder resin includes a polymer A, the polymer A contains a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is selected from (meth)acrylic acid esters having an alkyl group having 18 to 36 carbon atoms, the content of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol %, the content of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, the SP value of the first monomer unit and the SP value of the second monomer unit satisfy a predetermined relationship, the polymer A includes a predetermined polyvalent metal, and the content of the polyvalent metal is 25 ppm to 500 ppm.
TONER AND TWO-COMPONENT DEVELOPER
A toner having an inorganic fine particle and a toner particle containing a binder resin, wherein the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer that is different from the first polymerizable monomer, the first polymerizable monomer is selected from the (meth)acrylic acid esters each having a C.sub.18-36 alkyl group, the content of the first monomer unit in the polymer A is within a specific range, the SP value of the first monomer unit and the SP value of the second monomer unit are in a specific relationship to one another, the inorganic fine particle is surface treated with a compound having an alkyl group, and the volume resistivity of the inorganic fine particle is within a specific range.
TONER AND METHOD FOR PRODUCING TONER
Provided is a toner has a toner particle containing a binder resin and is characterized in that the binder resin contains a polymer A, which is a polymer of a composition containing a first polymerizable monomer, a second polymerizable monomer and a crosslinking agent, the first polymerizable monomer is at least one monomer selected from the group consisting of (meth)acrylic acid esters having an alkyl group with 18 to 36 carbon atoms, the crosslinking agent has two or more polymerizable double bonds, a content of the first polymerizable monomer in the composition is 5.0 to 60.0 mol %, a content of the second polymerizable monomer is 20.0 to 95.0 mol %, and when the SP values of the first polymerizable monomer, the second polymerizable monomer and the crosslinking agent are denoted by SP.sub.12, SP.sub.22 and SP.sub.C2, respectively, the formulae 0.60(SP.sub.22SP.sub.12)15.00 and SP.sub.12<SP.sub.C2<(SP.sub.22+3.00) are satisfied.
POSITIVE-CHARGING TONER
Provided is a positive-charging toner having a toner particle that contains a binder resin, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer, the first polymerizable monomer is at least one selected from the group consisting of (meth)acrylic acid esters having a C18 to C36 alkyl group, the content of the first monomer unit in the polymer A is 5.0 to 60.0 mol % and the content of the second monomer unit is 20.0 to 95.0 mol %, SP.sub.11 of the first monomer unit and SP.sub.21 of the second monomer unit satisfy 3.00(SP.sub.21SP.sub.11)25.00, and the work function of the toner is 5.0 to 5.4 V.