A method of recycling and reusing a tap water-soluble sulfonated polymer material from a structural component made using an additive manufacturing process comprises dissolving the structural component in water to disperse the sulfonated polymer material into the water. The sulfonated polymer material is precipitated from the water and recovered; then dried and reformed into a form suitable for subsequent use as a consumable feedstock in a subsequent additive manufacturing process.

A support material toner particle for use in xerographic additive manufacturing includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of a desired build material toner T.sub.g. A xerographic toner system includes a build toner material and a support toner material, the support toner material includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of the build material toner T.sub.g. A method of making a support toner material includes blending polyvinyl alcohol with blend additives including a chitosan and polyvinylpyrrolidone and forming support toner particles after the blending step.

A liquid developer includes a carrier liquid and a toner particle whose surface is treated by a polyamine, wherein an amount of sodium ion to be eluted in 1 g of the toner particles is 0.04 mg or less.

The toner binder of the present invention contains a crystalline resin (A) and a resin (B) that is a polyester resin or its modified resin, the polyester resin being obtained by reaction of an alcohol component (X) and a carboxylic acid component (Y) as raw materials, wherein a temperature (Tp) of the top of an endothermic peak derived from the crystalline resin (A) as measured by a differential scanning calorimeter (DSC) is in the range of 40 C. to 100 C., and endothermic peak areas S.sub.1 and S.sub.2 during heating satisfy the following equation.

(S.sub.2/S.sub.1)10035(1)

S.sub.1 is an area of the endothermic peak derived from the crystalline resin (A) in the first heating process, and S.sub.2 is an area of the endothermic peak derived from the crystalline resin (A) in the second heating process, when the toner binder is heated, cooled, and heated.

Composite materials such as composite particles have a solid non-elastomeric continuous phase made of an organic polymer having a glass transition temperature of at least 25 C. Dispersed within this solid non-elastomeric continuous phase are many multi-compartment porous chemically crosslinked elastomeric particles that have a mode particle size of at least 1 m and up to and including 10 m. The composite particles can be used as toner particles in electrophotographic imaging methods to provide fused toner images and especially stacked fused toner images.

A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having an engineering-grade thermoplastic material and a charge control agent. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.