A toner includes toner particles. Each of the toner particles includes a composite core and a shell layer covering a surface of the composite core. Each of the composite cores is a composite of a toner core and foamable particles provided on a surface of the toner core. An amount of the foamable particles is at least 0.3% by mass relative to mass of the toner cores. Each of the foamable particles includes a base particle and a coat layer covering a surface of the base particle. The base particles are non-foamable. The coat layers include a foamable group. The foamable group is bonded to the surfaces of the base particles through a bond including a bond represented by formula OSi.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, an amount of hot toner slurry is added to an external reactor holding an amount of chilled cooling water, wherein the temperature of the chilled cooling water in the external reactor is from about 8 C. to about 25 C. The amount of the chilled cooling water in the external reactor is about 10% to about 40% lower compared to the amount of the added hot toner slurry. Toner prepared using this crash cooling method is cooled at a rate of less than 0.8 C./min. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling processes using less water results in an improvement to the toner's print density and usage efficiency.

The present disclosure relates generally to a method to make a chemically prepared toner that employs a crash cooling process. In the crash cooling process, an amount of hot toner slurry is added to an external reactor holding an amount of chilled cooling water, wherein the temperature of the chilled cooling water in the external reactor is from about 8 C. to about 25 C. The amount of the chilled cooling water in the external reactor is about 10% to about 40% lower compared to the amount of the added hot toner slurry. Toner prepared using this crash cooling method is cooled at a rate of less than 0.8 C./min. Polyester toners and polyester core shell toners having a borax coupling agent between the toner core and toner shell made from this crash cooling processes using less water results in an improvement to the toner's print density and usage efficiency.

A toner comprising a binder resin and a colorant, wherein the toner has a Martens hardness, as measured at a maximum load condition of 2.010.sup.4 N, of from 200 MPa to 1,100 MPa.

A toner having a toner particle having a plurality of fine particles on the surface of a toner base particle, the toner base particle contains a binder resin, wherein a fine particle layer A constituted of a plurality of the fine particles is observed in an EDX mapping image of the constituent elements in a cross section of the toner particle as provided by EDX of the toner particle cross section observed using TEM; a fine particle B, containing a metal compound containing at least one metal element M selected from all the metal elements belonging to Groups 3 to 13, is observed in the fine particle layer A; and the number-average particle diameter D of the fine particle B, the average value H of the thickness of the fine particle layer A, and the standard deviation S on the thickness of the fine particle layer A satisfy prescribed relationships.

A toner comprising a toner particle comprising a binder resin, wherein a layer comprising an organosilicon condensate is present on the surface of the toner particle; the layer comprising the organosilicon condensate further comprises a reaction product of a compound comprising at least one metal element selected from all the metal elements belonging to Groups 3 to 13, and a polyhydric acid; in a backscattered electron image of the toner captured at a magnification of 50,000 times by using a scanning electron microscope, an average value of an area of the reaction product is from 10 nm.sup.2 to 5000 nm.sup.2, and a coefficient of variation of the area of the reaction product is not more than 10.0.

An electrostatic latent image developing toner includes toner particles each including a toner mother particle and an external additive. The toner mother particle includes a composite core and a shell layer. The composite core is a composite of a toner core, organic particles, and polyhedral magnetic particles. The organic particles each contain a releasing agent and adhere to a surface of the toner core. The magnetic particles include magnetic particles adhering to the surface of the toner core and magnetic particles adhering to surfaces of the organic particles. An amount of the magnetic particles is 0.5 parts by mass to 2.0 parts by mass relative to 100 parts by mass of the toner cores. In a cross-sectional image of each toner particle, an area of protruding portions of the magnetic particles, which protrude from the shell layer, accounts for 10% to 75% of an overall area of the magnetic particles.

A toner pack storing a toner is provided in which the toner comprises a first toner particle and a second toner particle, a portion formed by connecting a plurality of protrusions comprising silicon is present on the surface of the second toner particle, the content of the second toner particle relative to the first toner particle in the toner pack is within a specific range, the toner pack has a storage portion and a discharge member, the discharge member has a receiving port, a discharge port, a fixing part to which the storage portion is fixed, and an inclined surface that causes the toner to move toward the discharge port, and the inclined surface that is the closest to the storage portion is at an angle of 45 degrees or more and less than 90 degrees.

A toner comprising a binder resin and a colorant, wherein the toner has a Martens hardness, as measured at a maximum load condition of 2.010.sup.4 N, of from 200 MPa to 1,100 MPa.

Provided is toner that contains a toner particle, and an external additive containing a strontium titanate particle, wherein the toner has an average circularity of at least 0.935 and not more than 0.995, the strontium titanate particle has a number-average primary particle diameter of at least 10 nm and not more than 60 nm, the strontium titanate particle has a peak in the range of 39.7000.150 and a peak in the range of 46.2000.150 in a CuK x-ray diffraction spectrum obtained in the 2 range of at least 10 and not more than 90 where is the Bragg angle, and the ratio of the area Sb of the peak at 46.2000.150 to the area Sa of the peak at 39.7000.150 is at least 1.80 and not more than 2.30.