A carrier for developing an electrostatic charge image has magnetic particles and a resin coating that covers the magnetic particles and contains at least one lubricant. The resin coating has a dispersed phase of the lubricant and meets requirement (1). Requirement (1): the lubricant content in a top layer>the lubricant content in a middle layer>the lubricant content in a bottom layer The top, middle, and bottom layers are of the resin coating divided into three in the direction of thickness, and the lubricant content is the percentage area of the dispersed phase of the lubricant in a cross-section of the layer taken along the thickness thereof.

Provided are a ferrite carrier core material for an electrophotographic developer having a full length L.sub.1 of grain boundary and a circumference length L.sub.2 of the core material in a cross-section of the core material, and satisfying a relationship of 2≤L.sub.1/L.sub.2≤9; a carrier for an electrophotographic developer including the ferrite carrier core material and a coating layer containing a resin provided on a surface of the ferrite carrier core material; and an electrophotographic developer including the carrier and a toner.

The invention provides a process for preparing core-shell composite particles comprising a polyester, polymerized ethylenically unsaturated silane compounds, and optionally a hydrophobic surface treatment. The invention further provides a composite particle comprising a polyester and a radically polymerized ethylenically unsaturated silane compound.

The invention provides a process for preparing core-shell composite particles comprising a polyester, polymerized ethylenically unsaturated silane compounds, and optionally a hydrophobic surface treatment. The invention further provides a composite particle comprising a polyester and a radically polymerized ethylenically unsaturated silane compound.

To provide a magnetic core material and carrier for electrophotographic developer, which have small environmental dependence of the electric resistance, can suppress the carrier scattering, and can stably provide good images; a developer contains the carrier; and methods for producing them. The magnetic core material satisfying a value of Formula (1): a+b×10+c+d+e+f, being from 20 to 150, when a fluoride ion amount is denoted by a (ppm), a chloride ion amount is denoted by b (ppm), a bromide ion amount is denoted by c (ppm), a nitrite ion amount is denoted by d (ppm), a nitrate ion amount is denoted by e (ppm), and a sulfate ion amount is denoted by f (ppm), which are measured by a combustion ion chromatography method.

A carrier for forming an electrophotographic image is provided. The carrier includes a core particle comprising a manganese-based ferrite particle having an apparent density of from 2.0 to 2.2 g/cm.sup.3 and a magnetization of from 44 to 52 emu/g in a magnetic field of 500 Oe; and a coating layer coating a surface of the core particle. The coating layer contains a carbon black, an inorganic particle A, and an inorganic particle B. The inorganic particle A and the carbon black each have a concentration gradient in a thickness direction of the coating layer. A concentration of the inorganic particle A increases toward a surface of the coating layer, and a concentration of the carbon black decreases toward the surface of the coating layer.

A carrier for developing an electrostatic charge image has magnetic particles and a resin coating that covers the magnetic particles and contains at least one lubricant. The resin coating has a dispersed phase of the lubricant and meets requirement (1).

Requirement (1): the lubricant content in a top layer>the lubricant content in a middle layer>the lubricant content in a bottom layer

The top, middle, and bottom layers are of the resin coating divided into three in the direction of thickness, and the lubricant content is the percentage area of the dispersed phase of the lubricant in a cross-section of the layer taken along the thickness thereof.

An electrostatic charge image developing carrier includes: magnetic particles; and a resin layer coating the magnetic particles and containing inorganic particles, in which an average particle diameter of the inorganic particles is 5 nm or more and 90 nm or less, an average thickness of the resin layer is 0.6 μm or more and 1.4 μm or less, and a ratio B/A of a surface area B of the electrostatic charge image developing carrier to a plan view area A of the electrostatic charge image developing carrier is 1.020 or more and 1.100 or less when a surface of the electrostatic charge image developing carrier is three-dimensionally analyzed.

An electrostatic charge image developing carrier includes: magnetic particles; and a resin layer coating the magnetic particles and containing inorganic particles, in which an exposed area ratio of the magnetic particles is 0.1% or more and 4.0% or less, an average particle diameter of the inorganic particles is 5 nm or more and 90 nm or less, and a ratio B/A of a surface area B of the electrostatic charge image developing carrier to a plan view area A of the electrostatic charge image developing carrier is 1.020 or more and 1.100 or less when a surface of the electrostatic charge image developing carrier is three-dimensionally analyzed.

A carrier for a developer includes carrier particles. The carrier particles have a sea island structure including a sea portion and an island portion on the surface. The island portion contains a nitrogen-containing silicone resin. The sea portion contains a nitrogen-free silicone resin. The area ratio of the island portion in the total area of the surface of the carrier particle is 20% or more and 40% or less.