A gas sensor element includes a laminate formed of a detecting element section and a heater section, and a porous protection layer covering a forward end portion of the laminate. The detecting element section has one or more cells having a solid electrolyte body and a pair of electrodes. The heater section has a heater. Side surfaces of the solid electrolyte bodies in parallel with the direction of lamination are covered with dense insulating members. The cell-to-be-controlled is temperature controlled by the heater to 600° C. to 830° C. The porous protection layer is formed on the laminate from a forward end portion to a region which has a temperature of 500° C. or higher when the temperature control is performed, and the porous protection layer is not formed in a region which has a temperature of 300° C. or lower when the temperature control is performed.

A gas concentration detection device for detecting a gas concentration using a limiting current type gas concentration sensor. In an application voltage line set to pass through a plurality of limiting current regions for different values of gas concentration, the voltage set by the application voltage line is an identical first voltage value used when an air/fuel ratio corresponding to the gas concentration is in a predetermined first range, is an identical second voltage value different from the first voltage value used when the air/fuel ratio is in a second range adjacent to the first range, and the first voltage value and the second voltage value are switched between the first range and the second range.

A gas sensor includes a sensor element and a contact metal fitting. The sensor element has an element body having an oxygen-ion-conductive solid electrolyte layer; an upper connector electrode disposed outside the element body; a lead disposed outside the element body and electrically conductive to the upper connector electrode; and a first protection layer that covers the lead, where a thickness T1 of a portion covering the lead is 2 .Math.m or more, a porosity P1 is 20% or less, and a height difference D1 relative to the upper connector electrode is 22 .Math.m or less. The contact metal fitting has: a conduction member that projects to the upper connector electrode and is in contact with and electrically conducted to the upper connector electrode; and a support member that projects toward the lead and is in contact with the first protection layer.

A gas sensor element comprises a solid electrolyte layer; a detection electrode provided on one surface of the solid electrolyte layer; a reference electrode provided on another surface of the solid electrolyte layer; a first layer provided on a side where the other surface of the solid electrolyte layer is present, and having a reference gas flow path; and a heater layer provided on a side opposite to a side where the solid electrolyte layer is provided. In the gas sensor element, an introduction flow path is formed as a flow path for guiding the reference gas from outer surfaces of the gas sensor element to the reference gas flow path. The introduction flow path has an opening provided at an outer surface that is perpendicular to a stacking direction of the gas sensor element and is provided on a side opposite to the heater layer.

In a sensor element, a reference gas regulation pump cell pumps in oxygen to the periphery of a reference electrode in which a reference gas is introduced, by the flow of a control current Ip3 between the reference electrode and an outer pump electrode located in a region exposed to a measurement-object gas. An average current density of the reference electrode under the flow of the control current Ip3 is higher than 0 μA/mm.sup.2 and lower than 400 μA/mm.sup.2. The average current density is preferably not higher than 170 μA/mm.sup.2. An average value of the control current Ip3 is preferably higher than 1 μA. The outer pump electrode as a measurement-object gas side electrode of the reference gas regulation pump cell may be provided on an outer surface of a layered body (or more specifically, on a second solid electrolyte layer).

A sensor element 101 of a gas sensor 100 includes a blocking portion 65 including an outer blocking layer 67 that is formed to cover, in an upper surface of a multilayer body, at least a part of an upper closest region 6a where an outer pump electrode 23 is not disposed and a distance up to a third inner cavity 61 is minimal. The outer blocking layer 67 does not have conductivity for one or more among various types of substances containing oxygen. The outer blocking layer 67 is disposed between a lead line 93 for the outer pump electrode and the upper surface of the multilayer body to provide insulation therebetween, and is disposed between an upper connector pad 91 and the upper surface of the multilayer body to provide insulation therebetween. A porous protective layer 24 covers the outer pump electrode 23.

A nitrogen oxide based gas sensor includes: a substrate provided with a beam structure having a MEMS structure; a heater disposed on the substrate; a lower electrode disposed on the heater, a solid electrolyte layer disposed on the lower electrode; an upper electrode disposed on a surface of the solid electrolyte layer facing the lower electrode and configured to introduce a measurement target gas; a cavity portion formed in the substrate; and a gas flow path disposed so as to connect the cavity portion and the lower electrode, wherein the gas sensor is configured to detect a concentration of nitrogen oxide in the measurement target gas.

A control system of an exhaust sensor controlling an exhaust sensor comprises a heater control part controlling a heater and a temperature estimating part estimating a temperature of an exhaust pipe around the exhaust sensor. The heater control part sets the target temperature to a first target temperature after startup of the internal combustion engine and until the estimated temperature of the exhaust pipe reaches a first exhaust pipe temperature, sets the target temperature to a second target temperature from when the estimated temperature of the exhaust pipe reaches the first exhaust pipe temperature to when it reaches a second exhaust pipe temperature, and sets the target temperature to an operating temperature of the electrochemical cell when the estimated temperature of the exhaust pipe reaches the second exhaust pipe temperature.

A sensor element 101 includes an element main body 101a that includes oxygen ion-conductive solid electrolyte layers (1 to 6), and a porous protective layer 90 that covers at least part of the element main body 101a. The porous protective layer 90 includes a porous inner protective layer 92 and a porous outer protective layer 91 disposed on the outer side of the inner protective layer 92 and having a smaller average pore diameter than the inner protective layer 92.

A method for manufacturing a sensor element for detecting (i) a gas component in a measuring gas or (ii) a temperature of the measuring gas includes: introducing at least one functional element into at least one slip at least once in such a way that a slip layer is applied to the functional element, the functional element including at least one solid electrolyte and at least one functional layer; sintering the slip layer on the functional element; grinding the slip layer at least in the area of the at least one functional layer; impregnating the slip layer; and thermally treating the impregnated slip layer.