A sensor element includes an element body including an oxygen-ion-conductive solid electrolyte layer, the element body having a longitudinal direction, a measurement electrode disposed in the element body, a reference electrode disposed in the element body so as to come into contact with a reference gas, and a heater configured to heat the solid electrolyte layer. A center of gravity of the reference electrode overlaps the measurement electrode as viewed in a thickness direction of the solid electrolyte layer. A length of each of the reference electrode and the measurement electrode in a front-rear direction is less than or equal to 1.1 mm, the front-rear direction being a direction along the longitudinal direction of the element body. An area of the reference electrode as viewed in the thickness direction is greater than or equal to 1.0 mm.sup.2.

A gas sensor includes a sensor element, a detection device, a reference gas regulating device. The sensor element includes an element body having disposed therein a measurement-object gas flow section, a measurement-object-gas-side electrode disposed in or out of the element body, a reference electrode disposed within the element body, and a reference gas introducing section that allows a reference gas to be introduced thereinto and to flow therethrough to the reference electrode. The reference gas regulating device allows an oxygen pump-in current to flow between the reference electrode and the measurement-object-gas-side electrode to pump oxygen into around the reference electrode from around the measurement-object-gas-side electrode. A ratio R1/R2 of a reaction resistance R1 of the reference electrode to a diffusion resistance R2 of the reference gas introducing section is greater than or equal to 0.1 and less than or equal to 2.0.

A gas sensor includes a sensor element, a detection device, a reference gas regulating device. The sensor element includes an element body having disposed therein a measurement-object gas flow section, a measurement-object-gas-side electrode disposed in or out of the element body, a reference electrode disposed within the element body, and a reference gas introducing section that allows a reference gas to be introduced thereinto and to flow therethrough to the reference electrode. The reference gas regulating device allows an oxygen pump-in current to flow between the reference electrode and the measurement-object-gas-side electrode to pump oxygen into around the reference electrode from around the measurement-object-gas-side electrode. A ratio R1/R2 of a reaction resistance R1 of the reference electrode to a diffusion resistance R2 of the reference gas introducing section is greater than or equal to 0.1 and less than or equal to 2.0.

A limiting current-type gas sensor element including a plurality of stacked ceramic layers and configured to output a limiting current value which depends on a concentration of a specific gas in a gas to be measured when a certain voltage is applied. The gas sensor element includes a solid electrolyte member having oxygen ion conductivity; a heater that heats the solid electrolyte member; a measurement electrode and a reference electrode provided on the solid electrolyte member; a chamber facing the measurement electrode and into which the gas to be measured is introduced; a gas inlet located to a tip side of the chamber in a longitudinal direction; and a diffusion resistance part provided in the gas inlet. A heating center of the heater is located further to the tip side than an electrode center of the measurement electrode is.

A limiting current-type gas sensor element including a plurality of stacked ceramic layers and configured to output a limiting current value which depends on a concentration of a specific gas in a gas to be measured when a certain voltage is applied. The gas sensor element includes a solid electrolyte member having oxygen ion conductivity; a heater that heats the solid electrolyte member; a measurement electrode and a reference electrode provided on the solid electrolyte member; a chamber facing the measurement electrode and into which the gas to be measured is introduced; a gas inlet located to a tip side of the chamber in a longitudinal direction; and a diffusion resistance part provided in the gas inlet. A heating center of the heater is located further to the tip side than an electrode center of the measurement electrode is.

Methods and apparatus for sensing hydrogen in a mixture of hydrogen and natural gas are provided. One example of the apparatus comprises: a first chamber for receiving air; a second chamber for receiving the mixture of hydrogen and natural gas; a first electrode for adsorbing oxygen molecules from air in the first chamber and for reducing the oxygen molecules to oxide ions; a second electrode; an ionic conductor for transporting the oxide ions from the first electrode to the second electrode in order to cause the transported oxide ions to combine with hydrogen molecules at the second electrode; sensing circuitry for sensing an electrical parameter associated with the combination of the transported oxide ions with the hydrogen molecules at the second electrode; and processing circuitry configured to determine a proportion of hydrogen in the mixture, based at least in part on the electrical parameter sensed by the sensing circuitry.

Methods and apparatus for sensing hydrogen in a mixture of hydrogen and natural gas are provided. One example of the apparatus comprises: a first chamber for receiving air; a second chamber for receiving the mixture of hydrogen and natural gas; a first electrode for adsorbing oxygen molecules from air in the first chamber and for reducing the oxygen molecules to oxide ions; a second electrode; an ionic conductor for transporting the oxide ions from the first electrode to the second electrode in order to cause the transported oxide ions to combine with hydrogen molecules at the second electrode; sensing circuitry for sensing an electrical parameter associated with the combination of the transported oxide ions with the hydrogen molecules at the second electrode; and processing circuitry configured to determine a proportion of hydrogen in the mixture, based at least in part on the electrical parameter sensed by the sensing circuitry.

There is provided a method of manufacturing a gas sensor that includes: forming an insulating layer on a main surface of a substrate; forming a porous oxide layer on the insulating layer; and forming a porous metal layer on the porous oxide layer, wherein the forming the porous metal layer is performed by depositing a constituent material of the porous metal layer in an inclined direction with respect to a normal line of a main surface.

There is provided a method of manufacturing a gas sensor that includes: forming an insulating layer on a main surface of a substrate; forming a porous oxide layer on the insulating layer; and forming a porous metal layer on the porous oxide layer, wherein the forming the porous metal layer is performed by depositing a constituent material of the porous metal layer in an inclined direction with respect to a normal line of a main surface.

In a sensor element for a limiting-current type gas sensor measuring concentration of NOx in a measurement gas, an inner pump electrode located to face a first internal space communicating, under predetermined diffusion resistance, with a gas inlet through which a measurement gas is introduced from an external space is made of a cermet of a Pt—Au alloy and zirconia, and includes a first portion located on a surface farther from a heater part and a second portion located on a surface closer to the heater part from among surfaces opposing each other in the first internal space, an Au content with respect to the Pt—Au alloy as a whole of the second portion is 0.3 wt % or more smaller than that of the first portion, and a total area of the first portion and the second portion is 10 mm.sup.2 to 25 mm.sup.2.