Provided are pre-sintered and sintered zirconia dental ceramic materials. The materials have a gradient in yttria content. The materials may have a gradient in one or more physical/mechanical property and/or one or more optical property. The materials may be made by mixing at least two zirconia ceramic powders having different yttria content. A sintered zirconia dental ceramic material may be in the form of a dental article.

Provided are pre-sintered and sintered zirconia dental ceramic materials. The materials have a gradient in yttria content. The materials may have a gradient in one or more physical/mechanical property and/or one or more optical property. The materials may be made by mixing at least two zirconia ceramic powders having different yttria content. A sintered zirconia dental ceramic material may be in the form of a dental article.

A method for enhancing optical properties of sintered, zirconia ceramic bodies and zirconia ceramic dental restorations is provided. The porous or pre-sintered stage of a ceramic body is treated with an yttrium-containing composition and sintered, resulting in sintered ceramic bodies having enhanced optical properties. The enhanced optical properties may be substantially permanent, remaining for the useful life of the sintered ceramic body.

A method for enhancing optical properties of sintered, zirconia ceramic bodies and zirconia ceramic dental restorations is provided. The porous or pre-sintered stage of a ceramic body is treated with an yttrium-containing composition and sintered, resulting in sintered ceramic bodies having enhanced optical properties. The enhanced optical properties may be substantially permanent, remaining for the useful life of the sintered ceramic body.

A zirconia sintered body is provided and includes yttria and zirconia, containing yttria by a content ranging from 4.5 mol % or more to 6.5 mol % or less and zirconia as the remainder, the total light transmittance of a 1-mm thick sample measured in compliance with JIS K 7361-1 being 46.5% or higher, the three-point bending strength being 700 MPa or higher, and a ratio of an integrated value for the total light transmittance to an integrated value for the parallel light transmittance of a 1-mm thick sample measured at the measurement wavelength ranging from 400 to 700 nm being 1.3% or less.

The present invention relates to a method for additive manufacturing of a position sensitive colored ceramic article comprising: a) providing at least one flowable ceramic component; b) forming a green body by sequential deposition of the ceramic component provided in step a) and optionally a support material not intended to be part of the final article; c) position sensitive application of a coloring substance in a solvent to at least a part of the surface of the green body formed in step b), wherein the coloring substance is applied simultaneously to the sequential deposition; d) heat treatment or curing of at least a part of the green body surface obtained in step c); wherein the method steps a)-d) are at least performed once; e) optionally removing the support material from the green body; and f) sintering the green body to obtain the ceramic article; wherein the coloring substance is a dyestuff according to ISO 18451-1:2019(E). In addition, the present invention relates to a system adapted to perform the method and a control data set configured, when implemented in an additive manufacturing system, to cause the system to execute the steps of the inventive method.

The present invention relates to a spinel glass-ceramic made from a composition with the components 25 to 50% by weight SiO.sub.2, 10 to 35% by weight Al.sub.2O.sub.3, 1 to 15% by weight MgO, 1 to 15% by weight P.sub.2O.sub.5, 1 to 25% by weight ZrO.sub.2 and/or TiO.sub.2, 0 to 20% by weight La.sub.2O.sub.3, 0 to 10% by weight B.sub.2O.sub.3, and 0 to 15% by weight additives. The spinel glass-ceramic contains at least one spinel phase, but no high quartz solid solution phase. The glass-ceramic according to the invention exhibits very high mechanical stability, for example, very high flexural strength, wherein its optical properties can be simultaneously adjusted. In addition, the present invention also relates to a method for producing and the use of the spinel glass-ceramic. Furthermore, the present invention relates to a shaped dental product containing the spinel glass-ceramic.

Lithium silicate glass ceramics and precursors thereof are described, which comprise copper and are characterized by very good mechanical and optical properties and can be used in particular as restorative materials in dentistry.

Lithium silicate glass ceramics and precursors thereof are described, which contain tin and are characterized by very good mechanical and optical properties and can be used in particular as restorative materials in dentistry.

A method for enhancing optical properties of sintered, zirconia ceramic bodies and zirconia ceramic dental restorations is provided. The porous or pre-sintered stage of a ceramic body is treated with an yttrium-containing composition and sintered, resulting in sintered ceramic bodies having enhanced optical properties. The enhanced optical properties may be substantially permanent, remaining for the useful life of the sintered ceramic body.