Provided is an electrophotographic member in which the increase in tackiness is small even in an environment of high temperature and high humidity. The electrophotographic member includes an electroconductive substrate and a surface layer, the surface layer contains resin including at least one of a urethane bond and an amide bond, the resin includes a cationic structure and an anionic structure in a molecule, and also includes a particular main-chain structure with hydrophobicity.

Provided is an electrophotographic photosensitive member, wherein a surface layer of the electrophotographic photosensitive member contains a copolymer of a hole-transportable compound having a polymerizable functional group and a compound represented by the following general formula (1).

Ar.sup.1L.sup.1-P.sup.1).sub.m(1)

The photoconductor includes a conductive support, a photosensitive layer, and a protective layer. The protective layer is a polymer of a radical-polymerizable composition containing a perfluoropolyether compound including a radical-polymerizable functional group, a radical-polymerizable monomer including a radical-polymerizable functional group, and an inorganic fine particle including a radical-polymerizable functional group. The radical-polymerizable functional group of the perfluoropolyether compound is different from the radical-polymerizable functional group of the radical-polymerizable monomer and identical to the radical-polymerizable functional group of the inorganic fine particle.

An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer having a single-layer structure. The photosensitive layer contains a charge generating material, an electron transport material, a polycarbonate resin, and a hole transport material. The electron transport material includes a compound having a halogen atom and represented by general formula (1), (2), (3), (4), or (5). The polycarbonate resin has a terminal group having a fluoro group and represented by general formula (10). The hole transport material includes a compound represented by general formula (20), (21), (22), (23), (24), (25), (26), or (27). A charge of calcium carbonate as measured by charging the calcium carbonate through friction with the photosensitive layer is at least +6.5 C/g. The photosensitive layer has a Vickers hardness of at least 17.0 HV at 45 C.

##STR00001## ##STR00002## ##STR00003##

Provided are an electrophotographic photosensitive member capable of satisfying abrasion resistance and electrical properties and suppressing image deletion, and an electrophotographic apparatus and a process cartridge having the electrophotographic photosensitive member. A surface layer of the electrophotographic photosensitive member contains a polymer of a hole transport material having a polymerizable functional group, wherein the hole transport material has a specific structure.

An electrophotographic photosensitive member, in which occurrences of image defects are suppressed, and a method for manufacturing the electrophotographic photosensitive member are provided. In addition, a process cartridge and an electrophotographic apparatus, which include the electrophotographic photosensitive member, are provided. The surface layer of the electrophotographic photosensitive member contains a cured material, and the cured material is a copolymer of a hole transport compound having a chain-polymerizable functional group and a vinyl ester compound containing a long-chain alkyl group.

A polyarylate resin includes at least one type of repeating unit represented by a general formula (1), at least one type of repeating unit represented by a general formula (2), and a terminal group represented by a general formula (3). R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represent, independently of one another, a hydrogen atom or a methyl group. R.sup.5 and R.sup.6 each represent, independently of each other, a hydrogen atom or a C.sub.1-4 alkyl group. R.sup.5 and R.sup.6 may bond together to represent a C.sub.5-7 cycloalkylidene group. X.sup.1 represents a divalent group represented by a chemical formula (2A), (2B), (2C), or (2D) with the proviso that when only one type of repeating unit represented by the general formula (2) is included, X.sup.1 does not represent a divalent group represented by the chemical formula (2D). R.sup.f represents a chain aliphatic group having at least one fluoro group.

##STR00001##

The photoconductor includes a conductive support, a photosensitive layer, and a protective layer. The protective layer is a polymer of a radical-polymerizable composition containing a perfluoropolyether compound including a radical-polymerizable functional group, a radical-polymerizable monomer including a radical-polymerizable functional group, and an inorganic fine particle including a radical-polymerizable functional group. The radical-polymerizable functional group of the perfluoropolyether compound is different from the radical-polymerizable functional group of the radical-polymerizable monomer and identical to the radical-polymerizable functional group of the inorganic fine particle.

A photoreceptor for electrophotography, a method for manufacturing the photoreceptor, and an electrophotographic device including the photoreceptor are disclosed. The photoreceptor for electrophotography includes a conductive substrate; and a photosensitive layer that is provided on the conductive substrate and that has an outermost surface layer containing at least a resin binder and an electron transport material. The resin binder is composed of a polyarylate resin having a structural unit represented by a Chemical Structural Formula 1, and the electron transport material is composed of a compound having a structure represented by a Structural Formula (ET2-3). The photoreceptor has high sensitivity, low residual electric potential, no light fatigue and sufficient stain resistance.

An electrophotographic photosensitive member includes a conductive base and a single-layer-type photosensitive layer on the conductive base. The photosensitive layer contains a binder resin, a charge generation material, a hole transport material, a fluorine-atom-containing electron transport material, and fluorine-atom-containing resin particles. An amount of the charge generation material in the photosensitive layer is 0.5% by weight or more and less than 2.0% by weight. The charge generation material has a distribution that satisfies Formula (1): 30a/b in a thickness direction of the photosensitive layer where a and b are as defined in the specification, and b may be 0. The fluorine-atom-containing electron transport material has a distribution that satisfies Formula (2): 30c/d in the thickness direction of the photosensitive layer where c and d are as defined in the specification, and d may be 0.