Patent classifications
G03G9/08731
TONER AND METHOD FOR PRODUCING TONER
A toner including toner particles having a resin component containing a crystalline resin and an amorphous resin, in which the resin component contains a tetrahydrofuran-insoluble component, and the content of the tetrahydrofuran-insoluble component with respect to the content of the resin component is 5.0% to 80.0% by mass, wherein a maximum endothermic peak temperature of the tetrahydrofuran-insoluble component is 55.0 to 80.0° C., and the amount of heat absorption in the maximum endothermic peak of the tetrahydrofuran-insoluble component is 10.0 to 80.0 Pa, and toner particles have a structure which comprises a matrix containing the crystalline resin and domains containing the amorphous resin.
Toner binder and toner
The present invention relates to a toner binder containing: a polyester resin (A); and a vinyl resin (B), wherein the polyester resin (A) has an acid value of 2 mg KOH/g or more, the vinyl resin (B) has a weight average molecular weight of 4,000 to 40,000, the vinyl resin (B) is a polymer essentially containing a monomer (m) whose homopolymer has an SP value of 11.5 to 16.5 as a constituent monomer, the weight percentage of the monomer (m) in monomers constituting the vinyl resin (B) is 1 wt % or more based on the total weight of the monomers constituting the vinyl resin (B), the polyester resin (A) and the vinyl resin (B) are present at a weight ratio (A)/(B) of 80/20 to 99.5/0.5, and when the vinyl resin (B) contains polyethylene units (C11) having a degree of polymerization of 70 to 210 and/or polypropylene units (C12) having a degree of polymerization of 70 to 210, the total weight percentage of the polyethylene units (C11) and the polypropylene units (C12) in the vinyl resin (B) is 9 wt % or less based on the weight of the vinyl resin (B).
TONER
A toner comprising a toner particle containing a binder resin and a polymer A, wherein the binder resin contains a polyester resin having a specific structure, the polymer A has a first monomer unit derived from a specific (meth)acrylic acid ester and a second monomer unit different from the first monomer unit, a content ratio of the first monomer unit in the polymer A is 5.0 mol % to 60.0 mol % while a content ratio of the second monomer unit in the polymer A is 20.0 mol % to 95.0 mol %, and the SP value of the first monomer unit, the SP value of the second monomer unit, and the SP value of a silicone segment contained in the specific structure satisfy a specific relationship.
Toner and toner manufacturing method
A toner comprising a toner particle containing a binder resin, the storage elastic modulus Gt′ (150) of the toner at 150° C. is at least 1.0×10.sup.4 Pa, the binder resin contains a polymer A having a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer, the first polymerizable monomer is selected from specific (meth)acrylic acid esters, the contents of the first monomer unit and second monomer unit in the polymer A are within specific ranges, and the SP values of the first monomer unit and second monomer unit are within specific ranges.
TONER
A toner comprising a toner particle comprising a binder resin and an azo dye, wherein the binder resin comprises a polymer A, the polymer A is a polymer having a monomer unit derived from methacrylonitrile, and a relationship among an amount of substance (mol) of the monomer unit derived from methacrylonitrile, an amount of substance (mol) of the azo dye, and the number of azo groups in the azo dye in the toner particle satisfies formula below:
[(amount of substance of azo dye (mol))×(number of azo groups in azo dye)/(amount of substance of monomer unit derived from methacrylonitrile (mol))]≤0.500.
TONER
A toner having: a toner particle containing a binder resin including a first resin that is a crystalline resin and a second resin that is an amorphous resin; and a fine particle on a surface of the toner particle, wherein the first resin contains a specific ratio of a specific monomer unit, an acid value of the first resin and an acid value of the second resin are within specific ranges, a domain-matrix structure formed of a matrix containing the first resin and domains containing the second resin appears in cross-sectional observation of the toner, and the fine particle has on the surface a compound containing nitrogen atoms bound or adsorbed thereon.
TONER AND METHOD FOR MANUFACTURING TONER
A toner is provided, which has a toner particle containing a binder resin including a first resin and a second resin, wherein the first resin is a crystalline resin, the second resin is an amorphous resin, the first resin contains a specific amount of a first monomer unit having a specific structure, an acid value of the first resin and an acid value of the second resin are within specific ranges, a domain-matrix structure formed of a matrix containing the first resin and domains containing the second resin appears in cross-sectional observation of the toner, the toner particle contains a multivalent metal element, the multivalent metal element is at least one metal element selected from the group consisting of Mg, Ca, Al, Fe and Zn, and a total content of the multivalent metal element is within a specific range.
Magnetic toner and method for manufacturing magnetic toner
Provided is a magnetic toner having a toner particle containing a binder resin and a magnetic body, wherein the binder resin contains a polymer A having a first monomer unit and a second monomer unit, the first polymerizable monomer is at least one selected from the group consisting of the (meth)acrylic acid esters having C.sub.18-36 alkyl groups, a content of the first monomer unit and a content of the second monomer unit based on the total moles of all monomer units in the polymer A are respectively 5.0 to 60.0 mol % and 20.0 to 95.0 mol %, and assuming that an SP value of the first monomer unit and the second monomer unit are taken as SP.sub.11 (J/cm.sup.3).sup.0.5 and SP.sub.21(J/cm.sup.3).sup.0.5, respectively, 3.00≤(SP.sub.21−SP.sub.11)≤25.00 is satisfied, and an oil absorption of the magnetic body is 5 to 40 ml/100 g.
Two-component developer
Provided is a two-component developer has a toner including a toner particle including a binder resin, and a magnetic carrier, wherein the binder resin includes a polymer A having a first monomer unit derived from a first polymerizable monomer, and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer, the first polymerizable monomer is a specific (meth)acrylic acid ester, a content and an SP value of the first and second monomer units in the polymer A fall within respective specific ranges, the magnetic carrier has a magnetic core and a coating resin of the surface of the magnetic core, the coating resin includes a polymer B having monomer units (a) and (b), each SP value of the monomer units (a) and (b) is a specific value.
Toner
A toner, including a toner particle that contains a binder resin and a release agent, wherein the binder resin contains a polymer A, the polymer A including a first monomer unit derived from a first polymerizable monomer and a second monomer unit derived from a second polymerizable monomer different from the first polymerizable monomer; the first polymerizable monomer is selected from (meth)acrylic acid esters having a C.sub.18-36 alkyl group; the toner has a first monomer unit content and a second monomer unit content in the polymer A which are within specific ranges, and assuming that an SP value of the first monomer unit is taken as SP.sub.11 and an SP value of the second monomer unit is taken as SP.sub.21, the formula (1) below is satisfied, and the molecular weight of the release agent is at least 1,000.
3.00(SP.sub.21SP.sub.11)25.00(1)