A process includes forming an emulsion comprising a monomer and a colorant, the colorant further including an anionic functional group and a lipophilic counter ion, and polymerizing the monomer to form a latex, the latex includes polymer nanoparticles having the colorant dispersed therein.

A toner including toner particles having a resin component containing a crystalline resin and an amorphous resin, in which the resin component contains a tetrahydrofuran-insoluble component, and the content of the tetrahydrofuran-insoluble component with respect to the content of the resin component is 5.0% to 80.0% by mass, wherein a maximum endothermic peak temperature of the tetrahydrofuran-insoluble component is 55.0 to 80.0? C., and the amount of heat absorption in the maximum endothermic peak of the tetrahydrofuran-insoluble component is 10.0 to 80.0 J/g, and toner particles have a structure which comprises a matrix containing the crystalline resin and domains containing the amorphous resin.

A part material for printing three-dimensional parts with an electrophotography-based additive manufacturing system, the part material including a composition having a copolymer (including acrylonitrile units, butadiene units, and aromatic units), a charge control agent, and a heat absorber. The part material is provided in a powder form having a controlled particle size, and is configured for use in the electrophotography-based additive manufacturing system having a layer transfusion assembly for printing the three-dimensional parts in a layer-by-layer manner.

A support material toner particle for use in xerographic additive manufacturing includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of a desired build material toner T.sub.g. A xerographic toner system includes a build toner material and a support toner material, the support toner material includes a polyvinyl alcohol (PVA) polymer and blend-additives including a chitosan and a polyvinylpyrrolidone (PVP), the amount of blend-additives is selected to adjust the T.sub.g of the PVA polymer to be within about 1 C. to about 20 C. of the build material toner T.sub.g. A method of making a support toner material includes blending polyvinyl alcohol with blend additives including a chitosan and polyvinylpyrrolidone and forming support toner particles after the blending step.

A toner is provided. The toner includes a binder resin and a release agent. The release agent has an average aspect ratio of 31 or more, when the average aspect ratio is determined from cross-sectional images of the toner observed with a transmission electron microscope (TEM).

A process includes forming an emulsion comprising a monomer and a colorant, the colorant further including an anionic functional group and a lipophilic counter ion, and polymerizing the monomer to form a latex, the latex includes polymer nanoparticles having the colorant dispersed therein.

A toner set for electrostatic image development includes a white toner including white toner particles containing a polyester resin and a white colorant, and a non-white color toner including color toner particles containing a vinyl resin, a polyester resin, and a color colorant, in which a mass ratio C of the polyester resin to the vinyl resin in the color toner particles is 0.7 or more and 10 or less.

A process includes forming an emulsion comprising a monomer and a colorant, the colorant further including an anionic functional group and a lipophilic counter ion, and polymerizing the monomer to form a latex, the latex includes polymer nanoparticles having the colorant dispersed therein.

A toner having a toner particle including a binder resin, wherein the binder resin includes a crystalline vinyl resin having a specific monomer unit having at least two long-chain alkyl groups, the crystalline vinyl resin contains at least 5.0% by mass of the specific monomer unit having at least two long-chain alkyl groups, based on the mass of the crystalline vinyl resin, the toner particle contains at least one polyvalent metal selected from the group consisting of Mg, Ca, Al, and Zn, and a content ratio of the polyvalent metal in the toner particle is 25 ppm by mass to 500 ppm by mass.

A toner is provided, which has a toner particle including a binder resin and inorganic fine particles, wherein the binder resin includes a crystalline vinyl resin having a specific monomer unit having at least two long-chain alkyl groups, the content of the specific monomer unit is at least 5.0% by mass, based on the mass of the crystalline vinyl resin, the inorganic fine particles each have on a surface thereof alkyl groups, and the content of the inorganic fine particles is 0.10% by mass to 15.00% by mass, based on the mass of the toner particle.