A method of manufacturing a magnetic recording medium forms an unfinished product including a magnetic recording layer and a protection layer that are successively formed on a substrate, and forms a lubricant layer on the protection layer of the unfinished product. The lubricant layer is formed by coating a first organic fluorine compound on the protection layer of the unfinished product, and supplying a gas, including a second organic fluorine compound, onto the protection layer of the unfinished product, and decomposing the second organic fluorine compound by Townsend discharge and ultraviolet ray irradiation. The protection layer includes carbon, and the first organic fluorine compound includes a functional group at a terminal thereof.

High temperature lubricants for magnetic media are provided. One such lubricant includes fluoroalkyl, fluoroalkenyl, perfluoroalkyl, or perfluoroalkyl ether segments, anchoring functional groups engageable with a protective overcoat of a magnetic recording media, and cyclic functional groups. The lubricants can be used in conjunction with a magnetic recording medium and/or a magnetic data storage system.

What is provided is a fluorine-containing ether compound represented by the following formula. R.sup.1—CH.sub.2—R.sup.2—CH.sub.2—OCH.sub.2CH(OH)CH.sub.2O—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4 (In the formula, R.sup.2 and R.sup.3 are perfluoropolyether chains, and R.sup.1 and R.sup.4 are terminal groups having two or three polar groups, in which individual polar groups are bound to different carbon atoms and the carbon atoms to which the polar groups are bound are bound to each other via a linking group having a carbon atom to which the polar groups are not bound).

The fluorine-containing ether compound is represented by the following formula (1): R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4. In the formula (1), R.sup.1 is represented by the following formula (2), R.sup.2 is represented by the following formula (3), R.sup.3 is a perfluoropolyether chain, and R.sup.4 is an organic end group different from R.sup.1—R.sup.2— and contains two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to one another via a linking group containing a carbon atom to which the polar group is not bonded. In the formula (2), R.sup.5 is an alkoxy group selected from the group consisting of a methoxy, an ethoxy and a propoxy group. In the formula (3), w is 2 or 3. ##STR00001##

Provided is a fluorine-containing ether compound capable of forming a lubricant layer having excellent wear resistance even when the thickness is thin, and suitable as a material of a lubricant for a magnetic recording medium. The fluorine-containing ether compound is a compound represented by the following formula (1): R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5; wherein R.sup.3 is a perfluoropolyether chain; R.sup.1 is a terminal group bonded to R.sup.2; R.sup.5 is a terminal group bonded to R.sup.4; R.sup.1 is an alkenyl group or an alkynyl group; R.sup.5 is a group containing a heterocyclic ring; R.sup.2 is represented by the following formula (2); R.sup.4 is represented by the following formula (3); and a in the formula (2) and b in the formula (3) are each independently an integer of 1 to 3. ##STR00001##

A fluorine-containing ether compound represented by Formula (1) is provided,
R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4  (1)
(In Formula (1), R.sup.1 is an alkyl group that may have a substituent, R.sup.2 is a divalent linking group bonded to R.sup.1 via an ethereal oxygen, R.sup.3 is a perfluoropolyether chain, and R.sup.4 is an end group which is different from R.sup.1-R.sup.2 and includes two or three polar groups, in which each of the polar groups is bonded to a different carbon atom, and the carbon atoms bonded to the polar groups are bonded to each other via a linking group containing a carbon atom not bonded to the polar groups.).

A fluorine-containing ether compound represented by Formula (1) is provided;
R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5  (1)
(In Formula (1), R.sup.1 and R.sup.5 may be the same as or different from each other and each represents an alkenyl group having 2 to 8 carbon atoms or an alkynyl group having 3 to 8 carbon atoms, R.sup.2 and R.sup.4 may be the same as or different from each other and each represents a divalent linking group having a polar group, and R.sup.3 represents a perfluoropolyether chain, with a proviso that R.sup.1 and R.sup.2 are, and R.sup.4 and R.sup.5 are divided due to the presence of an atom other than the carbon atom such as an oxygen atom).

A fluorine-containing ether compound represented by formula (1) shown below.

R.sup.4—CH.sub.2—R.sup.3—CH.sub.2—R.sup.2—CH.sub.2—R.sup.1—CH.sub.2—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4  (1)

(In formula (1), R.sup.1 and R.sup.3 represent different perfluoropolyether chains, R.sup.2 represents a linking group containing one or more polar groups, and R.sup.4 represents a terminal group containing two or more polar groups.)

A fluorine-containing ether compound represented by Formula (1) is provided.

R.sup.1—O—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5  (1)

(in the formula, R.sup.3 is a perfluoropolyether chain; R.sup.1 is an alkenyl group having 2 to 8 carbon atoms or an alkynyl group having 3 to 8 carbon atoms; R.sup.2 and R.sup.4 are each independently a divalent linking group having one or more hydroxyl groups; and —R.sup.5 is a group represented by Formula (2) shown below.)

—O—(CH.sub.2).sub.g—N—R.sup.6R.sup.7  (2)

(in the formula, g is an integer of 2 or 3; R.sup.6 and R.sup.7 are the same or different saturated aliphatic groups; and R.sup.6 and R.sup.7 may form a ring structure together with a nitrogen atom.)

This fluorine-containing ether compound is a fluorine-containing ether compound represented by formula (1).
R.sup.1—X—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4  (1)
(In formula (1), R.sup.1 is an alkenyloxy group of 2 to 8 carbon atoms or an alkynyloxy group of 3 to 8 carbon atoms. R.sup.2 is represented by formula (2) shown below. In formula (2), a represents an integer of 1 to 3. X is represented by formula (3) shown below. In formula (3), b represents an integer of 1 to 5, Y is a divalent linking group that is bonded to a carbon atom in formula (2), and R represents an alkyl group of 1 to 6 carbon atoms or H. R.sup.3 represents a perfluoropolyether chain. R.sup.4 represents a terminal group containing two or three polar groups, wherein each polar group is bonded to a different carbon atom, and the carbon atoms to which the polar groups are bonded are bonded to each other via a linking group containing a carbon atom to which a polar group is not bonded.) ##STR00001##