Patent classifications
G03G5/061473
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, ELECTROPHOTOGRAPHIC PHOTORECEPTOR CARTRIDGE AND IMAGE FORMING APPARATUS
An object of the present invention is to provide an electrophotographic photoreceptor which can prevent an increase in potential even using a fluorine resin in a charge transport layer, and can achieve both electrical properties and abrasion resistance, and present invention relates to a lamination type electrophotographic photoreceptor, in which a charge transport layer of the lamination type electrophotographic photoreceptor contains a compound having an E_homo of −4.550 eV or more based on structure optimization calculation by density functional calculation B3LYP/6-31G (d, p) and fluorine resin particles, and a content of the fluorine resin particles is 3% by weight to 20% by weight based on a total mass of the charge transport layer.
Positive charging electrophotographic photoreceptor, electrophotographic cartridge and image forming apparatus
The object of the present invention is to provide a positive charging electrophotographic photoreceptor having high sensitivity, low residual potential, and excellent chargeability, and relates to a positive charging electrophotographic photoreceptor including a conductive support, a photosensitive layer, and a protective layer in this order, the photosensitive layer containing a charge generation substance, a positive hole transport substance, and an electron transport substance in the same layer, in which the positive hole transport substance includes at least one of the compounds represented by any one of the following formulas (1) to (5), and a binder resin of the protective layer is an alcohol-soluble thermoplastic resin, providing that the symbols in the formula are defined in the specification. ##STR00001##
IMAGE FORMING APPARATUS AND IMAGE FORMING METHOD
An image forming apparatus includes an image bearing member, a charger, a light exposure device, a development device, a transfer belt, a primary transfer device, a secondary transfer device, and a cleaning member. The cleaning member is pressed against a circumferential surface of the image bearing member and collects residual toner remaining on the circumferential surface of the image bearing member as a result of primary transfer of a toner. The transfer belt has a surface resistivity of at least 6 Log Ω and no greater than 11 Log Ω. A linear pressure of the cleaning member on the circumferential surface of the image bearing member is at least 10 N/m and no greater than 40 N/m. The image bearing member includes a conductive substrate and a photosensitive layer of a single layer. The image bearing member satisfies formula (1):
ELECTROPHOTOGRAPHIC PHOTOCONDUCTOR, METHOD OF MANUFACTURING THE SAME, AND ELECTROPHOTOGRAPHIC DEVICE
Provided are an electrophotographic photoconductor being resistant to abrasion even in long-term use, having highly sensitive electric characteristics, being capable of maintaining a high retention rate, and being capable of providing a stable image without filming, a method of manufacturing the same, and an electrophotographic device. The photoconductor includes an electroconductive substrate (1), a charge generation layer (3), and a charge transport layer (4); the charge transport layer contains a hole transport material, a resin binder, an electron transport material, and an inorganic oxide; the charge generation layer contains a charge generation material; the masses of the hole transport material, the resin binder, the electron transport material, and the inorganic oxide in the charge transport layer respectively denoted by a to d satisfy 1.5≤b/a≤5.7, 0.005≤c/a≤0.35, 0.05≤d/a≤0.70, a≥c+d, and c/d≥0.01; the hole transport material contains a compound expressed by formula (A-1); and the charge generation material contains titanyl phthalocyanine having an exothermic peak at 251±5° C., a half-value width of the exothermic peak equal to or less than 15° C., and a heating value equal to or greater than 1.0 mJ/mg when a temperature rise condition is 20° C./min in differential scanning calorimetry, and having an X-ray diffraction peak at 27.2±0.3°.
##STR00001##
Photosensitive body for electrophotography, method for producing same and electrophotographic apparatus
An electrophotographic photoreceptor includes a conductive substrate; and a photosensitive layer arranged on the conductive substrate and containing, as a charge generating material, any one material selected from the group consisting of titanyl phthalocyanines, metal-free phthalocyanines, chlorogallium phthalocyanines and hydroxygallium phthalocyanines; and, as an electron transporting material, a naphthalene tetracarboxylic acid diimide compound represented by Formula (1) below, where R.sup.1 and R.sup.2 each represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkylene group, an alkoxy group, an alkyl ester group, a phenyl group optionally having a substituent, a naphthyl group optionally having a substituent, or a halogen element; and R.sup.1 and R.sup.2 are optionally the same or different: ##STR00001##
The photoreceptor realizes a stable print density even in a low-temperature environment by suppressing a reduction in print density that is caused by potential fluctuation of the photoreceptor in the low-temperature environment.
Image forming apparatus and image forming method
In an image forming apparatus, a cleaning member is pressed against a circumferential surface of an image bearing member and collects a toner remaining on the circumferential surface of the image bearing member. The toner has a number average roundness of 0.965 to 0.998. The toner has a D.sub.50 of 4.0 m to 7.0 m. A linear pressure of the cleaning member on the circumferential surface of the image bearing member is 10 N/m to 40 N/m. The image bearing member includes a single-layer photosensitive layer containing a charge generating material and a hole transport material. Ionization potential Ip.sub.HTM of the hole transport material and ionization potential Ip.sub.CGM of the charge generating material satisfy mathematical formula (1) Ip.sub.HTM5.30 eV, mathematical formula (2) Ip.sub.CGM5.30 eV, and mathematical formula (3) 0.09 eV|Ip.sub.HTMIp.sub.CGM|0.30 eV.
Electrophotographic photosensitive member and image forming apparatus
An electrophotographic photosensitive member (1) includes a conductive substrate (2) and a photosensitive layer (3) disposed directly or indirectly on the conductive substrate (2). The photosensitive layer (3) has a charge generating layer (3a) and a charge transport layer (3b) disposed in order from the conductive substrate (2). The charge generating layer (3a) contains a charge generating material. The charge transport layer (3b) contains a charge transport material, a binder resin, and a pigment that absorbs light having an irradiation wavelength. The binder resin includes a polyarylate resin including a repeating unit represented by general formula (1): ##STR00001## In general formula (1), X and Y each represent, independently of one another, a divalent group represented by chemical formula (1-1), (1-2), (1-3), or (1-4): ##STR00002## The pigment is a naphthalocyanine compound represented by general formula (2) or (3): ##STR00003##
ELECTROPHOTOGRAPHIC PHOTORECEPTOR, PROCESS FOR PRODUCING THE ELECTROPHOTOGRAPHIC PHOTORECEPTOR, AND ELECTROPHOTOGRAPHIC DEVICE
An electrophotographic photoreceptor having sufficient solvent resistance and crack resistance in a liquid developer and having excellent electrical characteristics, a process for producing the photoreceptor, and an electrophotographic device are provided at low cost. The electrophotographic photoreceptor includes a conductive base; and a charge generation layer and a charge transport layer sequentially provided on the conductive base. The charge transport layer contains a binder resin that is a copolycarbonate resin having a structure represented by general formula (1) below:
##STR00001##
and a hole transport material that is a compound having a structure represented by general formula (2) below:
##STR00002##
Electrophotographic photosensitive member and method for producing electrophotographic photosensitive member
A method for producing an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order includes: forming a coating film for a protective layer by coating a coating liquid for the protective layer for forming the protective layer on the photosensitive layer and curing the coating film for the protective layer, in which the coating liquid for the protective layer contains a solvent, a compound represented by a general formula (1), a compound represented by a general formula (2), and a compound represented by a general formula (3) at a specific ratio. In addition, in an electrophotographic photosensitive member having a photosensitive layer and a protective layer above a support in this order, the protective layer is obtained by curing a coating liquid for the protective layer.
Electrophotographic photosensitive member
An electrophotographic photosensitive member includes a conductive substrate and a photosensitive layer. The photosensitive layer is a single-layer photosensitive layer and contains a charge generating material, a hole transport material, an electron transport material, and a binder resin. A hole mobility .sub.h is at least 1.0010.sup.7 cm.sup.2/V/second and an electron mobility .sub.e is at least 4.0010.sup.8 cm.sup.2/V/second in the photosensitive layer as measured under conditions of a temperature of 23 C. and an electric field intensity of 1.5010.sup.5 V/cm. A ratio (.sub.h/.sub.e) of the hole mobility .sub.h to the electron mobility .sub.e is at least 1.0 and no greater than 50.0.