Provided is a method for preparing lead iodide, which controls the crystal form of lead iodide through temperature, including: dissolving a lead compound in a first acid solution and adding an iodine compound to form a reaction solution including the first lead iodide; and heating the reaction solution to a temperature of 60° C. or more and standing at a constant temperature, to obtain the second lead iodide, wherein a peak intensity of the (003) crystal plane of the second lead iodide is greater than or equal to a peak intensity of the (110) crystal plane. Provided is also a method for preparing the perovskite film.

A solar cell is described that comprises a transparent conductor sheet having a polymeric substrate with an embedded metal grid, disposed within microchannels extending partially through a thickness of polymeric substrate from a first surface of the polymeric substrate; and a photoactive layer disposed adjacent to the first surface of the polymeric substrate. The transparent conductor sheet has a sheet resistance less than 1 Ω/□ and an average solar direct transmittance over the visible and infrared portion of the spectrum of at least about 80%.

The solar cell of the present disclosure includes a first electrode, a photoelectric conversion layer, an intermediate layer, a hole transport layer, and a second electrode in this order, wherein the hole transport layer includes a hole transport material and an oxidant, the photoelectric conversion layer includes a perovskite compound containing iodine, and the intermediate layer includes at least one selected from the group consisting of bromide, chloride, and fluoride.

A tandem photovoltaic device includes a silicon photovoltaic cell having a silicon layer, a perovskite photovoltaic cell having a perovskite layer, and an intermediate layer between a rear side of the perovskite photovoltaic cell and a front (sunward) side of the silicon photovoltaic cell. The front side of the silicon layer has a textured surface, with a peak-to-valley height of structures in the textured surface of less than 1 μm or less than 2 μm. The textured surface is planarized by the intermediate layer or a layer of the perovskite photovoltaic cell. Forming the tandem photovoltaic device includes texturing a silicon containing layer of a silicon photovoltaic cell and operatively coupling a perovskite photovoltaic cell comprising a perovskite layer to the silicon photovoltaic cell, thereby forming a tandem photovoltaic device and planarizing the textured surface of the silicon containing layer of the silicon photovoltaic cell.

Structures and methods for manufacturing photovoltaic devices by forming perovskite layers and perovskite precursor layers using vapor transport deposition (VTD) are described.

A solar cell module according to the present disclosure includes a first substrate, a second substrate, a solar cell, an intermediate layer, and a first sealing layer. The first sealing layer is disposed between a peripheral portion of the first substrate and a peripheral portion of the second substrate and seals the solar cell and the intermediate layer in an area between the first substrate and the second substrate. The solar cell has a laminate structure including a first electrode, a photoelectric conversion layer, and a second electrode. The intermediate layer is not adhered to the main surface of the solar cell. A softening temperature T1 of a material of the intermediate layer is higher than a softening temperature T2 of a material of the first sealing layer.

Disclosed are a transparent electrode for a solar cell and a method of manufacturing the same. The transparent electrode for a solar cell has a low Young's modulus, excellent elasticity, self-healing properties, an average visible-light transmittance sufficient to implement bifacial properties, and excellent power conversion efficiency (PCE). In addition, the method of manufacturing the transparent electrode for a solar cell does not require an additional deposition process, so the electrode-manufacturing time can be reduced, and the electrode-manufacturing process can be performed separately from other solar-cell-manufacturing processes, which is advantageous for mass production and large-area application.

An organic optoelectronic device comprises an active layer comprising a conjugated polymer material which comprises a structure of Formula I:

##STR00001##

wherein

##STR00002##

, and X.sup.1 and X.sup.2 are independently selected from the groups consisting of: N, CH and -CR.sup.1. A.sup.2 and A.sup.3 are the same or different electron-withdrawing groups, and A.sup.2 and A.sup.3 are not simultaneously the same as A.sup.1. D.sup.1, D.sup.2 and D.sup.3 are electron-donating group. sp.sup.1 to sp.sup.6 are independently selected from aromatic ring and heterocyclic ring. a, b and c are real numbers, and 0 < a ≦1, 0 ≦b ≦1, 0 ≦c ≦1, a+b+c=1. d, e, f, g, h and i are independently selected from 0, 1 and 2. The organic optoelectronic device of the present invention has adjustable energy gap, and can be a high-performance OPV or a high-detectivity OPD.

A solar cell module of the embodiment includes a first solar cell element and a second solar cell element disposed to be aligned, a connection member, and a shield member. The connection member electrically connects a first electrode of the first solar cell element and a second electrode of the second solar cell element. The first solar cell element and the second solar cell element each include a first cell containing a perovskite semiconductor and a second cell containing silicon. The first electrode is disposed at an end portion in a first direction in which the first cell is disposed in a thickness direction. The second electrode is disposed at an end portion in a second direction in which the second cell is disposed in the thickness direction. The shield member is made of an electrically insulating material and is disposed between an end portion of the first electrode of the first solar cell element on the second solar cell element side and the connection member.

High-performance perovskite solar cell (PSC) devices, arrays thereof, and modules manufactured on flexible and stretchable substrates using roll-to-roll high throughput manufacturing techniques. The flexible cells can be cut into strips and are connected via flexible and/or stretchable interconnects. The interconnect can be a layer deposited on a wavy surface of the stretchable substrate, a coiled or hinged wire, or a conductive paste that can be deformed prior to curing. The highly deformable solar modules can conform to complex organic contours and shapes, such as those that are common in vehicle designs. Such shapes typically require at least one axis of flex and at least one axis of stretch.