A perovskite solar cell includes a transparent electrode, an electron transport layer, a perovskite layer, a hole transport layer, and a second electrode in sequence. The perovskite layer includes a main perovskite layer and a two-dimensional perovskite coating layer covering both surface and periphery of the main perovskite layer. The two-dimensional perovskite coating layer includes a first overlay layer disposed between the main perovskite layer and the electron transport layer, a second overlay layer disposed between the main perovskite layer and the hole transport layer, and a third overlay layer covering the periphery of the main perovskite layer.

The invention provides an optoelectronic device comprising a mixed-anion perovskite, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention further provides a mixed halide perovskite of the formula (I) [A][B][X].sub.3 wherein: [A] is at least one organic cation; [B] is at least one divalent metal cation; and [X] is said two or more different halide anions. In another aspect, the invention provides the use of a mixed-anion perovskite as a sensitizer in an optoelectronic device, wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions. The invention also provides a photosensitizing material for an optoelectronic device comprising a mixed-anion perovskite wherein the mixed-anion perovskite comprises two or more different anions selected from halide anions and chalcogenide anions.

The present invention relates to a method for manufacturing: a perovskite solar cell in which the laminated shape and the composition of a perovskite absorbing layer are controlled; and a tandem solar cell comprising the perovskite solar cell, and the perovskite absorbing layer is formed through a method for manufacturing a solar cell, comprising the steps of: forming, on a substrate, an inorganic seed layer conformal with the substrate by using a BO source, an A-doped BO source or an AxOy source and the BO source; and supplying organic halides onto the seed layer, and thus a perovskite thin film having a complex composition conformal with the substrate can be formed such that an effect of enabling light absorption to increase can be achieved.

Optoelectronic devices, such as photovoltaic device and light-emitting diode, are provided. The devices include a quasi two-dimensional layered perovskite material and a passivating agent chemically bonded to the quasi two-dimensional layered perovskite material. The passivating agent includes a phosphine oxide compound. An active material is also provided. The active material includes a quasi two-dimensional perovskite compound having outermost edge(s), and a passivating agent chemically bonded to the outermost edge(s). The passivating agent includes a phosphine oxide compound. Methods for manufacturing the optoelectronics devices and the active material are also provided.

The present invention relates to a novel cathode buffer layer material, and an organic or organic/inorganic hybrid photoelectric device comprising same, and, if a novel compound of the present invention is applied to a cathode buffer layer of an organic photoelectric device such as organic solar cells, organic photodiode, colloidal quantum dot solar cell, and perovskite solar cell, a surface property of an electron transfer layer is improved via a high dipole moment of the novel compound, an electron can be easily extracted from a photoactive layer to a cathode electrode, and series resistance and leakage current can be reduced, thereby having a useful industrial effect, as performance of the organic or organic/inorganic hybrid photoelectric device being manufactured, such as an organic solar cell, organic photodiode, colloidal quantum dot solar cell, and perovskite solar cell, can be significantly improved.

Methods for preparation of surfactant-free ultra-small spinel ternary metal oxide nanoparticles are provided. A method comprises dissolving first and second metal salts in deionized water in a specific mole ratio to form a solution comprising two different metal ions, applying a coprecipitation method and adding an alkaline solution to the solution to form a colloidal suspension, wherein a colloid of the colloidal suspension is a metal hydroxide, adjusting the amount and the addition rate of the alkaline solution to form a specific structure of metal hydroxide precipitate; washing and drying the metal hydroxide to form a structured metal hydroxide powder, and applying a calcination method to the structured metal hydroxide powder to form a surfactant-free spinel-type (AB.sub.2O.sub.4) ternary metal oxide, wherein A and B each respectively comprise a metal element.

The present disclosure relates to a composition that includes a perovskite of A.sub.2BX.sub.4, where A includes an R-form of a chiral molecule of at least one of

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and/or an S-form of the chiral molecule, B includes a cation, X includes an anion, R.sub.1 includes a first carbon chain having between 2 and 5 carbon atoms, R.sub.2 includes at least one of a hydrogen atom, a halogen atom, a carboxylic acid group, an alkoxy group, and/or a second carbon chain, and R.sub.3 includes a third carbon chain.

A nanoparticle that includes a metal oxide core having the formula M.sub.2O.sub.5 wherein M is either tantalum (V) or niobium (V) and alkylsiloxane ligands surrounding the metal oxide core.

A method for producing an organic non-fullerene electron transport compound includes mixing naphthalene-1,4,5,8-tetracarboxylic dianhydride and an amine compound in dimethylformamide. The method also includes heating the mixture to a temperature greater than or equal to 70° and less than or equal to 160° C. for an amount of time greater than or equal to 1 hour and less than or equal to 24 hours. The method further includes isolating an organic non-fullerene electron transport compound reaction product.

A photovoltaic device includes a first electrode, a first photoactive material layer, one or more interfacial layers, a second photoactive material layer comprising a 2-D perovskite material having the formula (C′).sub.a(C).sub.bM.sub.nX.sub.3n+1 and a second electrode. C′ is a bulky organic cation, C is a small organic or inorganic cation, M is a metal, X is a halide, a and b are real numbers, and n is an integer.