The invention discloses a perovskite solar cell and a method of fabrication thereof. The perovskite solar cell sequentially comprises a transparent electrode, a mesoporous P-I-N framework and a counter electrode from the bottom to top; the mesoporous P-I-N framework is composed of an n-type semiconductor layer, an insulating layer, and a p-type semiconductor layer in a sequentially stacked mode, and the n-type semiconductor layer, the insulating layer and the p-type semiconductor layer all comprise mesopores filled with a perovskite material. The preparation method sequentially includes preparing the mesoporous P-I-N framework on a transparent conductive substrate through a spin-coating method or a screen printing method, filling with the perovskite material and preparing the counter electrode layer.

An arrangement includes a solar cell and a covering, wherein the covering covers the solar cell, at least on the side that is intended to be exposed to electromagnetic radiation of the sun. The covering has an electrochromic layer. The arrangement also has a control unit for controlling the electrochromic layer. The control unit is designed to control the transmittance of the electrochromic layer for electromagnetic radiation in a defined wavelength range by applying an electrical voltage to the electrochromic layer.

A porous electrode of the present invention is a porous electrode in which at least a first porous layer, an intermediate layer and a second porous layer are stacked on a substrate in this order, characterized in that the first porous layer and the second porous layer are formed of particles of the same material, and the first porous layer and the intermediate layer are formed of particles of different materials from each other. Preferably, the average particle diameter of the particles constituting the first porous layer differ in average particle diameter from the particles constituting the second porous layer.

Provided is a photoelectric conversion element including a first electrode, a hole blocking layer, an electron transport layer, a first hole transport layer, and a second electrode, wherein the first hole transport layer includes at least one of basic compounds represented by general formula (1a) and general formula (1b) below:

##STR00001##

where in the formula (1a) or (1b), R.sub.1 and R.sub.2 represent a substituted or unsubstituted alkyl group or aromatic hydrocarbon group and may be identical or different, and R.sub.1 and R.sub.2 may bind with each other to form a substituted or unsubstituted heterocyclic group containing a nitrogen atom.

A dye-sensitized solar cell (DSC) element includes at least one DSC, and the DSC includes a first electrode, a second electrode facing the first electrode, and an oxide semiconductor layer provided on the first electrode. The oxide semiconductor layer includes a light absorbing layer provided on the first electrode and a reflecting layer as a layer contacting a portion of a first surface of a side opposite to the first electrode among surfaces of the light absorbing layer and being arranged at a position farthest from the first electrode. The first surface of the light absorbing layer includes a second surface contacting the reflecting layer, and a surface area S.sub.1 of the first surface and a surface area S.sub.2 of the second surface satisfy the following formula:
0.7S.sub.2/S.sub.1<1
The reflecting layer is arranged in an inner side of the first surface of the light absorbing layer.

The present disclosure may provide semiconductor perovskite layers and method of making thereof. In some cases, the perovskite layer may comprise a composition of MA.sub.n1FA.sub.n2Cs.sub.n3PbX.sub.3. MA may be methylammonium, FA may be formamidinium, n1, n2, and n3 may independently be greater than 0 and less than 1, and n1+n2+n3 may equal 1.

The invention relates to a solar cell structure (10) having at least one transparent photovoltaic cell (42), in particular having a dye solar cell or a thin-film semiconductor cell. It comprises at least one polymer layer (36) which is provided with a fluorescent material, or a mixture of a plurality of fluorescent materials, and covers the at least one transparent photovoltaic cell (42).

There is provided a photoelectric conversion element in which a porous semiconductor layer is prevented from being detached from an upper supporting body, wherein a photoelectric conversion layer, a collecting electrode, an insulating layer, and a counter electrode are disposed between an upper supporting body and a lower supporting body in this order from the upper supporting body side, the upper supporting body being located at a light incidence side and having a light transmission property, the lower supporting body being located opposite to the upper supporting body, the photoelectric conversion layer having a porous semiconductor layer, a carrier transport material being included between the upper supporting body and the lower supporting body, and an adhesion portion having a film thickness of 0.5 to 10 nm is disposed at least adjacent to and between the upper supporting body and the porous semiconductor layer.

A solar cell according to the present disclosure includes a first electrode, a second electrode, a photoelectric conversion layer disposed between the first electrode and the second electrode, and an electron transport layer disposed between the first electrode and the photoelectric conversion layer. At least one electrode selected from the group consisting of the first electrode and the second electrode has a light-transmitting property. The photoelectric conversion layer contains a perovskite compound comprising a monovalent cation, a Sn cation, and a halogen anion. The electron transport layer contains porous TiZnO.sub.3.

A photovoltaic device includes a semi-transparent substrate and at least one translucent photovoltaic cell. The photovoltaic cell includes a stack of layers disposed on the substrate, wherein the stack has apertures extending through it at least partially, contain a functionalizing agent and are uniformly distributed within the photovoltaic cell.