A coating method has: a first step for mixing an active material, a binding agent, and a solvent, and obtaining a mixed slurry; a second step for adding an additive to the mixed slurry, stirring the mixed slurry and the additive, and obtaining a coating slurry and a third step for intermittently coating the coating slurry on a collector body, and forming a coated part and a non-coated part. In the second step, the addition amount of the additive is set in accordance with a preset coating speed of the coating slurry, or the weight of the coated part, and the additive includes castor oil, cellulose nanofibers, modified silicone, an amide, polyethylene oxide, propylene glycol monomethyl ether acetate, polyamine, and/or polycarboxylic acid.

A coating method has: a first step for mixing an active material, a binding agent, and a solvent, and obtaining a mixed slurry; a second step for adding an additive to the mixed slurry, stirring the mixed slurry and the additive, and obtaining a coating slurry and a third step for intermittently coating the coating slurry on a collector body, and forming a coated part and a non-coated part. In the second step, the addition amount of the additive is set in accordance with a preset coating speed of the coating slurry, or the weight of the coated part, and the additive includes castor oil, cellulose nanofibers, modified silicone, an amide, polyethylene oxide, propylene glycol monomethyl ether acetate, polyamine, and/or polycarboxylic acid.

The present invention provides a silicon-silicon composite oxide-carbon composite, a method for preparing same, and a negative electrode active material for a lithium secondary battery, comprising same. More particularly, the silicon-silicon composite oxide-carbon composite of the present invention has a core-shell structure wherein the core comprises silicon, a silicon oxide compound, and magnesium silicate, and the shell comprises a carbon layer. In addition, by having a specific range of span values through the adjustment of particle size distribution of the composite, when used as a negative electrode active material of a secondary battery, the composite can improve not only the capacity of the secondary battery but also the cycle characteristics and initial efficiency thereof.

Provided are binder particles for an all-solid-state battery with which an all-solid-state battery having excellent battery characteristics can be obtained even in a situation in which the all-solid-state battery is produced by a dry method. The binder particles for an all-solid-state battery are formed of a polymer and have a cohesion of not less than 1% and less than 30% and a volume-average particle diameter D50 of not less than 10 μm and not more than 100 μm. Moreover, a composition for an all-solid-state battery contains these binder particles for an all-solid-state battery and solid electrolyte particles. Furthermore, a functional layer for an all-solid-state battery is formed from this composition for an all-solid-state battery. Also, an all-solid-state battery includes this functional layer for an all-solid-state battery.

Provided are binder particles for an all-solid-state battery with which an all-solid-state battery having excellent battery characteristics can be obtained even in a situation in which the all-solid-state battery is produced by a dry method. The binder particles for an all-solid-state battery are formed of a polymer and have a cohesion of not less than 1% and less than 30% and a volume-average particle diameter D50 of not less than 10 μm and not more than 100 μm. Moreover, a composition for an all-solid-state battery contains these binder particles for an all-solid-state battery and solid electrolyte particles. Furthermore, a functional layer for an all-solid-state battery is formed from this composition for an all-solid-state battery. Also, an all-solid-state battery includes this functional layer for an all-solid-state battery.

A lithium transition metal oxide electrode including an additional metal is provided herein as well electrochemical cells including the lithium transition metal oxide electrode and methods of making the lithium transition metal oxide electrode. The lithium transition metal oxide electrode includes a first electroactive material including Li.sub.1+aNi.sub.bMn.sub.cM.sub.dO.sub.2, where 0.05≤a≤0.6; 0.01≤b≤0.5; 0.1≤c≤0.9; zero (0)≤d≤0.3; b+c+d=1 or a+b+c+d=1; and M represents an additional metal, such as W, Mo, V, Zr, Nb, Ta, Fe, Al, Mg, Si, or a combination thereof.

A lithium transition metal oxide electrode including an additional metal is provided herein as well electrochemical cells including the lithium transition metal oxide electrode and methods of making the lithium transition metal oxide electrode. The lithium transition metal oxide electrode includes a first electroactive material including Li.sub.1+aNi.sub.bMn.sub.cM.sub.dO.sub.2, where 0.05≤a≤0.6; 0.01≤b≤0.5; 0.1≤c≤0.9; zero (0)≤d≤0.3; b+c+d=1 or a+b+c+d=1; and M represents an additional metal, such as W, Mo, V, Zr, Nb, Ta, Fe, Al, Mg, Si, or a combination thereof.

A cathode structure for a battery includes a substrate having an electrically conductive surface and an electrode deposited onto the electrically conductive surface. The electrode is made of two or more electrode materials, including (i) one or more active materials, and (ii) specified weight percentage ranges of multi-walled carbon nanotubes (“MWCNTs”), or milled carbon fibers (“MCFs”), or a mixture of MWCNTs and MCFs. Using the specified weight percentage ranges, the electrode may be produced with a thickness of greater than 120 μm. Also disclosed are a slurry formulation for producing thick electrodes for a battery, and a method of fabricating a cathode structure for a battery.

Provided is a lithium-containing oxide precursor solution for coating an electrode active material that is capable of improving the coverage of a coating layer that is formed by applying the lithium-containing oxide precursor solution to the surface of powder of the electrode active material and king it, and that is easy to handle in a normal atmosphere because a solution composed mainly of water is used as a solvent. The lithium-containing oxide precursor solution for coating an electrode active material includes Li in an amount of 0.1 mass % or more and 5.0 mass % or less, at least one element selected from Nb, F, Fe, P, Ta, V, Ge, B, Al, Ti, Si, W, Zr, Mo, S, Cl, Br, and I in an amount of 0.05 mass % or more and 35 mass % or less, and water in an amount of 60 mass % or more and 98.4 mass % or less. The value of absorbance of the solution at a wavelength of 660 nm is 0.1 or less, and the value of surface energy thereof is 72 mN/m or less.

Provided is a lithium-containing oxide precursor solution for coating an electrode active material that is capable of improving the coverage of a coating layer that is formed by applying the lithium-containing oxide precursor solution to the surface of powder of the electrode active material and king it, and that is easy to handle in a normal atmosphere because a solution composed mainly of water is used as a solvent. The lithium-containing oxide precursor solution for coating an electrode active material includes Li in an amount of 0.1 mass % or more and 5.0 mass % or less, at least one element selected from Nb, F, Fe, P, Ta, V, Ge, B, Al, Ti, Si, W, Zr, Mo, S, Cl, Br, and I in an amount of 0.05 mass % or more and 35 mass % or less, and water in an amount of 60 mass % or more and 98.4 mass % or less. The value of absorbance of the solution at a wavelength of 660 nm is 0.1 or less, and the value of surface energy thereof is 72 mN/m or less.