An energy storage device, such as a silver oxide battery, can include a silver-containing cathode and an electrolyte having an ionic liquid. An anion of the ionic liquid is selected from the group consisting of: methanesulfonate, methylsulfate, acetate, and fluoroacetate. A cation of the ionic liquid can be selected from the group consisting of: imidazolium, pyridinium, ammonium, piperidinium, pyrrolidinium, sulfonium, and phosphonium. The energy storage device may include a printed or non-printed separator. The printed separator can include a gel including dissolved cellulose powder and the electrolyte. The non-printed separator can include a gel including at least partially dissolved regenerate cellulose and the electrolyte. An energy storage device fabrication process can include applying a plasma treatment to a surface of each of a cathode, anode, separator, and current collectors. The plasma treatment process can improve wettability, adhesion, electron and/or ionic transport across the treated surface.

An energy storage device, such as a silver oxide battery, can include a silver-containing cathode and an electrolyte having an ionic liquid. An anion of the ionic liquid is selected from the group consisting of: methanesulfonate, methylsulfate, acetate, and fluoroacetate. A cation of the ionic liquid can be selected from the group consisting of: imidazolium, pyridinium, ammonium, piperidinium, pyrrolidinium, sulfonium, and phosphonium. The energy storage device may include a printed or non-printed separator. The printed separator can include a gel including dissolved cellulose powder and the electrolyte. The non-printed separator can include a gel including at least partially dissolved regenerate cellulose and the electrolyte. An energy storage device fabrication process can include applying a plasma treatment to a surface of each of a cathode, anode, separator, and current collectors. The plasma treatment process can improve wettability, adhesion, electron and/or ionic transport across the treated surface.

Energy storage devices, battery cells, and batteries of the present technology may include a first current collector including a material characterized by a maximum corrosion current in an aqueous electrolyte below or about 2 mA/cm.sup.2. The batteries may include a cathode material coupled with the first current collector. The batteries may include a second current collector, and may include an anode material coupled with the second current collector. The batteries may also include an aqueous electrolyte characterized by a pH greater than or about 14.

A layered double hydroxide (LDH) separator capable of more effectively restraining short circuiting caused by zinc dendrites. The LDH separator for secondary zinc batteries includes a porous substrate made of a polymer material and a LDH plugging pores in the porous substrate. The LDH separator has a dendrite buffer layer therein, the dendrite buffer layer being at least one selected from the group consisting of: (i) a pore-rich internal porous layer in the porous substrate, the internal porous layer being free from the LDH or deficient in the LDH; (ii) a releasable interfacial layer; which is provided by two adjacent layers constituting part of the LDH separator in releasable contact with each other; and (iii) an internal gap layer free from the LDH and the porous substrate, which is provided by two adjacent layers constituting part of the LDH separator formed apart from each other.

The present invention provides a novel method for charging silver-zinc rechargeable batteries and an apparatus for practicing the charging method. The recharging apparatus includes recharging management circuitry; and one or more of a silver-zinc cell, a host device or a charging base that includes the recharging management circuitry. The recharging management circuitry provides means for regulating recharging of the silver-zinc cell, diagnostics for evaluating battery function, and safety measures that prevent damage to the apparatus caused by charging batteries composed of materials that are not suited for the charging method (e.g., non-silver-zinc batteries).

A method of making an electrode by providing a mixture of first particles of silver or silver oxide and second particles of an inorganic porogen, molding the mixture, cohering the mixture to form a green body, demolding the green body, heating the green body to form a monolith, to convert any silver oxide to silver, and to fuse the first particles together, and submerging the monolith in a liquid that removes the second particles.

A method of making an electrode by providing a mixture of first particles of silver or silver oxide and second particles of an inorganic porogen, molding the mixture, cohering the mixture to form a green body, demolding the green body, heating the green body to form a monolith, to convert any silver oxide to silver, and to fuse the first particles together, and submerging the monolith in a liquid that removes the second particles.

A prismatic Zn—AgO secondary twin cell battery includes: an outer cell case of prismatic shape, wherein the outer cell case has bottom surface and a top surface with a cell case cover, an electrode assembly housed inside the outer cell case. The electrode assembly is formed by stacking a positive electrode plate and a negative electrode plate covered with a separator. The cell case cover is provided on the top/upper surface with a positive electrode terminal and a negative electrode terminal which seals the battery twin cell and an internal cell wall interposed in between the positive electrode plate and the negative electrode plate. The positive electrode plate and the negative electrode plate are coupled internally by crimping and potted to avoid inter cell leakage.

A prismatic Zn—AgO secondary twin cell battery includes: an outer cell case of prismatic shape, wherein the outer cell case has bottom surface and a top surface with a cell case cover, an electrode assembly housed inside the outer cell case. The electrode assembly is formed by stacking a positive electrode plate and a negative electrode plate covered with a separator. The cell case cover is provided on the top/upper surface with a positive electrode terminal and a negative electrode terminal which seals the battery twin cell and an internal cell wall interposed in between the positive electrode plate and the negative electrode plate. The positive electrode plate and the negative electrode plate are coupled internally by crimping and potted to avoid inter cell leakage.

A separator which is permeable to hydroxide ion, and which contains at least one Dendrite Stopping Substance such as Ni(OH).sub.2, or its precursor.