Disclosed herein a monovalent-ion-selective composite membrane comprising a polymeric cation exchange membrane and a metal-oxide-based layer, wherein said metal-oxide-based layer comprises a metal oxide or an organic-inorganic hybrid polymer, of e.g. Zn, Al, Mg, Si, Cu, W, Ni, or Ti. Also disclosed are the methods for the preparation of the membrane, and also electrodialysis assemblies comprising the membranes.

The present application relates to a separator in the electrochemical field and a preparation method therefor, and to a secondary battery comprising the separator, a device comprising the secondary battery. The separator of the present application is prepared by a simple process and has excellent heat resistance performance. Moreover, the secondary batteries and devices comprising the separator of the present application have good safety performance and cycling performance.

The present application relates to a separator in the electrochemical field and a preparation method therefor, and to a secondary battery comprising the separator, a device comprising the secondary battery. The separator of the present application is prepared by a simple process and has excellent heat resistance performance. Moreover, the secondary batteries and devices comprising the separator of the present application have good safety performance and cycling performance.

The present application relates to a separator, comprising a substrate and a coating formed on at least one surface of the substrate; wherein the coating comprises inorganic particles and organic particles, the organic particles comprise first organic particles and second organic particles both embedded in the inorganic particles and forming protrusions on the surface of the coating, the first organic particles have a number-average particle size of ≥8 μm; the second organic particles have a number-average particle size of ≥2 μm, and at least part of the second organic particles comprise a core structure and a shell structure. The present application also relates to a secondary battery comprising the separator, a device comprising the secondary battery and a method for preparing the separator.

The present application relates to a separator, comprising a substrate and a coating formed on at least one surface of the substrate; wherein the coating comprises inorganic particles and organic particles, the organic particles comprise first organic particles and second organic particles both embedded in the inorganic particles and forming protrusions on the surface of the coating, the first organic particles have a number-average particle size of ≥8 μm; the second organic particles have a number-average particle size of ≥2 μm, and at least part of the second organic particles comprise a core structure and a shell structure. The present application also relates to a secondary battery comprising the separator, a device comprising the secondary battery and a method for preparing the separator.

The present application relates to a separator, comprising a substrate and a coating formed on at least one surface of the substrate, wherein the coating comprises inorganic particles and first organic particles embedded in the inorganic particles and forming protrusions on the surface of the coating, and the first organic particles have a primary particle morphology and a number-average particle size of ≥2 μm. The present application also relates to a secondary battery comprising the separator, a device comprising the secondary battery and a method for preparing the separator.

The present application relates to a separator, comprising a substrate and a coating formed on at least one surface of the substrate, wherein the coating comprises inorganic particles and first organic particles embedded in the inorganic particles and forming protrusions on the surface of the coating, and the first organic particles have a primary particle morphology and a number-average particle size of ≥2 μm. The present application also relates to a secondary battery comprising the separator, a device comprising the secondary battery and a method for preparing the separator.

Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10 C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.

Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10 C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.

A plasma generator for a secondary battery includes a transfer roller for transferring a separator and a plasma generation part configured to form an adhesive surface having adhesive force on a portion of a surface of the separator transferred by the transfer roller and a non-adhesive surface having no adhesive force on a remaining portion. The plasma generation part includes a metal member embedded in the transfer roller, a plasma generation member configured to be spaced apart from the transfer roller and to react with the metal member to generate plasma and thereby to-form the adhesive surface, and a blocking member on an outer circumferential surface of the transfer roller configured to block the reaction between the metal and plasma generation members and thereby form the non-adhesive surface having no adhesive force on the remaining portion of the surface of the separator.