Provided are a separator and a method for producing the same, and more particularly, a separator which may secure battery stability and has characteristics of significantly low heat shrinkage even at a high temperature and minimally increased resistance, and a method for producing the same.

The separator according to the present disclosure includes: a porous substrate; and an inorganic particle layer positioned on one or both surfaces of the porous substrate, wherein the inorganic particle layer includes inorganic particles and a rod-shaped inorganic binder.

A separator for power storage devices includes a synthetic resin film having minute pore portions, the separator having an air resistance of 30 sec/100 mL/16 μm or more and 100 sec/100 mL/16 μm or less, and a first scattering peak in a stretching direction measured by small-angle X-ray scattering measurement (SAXS) present in a range where a scattering vector is 0.0030 nm.sup.−1 or more and 0.0080 nm.sup.−1 or less.

A separator including a porous substrate layer, an intermediate layer, and a ceramic coating layer is provided. The ceramic coating layer is disposed on a side of the intermediate layer away from the porous substrate layer. The intermediate layer includes a metal oxide powder. The particle diameter of the metal oxide powder is less than the pore diameter of the porous substrate layer, and at least a portion of the metal oxide powder is embedded in the porous substrate layer. A method of preparing the separator and a lithium-ion battery including the separator are also provided.

A separator including a porous substrate layer, an intermediate layer, and a ceramic coating layer is provided. The ceramic coating layer is disposed on a side of the intermediate layer away from the porous substrate layer. The intermediate layer includes a metal oxide powder. The particle diameter of the metal oxide powder is less than the pore diameter of the porous substrate layer, and at least a portion of the metal oxide powder is embedded in the porous substrate layer. A method of preparing the separator and a lithium-ion battery including the separator are also provided.

Disclosed is a method for manufacturing a functionalized separator having a zwitterionic coating thereon. The method includes preparing a porous separator; coating a linker on a surface of the porous separator; and chemically reacting zwitterions with the linker such the zwitterions are grafted to the linker on the surface of the separator. The zwitterions grafted to the linker acts as a monolayer to functionalize the surface of the separator. The functionalized separator may disallow elution of polysulfide compound in a lithium-sulfur battery. Further, the functionalized separator may increase ion conductivity of electrolyte of the lithium-sulfur battery and thus ensure high output characteristics.

Disclosed is a method for manufacturing a functionalized separator having a zwitterionic coating thereon. The method includes preparing a porous separator; coating a linker on a surface of the porous separator; and chemically reacting zwitterions with the linker such the zwitterions are grafted to the linker on the surface of the separator. The zwitterions grafted to the linker acts as a monolayer to functionalize the surface of the separator. The functionalized separator may disallow elution of polysulfide compound in a lithium-sulfur battery. Further, the functionalized separator may increase ion conductivity of electrolyte of the lithium-sulfur battery and thus ensure high output characteristics.

A composite membrane with nanostructured inorganic and organic phases is applied as an ion-selective layer to prove processability, prevent dendrite shorting, and increase power output of lithium-metal anodes through better Li-ion conductivity. Nanoconfinement, as opposed to macroscale confinement, is known to dramatically alter the properties of bulk materials. Control over a ceramic's size, shape, and properties is achieved with polymer templates. This is a new composition of matter and unique approach to composite membrane design.

A lithium-sulfur battery comprising a separator in which an adsorption layer including a radical compound having a nitroxyl radical site is formed, and in particular, to a lithium-sulfur battery suppressing elution of lithium polysulfide by using an adsorption layer including a radical compound having a nitroxyl radical site and optionally a conductive material on at least one surface of a separator. In the lithium-sulfur battery, elution and diffusion may be prevented by a radical compound having a nitroxyl radical site, a stable radical compound, adsorbing lithium polysulfide eluted from positive electrode, and in addition thereto, electrical conductivity is further provided to provide a reaction site of a positive electrode active material, and as a result, battery capacity and lifetime properties are enhanced.

A lithium-sulfur battery comprising a separator in which an adsorption layer including a radical compound having a nitroxyl radical site is formed, and in particular, to a lithium-sulfur battery suppressing elution of lithium polysulfide by using an adsorption layer including a radical compound having a nitroxyl radical site and optionally a conductive material on at least one surface of a separator. In the lithium-sulfur battery, elution and diffusion may be prevented by a radical compound having a nitroxyl radical site, a stable radical compound, adsorbing lithium polysulfide eluted from positive electrode, and in addition thereto, electrical conductivity is further provided to provide a reaction site of a positive electrode active material, and as a result, battery capacity and lifetime properties are enhanced.

A method for manufacturing a crosslinked polyolefin separator and a separator are provided. The method includes putting a polyolefin and a polyolefin elastomer into an extruder first, and putting an alkoxy silane containing a carbon-carbon double bond functional group, an initiator and a crosslinking catalyst to form the separator. The crosslinked polyolefin separator has high meltdown temperature and low shutdown temperature.