Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li.sup.+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.

Set forth herein are pellets, thin films, and monoliths of lithium-stuffed garnet electrolytes having engineered surfaces. These engineered surfaces have a list of advantageous properties including, but not limited to, low surface area resistance, high Li.sup.+ ion conductivity, low tendency for lithium dendrites to form within or thereupon when the electrolytes are used in an electrochemical cell. Other advantages include voltage stability and long cycle life when used in electrochemical cells as a separator or a membrane between the positive and negative electrodes. Also set forth herein are methods of making these electrolytes including, but not limited to, methods of annealing these electrolytes under controlled atmosphere conditions. Set forth herein, additionally, are methods of using these electrolytes in electrochemical cells and devices. The instant disclosure further includes electrochemical cells which incorporate the lithium-stuffed garnet electrolytes set forth herein.

A lithium ion cell includes a ribbon-shaped electrode-separator assembly having an anode, a separator, and a cathode. The electrode-separator assembly has two terminal end faces or two terminal sides. The anode comprises a ribbon-shaped anode current collector having a first longitudinal edge, the cathode comprises a ribbon-shaped cathode current collector having a first longitudinal edge, and the electrode-separator assembly is enclosed in a housing. The first longitudinal edge of the anode current collector protrudes from one of the terminal end faces or terminal sides of the stack and the first longitudinal edge of the cathode current collector protrudes from the other. A contact sheet metal member is in direct contact with a respective longitudinal edge. A part of the housing serves as the contact sheet metal member and/or the contact sheet metal member forms a part of the housing enclosing the electrode-separator assembly.

A lithium-ion cell includes a ribbon-shaped electrode-separator assembly having an anode, a cathode, and a separator. The electrode-separator assembly is in the form of a winding with two terminal end faces. The anode has a ribbon-shaped anode current collector with a free edge strip extending along a first longitudinal edge that is not loaded with negative electrode material. The cathode has a ribbon-shaped cathode current collector with a free edge strip extending along a first longitudinal edge that is not loaded with positive electrode material. The separator has at least one inorganic material that improves its resistance to thermal stress. The lithium-ion cell further includes a housing enclosing the electrode-separator assembly and a metallic contact element. The metallic contact element is connected to a respective first longitudinal edge of one of the current collectors by a weld.

Provided is a separator for a power storage device that combines high permeability and battery safety at high temperature. The separator for a power storage device has an inorganic content layer that contains inorganic particles and polyolefin resin. In a cross section of the inorganic content layer, a ratio b of the area occupied by the inorganic particles is 9-35% [inclusive], the ratio of the area occupied by vacancies is 20-60% [inclusive], and a TD direction heat shrinkage a at 150° C. of the separator for a power storage device is 4% or less.

Provided is an electrochemical device including a negative electrode, a positive electrode, and a separator disposed between the negative electrode and the positive electrode. In the electrochemical device, the negative electrode is an electrode containing magnesium, and is in contact with a fullerene analogue-containing layer containing a fullerene analogue. The electrolytic solution of the electrochemical device includes a solvent and a magnesium salt contained in the solvent.

A cell of Li-ion battery comprises a plurality of anodes and cathodes of rectangular shape, each one having a current collector tab protruding from a side of the rectangular shape. Each cathode is wrapped in a separator sheet and the cathodes and anodes are stacked on each other. A Li-ion battery comprises a stack of cells and at least four bus bar posts, each bus bar post being positioned in front of one tab in order to create an electrical connection between the tab and the bus bar post. A method for disassembling the battery comprises—holding the anode bus bar posts, and simultaneously pulling the cathode bus bar posts in the direction of the cathode tab protrusions, pulling the anode bus bar posts in the direction of the anode tab protrusions, separating the cathodes from the separators, and separating electrodes from the bus bar posts.

The method for manufacturing a positive electrode active material for a non-aqueous electrolyte secondary battery according to one embodiment of the present invention comprises: a first step for adding an alkaline solution having a tungsten compound dissolved therein to a lithium-metal composite oxide powder represented by general formula Li.sub.zNi.sub.1-x-yCo.sub.xM.sub.yO.sub.2 (where 0≤x≤0.1, 0≤y≤0.1, and 0.97≤z≤1.20 are satisfied, and M is at least one type of element selected from among Mn, W, Mg, Mo, Nb, Ti, Si, and Al), and mixing same; and a second step for heating the mixture of the alkaline solution and the lithium-metal composite oxide powder at 100-600° C., wherein the amount of the alkaline solution to be added in the first step is 0.1-10 mass % with respect to the amount of the lithium-metal composite oxide powder.

The method for manufacturing a positive electrode active material for a non-aqueous electrolyte secondary battery according to one embodiment of the present invention comprises: a first step for adding an alkaline solution having a tungsten compound dissolved therein to a lithium-metal composite oxide powder represented by general formula Li.sub.zNi.sub.1-x-yCo.sub.xM.sub.yO.sub.2 (where 0≤x≤0.1, 0≤y≤0.1, and 0.97≤z≤1.20 are satisfied, and M is at least one type of element selected from among Mn, W, Mg, Mo, Nb, Ti, Si, and Al), and mixing same; and a second step for heating the mixture of the alkaline solution and the lithium-metal composite oxide powder at 100-600° C., wherein the amount of the alkaline solution to be added in the first step is 0.1-10 mass % with respect to the amount of the lithium-metal composite oxide powder.

In accordance with at least selected embodiments or aspects, the present invention is directed to improved, unique, and/or complex performance lead acid battery separators, such as improved flooded lead acid battery separators, batteries including such separators, methods of production, and/or methods of use. The preferred battery separator of the present invention addresses and optimizes multiple separator properties simultaneously. It is believed that the present invention is the first to recognize the need to address multiple separator properties simultaneously, the first to choose particular multiple separator property combinations, and the first to produce commercially viable multiple property battery separators, especially such a separator having negative cross ribs.